Proportions, Timing, and Re-equilibration Progress During the 1959 Summit Eruption of Kīlauea: an Example of Magma Mixing Processes Operating During OIB Petrogenesis

Petrographic and chemical analysis of scoria samples collected during the 1959 Kīlauea summit eruption illustrate the progress of thermal and chemical homogenization of the melts, and the gradual growth and/or re-equilibration of olivine phenocrysts, over the course of the eruption. Glass compositions show that thermal equilibration was largely complete within the span of the eruption, while chemical homogenization was a work in progress. The olivine phenocryst population, known to contain conspicuous antecrystic components, is also hybrid within the euhedral population. The bulk of the olivine reached the level of the erupting magma on November 18-19, 1959. Zoning patterns in olivine phenocrysts show that initially unzoned grains developed normal zoning by the end of the eruption. Reverse zoning in relatively Fe-rich olivine phenocrysts (interpreted as cognate to the stored magma) was progressively eliminated from November 21 to December 19, 1959, by diffusive re-equilibration between crystals and melt. Toward the end of the eruption, the only olivine composition in direct contact with the melt was Fo84-86, with the original rim compositional heterogeneity gone in 4-5 weeks’ time. Activity in December 1959 differed from that in November, as high fountaining events were more closely spaced and almost all samples were picritic, with bulk MgO ≥16.5 wt %. Three different levels were in play during the 1959 eruption: a deep source for high-MgO melts and forsteritic (Fo87-89) olivines, an intermediate source for the bulk of the stored magma, and a shallower source for the most differentiated magma. This model is consistent with geophysical, petrologic and chemical observations. Comparison of the 1959 eruption with results from older explosive deposits suggest that stored and recharge melts and olivine from the deeper parts of Kīlauea’s plumbing are similar in composition to those observed or inferred in the 1959 eruption, so they behave similarly during extrusive and explosive periods alike.

Distribution of sulfides and PGE minerals in the picritic and taxitic gabbro-dolerites of the Norilsk 1 intrusion

ABSTRACT Disseminated ores in the Norilsk 1 intrusion were studied to elucidate the typomorphic features of sulfides and noble metal mineralizations in picritic and taxitic (or lower olivine) gabbro-dolerites. The former are characterized by the development of a low-sulfur sulfide association (troilite, Fe-rich pentlandite, talnakhite, chalcocite, native copper) while the latter exhibits a high-sulfur association (monoclinic pyrrhotite, Ni-rich pentlandite, pyrite, heazlewoodite). The contact between these types of rocks is geochemically and mineralogically contrasting. The mineralogical and geochemical zoning directed from the roof to the base of each layer is expressed by an increase in the Cu content (and chalcopyrite) in ores, an increase in the concentration of Ni in pentlandite and S in pyrrhotite in line with a decrease of the crystallization temperature, and an increase in sulfur fugacity in the same direction. Zoning of Pd(Pt) mineralization in picritic and taxitic (olivine) gabbro-dolerites is uniform and characterized by the distribution of Pd-Sn compounds in the upper parts (together with Pd-Pb minerals in picritic rocks) and Pd-As compounds in the lower parts of the sections according to a drop in temperature. Such reverse zoning contradicts the typical mechanism of differentiation by fractional crystallization, and possibly suggests a fluid-magmatic nature. Mineralogical and geochemical features in platinum group element-Cu-Ni-bearing rocks are consistent with the idea that different stages of multi-pulse intrusions of mafic-ultramafic magmas with different compositions formed the picritic and taxitic gabbro-dolerites of the Norilsk region.

Compositional Evolution of the Variscan Intra-Orogenic Extensional Magmatism in the Valencia del Ventoso Plutonic Complex, Ossa-Morena Zone (SW Iberia): A View from Amphibole Compositional Relationships

