Guest induced reversible on–off switching of elastic frustration in a 3D spin crossover coordination polymer with room temperature hysteretic behaviour

Reversible switch between a robust bistable two-state room temperature spin crossover (SCO) and its transformation in a four-stepped elastically frustrated SCO due to guest inclusion in a metal–organic Hofmann framework.

Experimental Research on the Hysteretic Behaviour of Pressurized Artificial Muscles Made from Elastomers with Aramid Fibre Insertions

Inherent hysteresis behaviour of pressurized artificial muscles is complicated to understand and handle, calling for experimental research that allows the modelling of this phenomenon. The paper presents the results of the experimental study of the hysteretic behaviour of a small-size pneumatic muscle. The specific hysteresis loops were revealed by isotonic and isometric tests. Starting from hypothesis according to that the tube used for the pneumatic muscle is made entirely of aramid fibres enveloped by an elastomer material that merely ensures their airtightness, the paper presents the hysteresis curves that describe the radial and axial dimensional modifications as well as the variation of the developed forces for different feed pressures. The obtained third-degree polynomial equations underlie the configuration of high-performance positioning systems.

Effect of Porosity on Functional Properties of Lead-Free Piezoelectric BaZr0.15Ti0.85O3 Porous Ceramics

The present paper reports the dependence of dielectric, ferroelectric and piezoelectric properties on the porosity level in BaZr0.15Ti0.85O3 ceramics with porosity from 5% to 21%. Microporosity with 0–3 connectivity has been produced using PMMA microspheres as a sacrificial template. The functional properties (dielectric, ferroelectric and piezoelectric effect) are mostly affected by the “dilution effect”: permittivity decreases by 40% when porosity increases by 21%, and Pmax decreases from 13 to 5 µC/cm2 while the Prem is in the range of (2–8) µC/cm2. However, the reduction of the zero-field permittivity and hysteretic behaviour of ε(E) while the tunability level is still high makes from porous ceramics interesting materials for tunability application.