Study of anisotropy through microscopy, internal friction and electrical resistivity measurements of Ti-6Al-4V samples fabricated by selective laser melting

Purpose This paper aims to investigate the microstructural anisotropy of Ti-6Al-4V samples fabricated by selective laser melting. Design/methodology/approach Specimens are fabricated through a Renishaw AM400 selective laser melting machine. Three microstructures (as-built, 850°C annealed and 1,050°C annealed) and two building orientations, parallel (PA) and perpendicular (PE) to the building platform, are considered. Starting from in-depth microscopic observations and comprehensive electron backscattered diffraction imaging, the study addresses non-conventional techniques such as internal friction and electrical resistivity measurements to assess the anisotropy of the fabricated parts. Findings Microscope observations highlight a fine texture with columnar grains parallel to the building direction in the as-built and 850°C annealed samples. Besides, coarse grains characterized the 1,050°C annealed specimens. Internal friction measurements pointed out the presence of internal stress while storage modulus analyses appear sensitive to texture. Electrical resistivity is resulted to be dependent on grain orientation. Originality/value The work uses some novel characterization techniques to study the anisotropy and internal stresses of Ti-6Al-4V samples processed by selective laser melting. Mechanical spectroscopy results suitable in this kind of study, as it mimics the operating conditions of the material.

Determination of the anisotropic elasticity tensor by mechanical spectroscopy

A method is proposed to identify the fully anisotropic elasticity tensor by applying the impulse excitation technique. A specially designed batch of several differently oriented bar-shaped specimens with rectangular cross section is analyzed with respect to the eigenfrequencies of their fundamental flexural and torsional modes. Estimations based on the equations for the calculation of the isotropic Young’s modulus and the shear modulus from the ASTM standard allow a first approximation of the elasticity tensor from a selected subset of the measured eigenfrequencies. Subsequently, a more precise determination of the elasticity tensor is achieved by a numerical modal analysis using the finite element method. In this course, a Newton–Raphson optimization method is applied to solve the inverse problem. The proposed approach is demonstrated on a batch of specimen fabricated from the nickel-base alloy IN718 by selective laser melting.

Dynamic Processes and Mechanisms Involved in Relaxations of Single-Chain Nano-Particle Melts

We present a combined study by quasielastic neutron scattering (QENS), dielectric and mechanical spectroscopy, calorimetry and wide-angle X-ray diffraction on single-chain nano-particles (SCNPs), using the corresponding linear precursor chains as reference, to elucidate the impact of internal bonds involving bulky cross-links on the properties of polymer melts. Internal cross-links do not appreciably alter local properties and fast dynamics. This is the case of the average inter-molecular distances, the β-relaxation and the extent of the atomic displacements at timescales faster than some picoseconds. Contrarily, the α-relaxation is slowed down with respect to the linear precursor, as detected by DSC, dielectric spectroscopy and QENS. QENS has also resolved broader response functions and stronger deviations from Gaussian behavior in the SCNPs melt, hinting at additional heterogeneities. The rheological properties are also clearly affected by internal cross-links. We discuss these results together with those previously reported on the deuterated counterpart samples and on SCNPs obtained through a different synthesis route to discern the effect of the nature of the cross-links on the modification of the diverse properties of the melts.

Time–connectivity superposition and the gel/glass duality of weak colloidal gels

Colloidal gels result from the aggregation of Brownian particles suspended in a solvent. Gelation is induced by attractive interactions between individual particles that drive the formation of clusters, which in turn aggregate to form a space-spanning structure. We study this process in aluminosilicate colloidal gels through time-resolved structural and mechanical spectroscopy. Using the time–connectivity superposition principle a series of rapidly acquired linear viscoelastic spectra, measured throughout the gelation process by applying an exponential chirp protocol, are rescaled onto a universal master curve that spans over eight orders of magnitude in reduced frequency. This analysis reveals that the underlying relaxation time spectrum of the colloidal gel is symmetric in time with power-law tails characterized by a single exponent that is set at the gel point. The microstructural mechanical network has a dual character; at short length scales and fast times it appears glassy, whereas at longer times and larger scales it is gel-like. These results can be captured by a simple three-parameter constitutive model and demonstrate that the microstructure of a mature colloidal gel bears the residual skeleton of the original sample-spanning network that is created at the gel point. Our conclusions are confirmed by applying the same technique to another well-known colloidal gel system composed of attractive silica nanoparticles. The results illustrate the power of the time–connectivity superposition principle for this class of soft glassy materials and provide a compact description for the dichotomous viscoelastic nature of weak colloidal gels.