The Ossa-Morena Zone (OMZ), SW Iberia, has numerous Lower Carboniferous compositionally zoned plutons that formed in a Variscan intra-orogenic extensional setting. This magmatism shows a wide compositional variation comprising alkaline, transitional, and calc-alkaline suites. The calc-alkaline suite was produced by hybridization of alkaline magmas with felsic melts generated by crustal anatexis related to the intrusion of mafic magmas in the middle crust. In this work, we present a textural and mineralogical study of the Variscan Valencia del Ventoso main pluton from the OMZ to track the compositional evolution of magmas during hybridization using constraints from amphibole compositions and to determine the P-T conditions of emplacement using amphibole-based thermobarometry. This pluton exhibits reverse zoning with an inner facies containing alkaline dolerites, gabbros, and quartz diorites, an intermediate facies with transitional diorites, and an outer facies with calc-alkaline quartz diorites to monzogranites. Magmas from the intermediate and border facies crystallized under oxidizing conditions at relatively low temperatures (range: 640–760 °C) and ca. 280–300 MPa, implying near H2O-saturated conditions. These rock facies show mineralogical evidence of hybridization between alkaline to mildly alkalic and calc-alkaline magmas. The former is inferred from the occurrence of antecrysts of labradorite-andesine, high-Ti pargasite-hastingsite, and biotite with deficiency in tetrahedral-site occupancy, a distinctive feature of biotite from the inner facies alkaline dolerites. This contrasts with later crystallization from the calc-alkaline magma of andesine-oligoclase, low-Ti magnesiohornblende-edenite, and biotite with full tetrahedral-site occupancy. Constraints from amphibole-melt compositional relationships in antecrystic high-Ti amphibole suggest that the alkaline magmatic component could have a high- to ultra-K affinity.

Experimental constraints on dacite magma storage beneath Volcán Quizapu, Chile

Volcán Quizapu, Chile, is an under-monitored volcano that was the site of two historical eruptions: an effusive eruption in 1846-1847 and a Plinian eruption in 1932, both of which discharged ∼5 km3 (DRE) of lava and/or tephra. The majority of material erupted in both cases is trachydacite, nearly identical for each event. We present H2O-saturated, phase equilibrium experiments on this end-member dacite magma, using a pumice sample from the 1932 eruption as the main starting material. At an oxygen fugacity (fO2) of ∼NNO+0.2, the phase assemblage of An25-30 plagioclase + amphibole + orthopyroxene, without biotite, is stable at 865±10 °C and 110±20 MPa H2O pressure (PH2O), corresponding to ∼4 km depth. At these conditions, experiments also reproduce the quenched glass composition of the starting pumice. At slightly higher PH2O and below 860 °C, biotite joins the equilibrium assemblage. Because biotite is not part of the observed Quizapu phase assemblage, its presence places an upper limit on PH2O. At the determined storage PH2O of ∼110 MPa, H2O undersaturation of the magma with XH20fluid==0.87 would align Ptotal to mineral-based geobarometry estimates of ∼130 MPa. However, XH20fluid=1< 1 is not required to reproduce the Quizapu dacite phase assemblage and compositions. A second suite of experiments at lower fO2 shows that the stability fields of the hydrous silicates (amphibole and biotite) are significantly restricted at NNO-2 relative to NNO+0.2. Additional observations of Quizapu lava and pumice samples support the existing hypothesis that rapid pre-eruptive heating drove the effusive 1846-1847 eruption, with important refinements. We demonstrate that microlites in the end-member dacite lavas are consistent with in situ crystallization (during ascent), rather than transfer from an andesite. In one end-member dacite lava, newly identified reverse zoning in orthopyroxene and incipient destabilization of amphibole are consistent with small degrees of heating. Our work articulates a clear direction for future Quizapu studies, which are warranted given the active nature of the Cerro Azul-Descabezado Grande volcanic axis.

Ophiolitic peridotites in Xigaze (Tibet): Constraints on modes of melt transport in the mantle

<p>The Xigaze ophiolite (Tibet), which occurs in the central segment of the Yarlung Zangbo Suture Zone, exposes a complete portion of a mantle sequence that consists essentially of fresh as well as serpentinized peridotites. We studied a sequence beneath the crustal section that exposes fresh, Cpx-bearing harzburgites and dunites that are underlain by serpentinized Cpx-bearing harzburgites and dunites. The rocks at the bottom are crosscut by dykes that have undergone different degrees of rodingitization. The modal compositions of peridotite from both fresh and serpentinized sections plot in abyssal upper mantle fields, with clinopyroxene modes less than 5 vol. %. Although harzburgites and dunites indicate that melt has been lost relative to primitive mantle compositions, the trace element patterns carry signatures of enrichment in incompatible elements, such as (i) “bowl-shaped” patterns of trace elements in silicate-Earth normalized spider diagrams, (ii) positive anomalies in highly incompatible trace elements such as Rb, Th, U, Ta, and (iii) enrichment of LREE in the clinopyroxenes from dunites and harzburgites. These features are indicative of complex melt transfer processes and cannot be produced by simple melt extraction. Petrographic studies reveal that harzburgite and dunite contain interstitial polyphase aggregates of olivine + Cpx + spinel + Opx and olivine + Cpx + Spinel, respectively. Experimental studies (e.g. Morgan and Liang, 2003) suggest that these aggregates represent frozen melt-rich components, indicating that fertile melt was percolating through the depleted harzburgite – dunite matrix. Presence of such “melt pods” would explain the trace element enrichment patterns of the bulk rock, as well as features such as reverse zoning (core: Cr, Fe<sup>2+</sup> rich, rim: Al, Mg rich) of spinels in polyphase aggregates in fresh dunites. These results show that melt extraction from the mantle is not a single stage process, and that evidence of multiple melt pulses that propagated through a rock are preserved in the petrographic features as well as in the form of chemical signatures that indicate refertilization of initially depleted rocks.</p>

