Real-space subfemtosecond imaging of quantum electronic coherences in molecules

Tracking electron motion in molecules is the key to understanding and controlling chemical transformations. Contemporary techniques in attosecond science are able to generate and trace the consequences of this motion in real time, but not in real space. Scanning tunnelling microscopy, on the other hand, can locally probe the valence electron density in molecules, but cannot alone provide dynamical information at this ultrafast timescale. Here we show that, by combining scanning tunnelling microscopy and attosecond technologies, quantum electronic coherences induced in molecules by <6-fs-long carrier-envelope-phase-stable near-infrared laser pulses can be directly visualized at ångström-scale spatial and subfemtosecond temporal resolutions. We demonstrate concurrent real-space and -time imaging of coherences involving the valence orbitals of perylenetetracarboxylic dianhydride molecules, and full control over the population of the involved orbitals. This approach opens the way to the unambiguous observation and manipulation of electron dynamics in complex molecular systems.

Germanium Quantum-Dot Array with Self-Aligned Electrodes for Quantum Electronic Devices

Semiconductor-based quantum registers require scalable quantum-dots (QDs) to be accurately located in close proximity to and independently addressable by external electrodes. Si-based QD qubits have been realized in various lithographically-defined Si/SiGe heterostructures and validated only for milli-Kelvin temperature operation. QD qubits have recently been explored in germanium (Ge) materials systems that are envisaged to operate at higher temperatures, relax lithographic-fabrication requirements, and scale up to large quantum systems. We report the unique scalability and tunability of Ge spherical-shaped QDs that are controllably located, closely coupled between each another, and self-aligned with control electrodes, using a coordinated combination of lithographic patterning and self-assembled growth. The core experimental design is based on the thermal oxidation of poly-SiGe spacer islands located at each sidewall corner or included-angle location of Si3N4/Si-ridges with specially designed fanout structures. Multiple Ge QDs with good tunability in QD sizes and self-aligned electrodes were controllably achieved. Spherical-shaped Ge QDs are closely coupled to each other via coupling barriers of Si3N4 spacer layers/c-Si that are electrically tunable via self-aligned poly-Si or polycide electrodes. Our ability to place size-tunable spherical Ge QDs at any desired location, therefore, offers a large parameter space within which to design novel quantum electronic devices.

Substantiation of requirements and ways of their realization at synthesis of proof-stable perspective electronic signatures

The paper identifies and substantiates the requirements and ways to implement these requirements at the synthesis of proof-stable perspective electronic signatures. Today there is a problem of building post-quantum electronic signatures. At the stages of solving this problem, a wide range of requirements for technical, technical-economical and other capabilities is formed. At the national and international levels, in the most generalized form, these requirements are implemented at the NIST USA level during the NIST PQC competition for electronic signatures, asymmetric ciphers and key encapsulation protocols. In Ukraine, work is also underway to synthesize such post-quantum cryptotransformations. Requirements in these areas are justified and approved at the state level. The peculiarity of the national requirements is that the requirements for protection against special quantum attacks and attacks through side channels have been significantly increased.

Quantum attack against post-quantum electronic signature complexity and implementation probability analysis

The paper identifies and analyzes attacks aimed at Rainbow post-quantum electronic signature cryptanalysis. Today, due to advances in the quantum computers development, the need to present new standards for electronic signatures resistant to both quantum and classical cryptanalysis arisen. To solve the lack of such electronic signatures, NIST USA is running the NIST PQC competition. As part of this competition some electronic signatures designed to resist quantum cryptanalysis were presented, including Rainbow electronic signature. CZ-Rainbow and the compressed Rainbow algorithm were also presented along with the regular Rainbow algorithm. This paper analysis attacks on all three types of electronic signature. The possibility of a quantum attack against the Rainbow electronic signature, as well as the complexity of such an attack, defines the possibility of this electronic signature usage during the post-quantum period.

Asymmetric Synthesis of Tetrahydroisoquinoline Derivatives through 1,3-Dipolar Cycloaddition of C,N-Cyclic Azomethine Imines with Allyl Alkyl Ketones

[3 + 2] A 1,3-Dipolar cycloaddition of C,N-cyclic azomethine imines with allyl alkyl ketones has been achieved. The reaction proceeds under mild conditions and tolerates a wide range of functional groups. An array of tetrahydroisoquinoline derivatives is generally constructed with good diastereoselectivities and enantioselectivities (up to >25:1 dr, >95% ee). Moreover, the absolute configuration of the product was previously determined by using the quantum electronic circular dichroism calculation and ECD spectrum method.

Definitions and Security of Quantum Electronic Voting

Recent advances indicate that quantum computers will soon be reality. Motivated by this ever more realistic threat for existing classical cryptographic protocols, researchers have developed several schemes to resist “quantum attacks.” In particular, for electronic voting (e-voting), several schemes relying on properties of quantum mechanics have been proposed. However, each of these proposals comes with a different and often not well-articulated corruption model, has different objectives, and is accompanied by security claims that are never formalized and are at best justified only against specific attacks. To address this, we propose the first formal security definitions for quantum e-voting protocols. With these at hand, we systematize and evaluate the security of previously proposed quantum e-voting protocols; we examine the claims of these works concerning privacy, correctness, and verifiability, and if they are correctly attributed to the proposed protocols. In all non-trivial cases, we identify specific quantum attacks that violate these properties. We argue that the cause of these failures lies in the absence of formal security models and references to the existing cryptographic literature.