A System Dynamics Approach to Understanding the deep Magma Plumbing System Beneath Dominica (Lesser Antilles)

To understand the dynamics of magmatic systems, one must first seek to characterize the time-dependent behavior of magma storage and ascent. Herein, we do this through a combination of the Crystal System Approach and careful study of Fe-Mg interdiffusion in orthopyroxene. This allows us to trace the pre-eruptive dynamics of magma plumbing systems, both in space and time. We apply this novel approach on two large silicic eruptions (about 3–5 km3 DRE/eruption) that occurred in the central part of Dominica Island (Lesser Antilles Arc): the eruptions of Layou (∼51 ka) from Morne Diablotins, and Roseau (∼33 ka) from Morne Trois Pitons-Micotrin. For the Roseau eruption, two magmatic environments (MEs) are identified on the basis of orthopyroxene composition, with a dominant reverse-zoning pattern from 50 to 54 to 54–59 mol% enstatite (En), indicating interaction with hotter magma. For the Layou eruption, three MEs are observed as represented by three populations of pyroxenes: En47-51, En51-53 and En53-58. The normal-zoning pathway from En51-53 to En47-51 is significantly registered by crystals, interpreted as convective mixing in a zoned reservoir. The reverse-zoning pathway from En47-51 to En51-53 and also En53-58 is also significantly present, supporting the mixing within the zoned reservoir but also suggesting mixing with a hotter magma, possibly stored in another part of a sub-volcanic mush. The crystal and glass compositions (melt inclusion and matrix glass) from both studied eruptions suggest heating and mixing between different magma pockets located within the mush that were the dominant process for mobilizing eruptible magma. In parallel, we constrain the associated pre-eruptive timescales by modeling the diffusive relaxation of Fe-Mg chemical gradients that originated within the zonation of the same orthopyroxene crystals. Diffusion modeling was considered along the b-axis of 66 zoned orthopyroxene crystals for these two eruptions, at a magmatic temperature of 850 ± 25°C. In light of these results, we propose that the Layou and the Roseau magma reservoirs were rejuvenated and heated by ∼25–50°C about 10 years prior to eruption by the injection of an underplating, hotter magma, creating the observed dominant reverse-zoning patterns of the erupted orthopyroxenes. We thus have evidence that silicic mush can be re-mobilized over timescales of decades prior to eruption, as previously suggested for Santorini and Taupo volcanoes.

Rapid assembly of high-Mg andesites and dacites by magma mixing at a continental arc stratovolcano

Studies of pre-eruptive processes at active volcanoes require precise petrochronological constraints if they are to contribute to hazard assessment during future eruption events. We present petrological and geochemical data and orthopyroxene diffusion time scales for samples from Late Pleistocene high-Mg andesite-dacite lavas (Mg# 53–69) at Ruapehu volcano, New Zealand, as a case study of rapid magma genesis and eruption at a continental arc stratovolcano. Assembly of Ruapehu high-Mg magmas involved the mixing of primitive magmas plus entrained mantle-equilibrated olivines with mid-crustal felsic mush bodies, yielding hybridized magmas with ubiquitous pyroxene reverse-zoning patterns. Orthopyroxene Fe-Mg interdiffusion time scales linked to quantitative crystal orientation data show that most lavas erupted <10 days after resumption of crystal growth following magma mixing events. The eruption of lavas within days of mixing events implies that pre-eruptive warnings may be correspondingly short.

Differentiation in Sheared Granular Magma

<p>Recent developments in high definition mineral chemistry at the grain scale are shedding new light on the processes and rates of magma storage, differentiation and eruption. However, the complementary physics and fluid dynamics of magma as a granular material are still based on viscous compaction theory, which may not be relevant in sub-volcanic settings where magma is being deformed by external shear. We present a quantitative model for shear deformation of a crystallised dense magma (>70% solid) with poro-elastic properties where the critical link between the mechanics and associated compositional changes in the melt are governed by dilation (volume increase) of the granular skeleton. Key material parameters governing the dilatancy effect include magma permeability, mush strength, the shear modulus and the contact mechanics and geometry of the granular assemblage. Calculations show that dilation reduces the interstitial fluid (melt) pressure to produce a ‘suction’ effect. At shear strain rates in excess of the tectonic background, deformation-induced melt flow can redistribute chemical components and heat between regions of crystallising magma with contrasting rheological properties, at velocities far in excess of diffusion or buoyancy forces, the latter of course the driving force behind fractional crystallisation and compaction. Unlike static magmas, there is no ‘lock-up’ state above which the interstitial melt cannot percolate. Co-mingling of hotter, indigenous melt has the potential to interrupt (or locally reverse) fractionation trends and produce reverse zoning or resorbtion of crystals, mimicking some of the textural effects attributed to magma mixing. Post-failure instabilities include hydraulic rupture of the mush along shear zones with potential for larger scale extraction and redistribution of evolved melt. A novel feature of congested, sub-volcanic granular magma is that the eruption itself helps drive rapid melt extraction, negating the requirement to first segregate large volumes of evolved melt as a precursor. </p>

Petrology of Gameleira potassic lamprophyres, São Francisco Craton

Gameleira lamprophyres are dykes and mafic microgranular enclaves associated with the shoshonitic Gameleira monzonite. This association belongs to the Paleoproterozoic alkaline magmatism from Serrinha nucleus, northeast Brazil. The liquidus paragenesis is diopside, pargasite, apatite and mica. Reverse zoning was identified in the groundmass alkali feldspar and was related to the undercooling of lamprophyric magma during the emplacement, with high growth rate of pargasite/edenite inducing disequilibrium between feldspars and liquid. Chemical data indicate that the lamprophyres are basic rocks (SiO2 < 48 wt%), with alkaline character (Na2O + K2O > 3 wt%) and potassic signature (K2O/Na2O ≈ 2). High contents of MgO and Cr are consistent with a signature of a primary liquid, and such concentrations, as well as Al, K, P, Ba, Ni- and light rare earth elements, are consistent with an olivine-free metasomatic mantle source enriched in amphibole, clinopyroxene and apatite. By contrast, the ultrapotassic lamprophyres from Morro do Afonso, contemporaneous alkaline ultrapotassic magmatism in Serrinha nucleus, were probably produced by melting of a clinopyroxene-phlogopite-apatite enriched-source. The identification of different mineral paragenesis in the source of potassic and ultrapotassic lamprophyres from Serrinha nucleus can contribute to the understanding of the mantle heterogeneities and tectonic evolution of this region.

Hybrid magma generation preceding Plinian silicic eruptions at Hekla, Iceland: evidence from mineralogy and chemistry of two zoned deposits

Hekla is a Holocene volcanic ridge in southern Iceland, which is notable for the link between repose periods and the composition of the first-erupted magma. The two largest explosive silicic eruptions, H4 and H3, erupted about 4200 and 3000 years ago. Airfall deposits from these eruptions were sampled in detail and analysed for major and trace elements, along with microprobe analyses of minerals and glasses. Both deposits show compositional variation ranging from 72 % to 56 % SiO2, with mineralogical evidence of equilibrium crystallization in the early erupted rhyolitic component but disequilibrium in the later erupted basaltic andesite component. The eruptions started with production of rhyolitic magma followed by dacitic to basaltic andesite magma. Sparse crystallization of the intermediate magma and predominant reverse zoning of minerals, trending towards a common surface composition, indicate magma mixing between rhyolite and a basaltic andesite end-member. The suggested model involves partial melting of older tholeiitic crust to produce silicic magma, which segregated and accumulated in deep crustal reservoir. Silicic magma eruption is triggered by basaltic andesite dyke injection, with a proportion of the dyke magma contributing to the production and eruption of a mixed hybrid magma. Both the volume of the silicic partial melt, and the proportion of the hybrid magma depend on the pre-eruptive repose time.