Material Flux through an Innovative Recycling Process Treating Different Types of End-of-Life Photovoltaic Panels: Demonstration at Pilot Scale

A quantitative assessment of the material flux emerging from a pilot plant for the treatment of end-of-life photovoltaic panel waste was reported. The process included the manual dismantling of aluminum frames, mechanical treatment for size reduction, and the physical treatment of the milled materials for the release of coarse glass from the encapsulant polymer. Demonstration activities were performed using 1 ton of Si-, 1 ton of CdTe-, and 1 ton of CIGS-based photovoltaic panels (investigated separately), confirming the ability of the process to treat different photovoltaic technologies. The characterization of the input materials was performed and compared with previous literature data. The major bottleneck in the definition of an effective process option for the treatment of different panel technologies was emphasized by the high heterogeneity reported. Mass balances for the proposed process were derived by the recovered material flow. It was highlighted that in processes based on mechanical treatments, producing predominantly coarse fractions allows for the facile separation of most of the valuable components. In this perspective, the present work offers further insights into the design of recycling process to reach increased profitability/sustainability, especially considering the distributions of valuable metals in the process products.

Fe induced a dynamic and biased allocation of material flux within terpenoid metabolism is controlled by CbNudix in Conyza blinii

Conyza Blinii (C. blinii) is a unique traditional Chinese medicine growing in Sichuan, China, which has soils with an abundant iron content. This Fe enrichment environment contributed to a variety of terpenoids of C. blinii, blinin and saponin which can play an important role in the process of resisting abiotic stress. The relationship between Fe and terpenoid metabolism was studied to explore Fe tolerance mechanism of C. blinii. In this study, C. blinii was treated with ferrous iron solutions, and the effect of ferrous iron on the synthesis of blinin and saponins was further studied by spectrophotometry and liquid chromatography. Also, gene expression was detected by qRT-PCR. Under ferrous treatment, the blinin content of C. blinii increased, while the total saponin content decreased. When the ferrous concentration reached 200 μM, the difference in metabolite production was the largest. Furthermore, it was found that blinin and saponin have synchronous and opposite accumulation trends, accompanied by time dependence. The genes expression results of key enzyme in the MVA and MEP pathways showed the same trends. In this process, the expression of CbNudixs played a key role to switch the material flux between MVA and MEP, via catalyzed the dephosphorylation of isoprenoid diphosphate. This study explored the effect of ferrous iron on the saponin and blinin synthesis of C. blinii and found the unique role of CbNudixs in regulating material flux between diterpene and triterpene synthesis, which greatly deepened our understanding of the mechanism of Fe tolerance of C. blinii.

Heraclitus and Sonic Thinking

“The material Flux”; “the hidden mobility beneath”; “Sonic Logos.” Any classicist familiar with the fragments of Heraclitus would be surprised to find these concepts developed in today’s theories about sonic art from authors from different traditions such as Salomé Voegelin, Julian Henriques, Jean-Luc Nancy, and Christoph Cox. The present paper intends to open a dialogue between these authors and Heraclitus, claiming that there is an underlying connection beyond mere coincidence. Sonic thinking proposes listening as the way to access or produce a particular knowledge—one that would otherwise be too difficult or impossible to grasp. This knowledge is produced by practices such as listening and musical meditation instead of intellectual activity alone. To make the case, the authors will present a general outline of what sonic thinking entails to compare it with the relevant points in Heraclitus’s philosophy. The purpose of this paper is twofold: to provide a new sonic framework to read Heraclitus and to provide an old framework to read sonic thinking.

Lateral particle supply as a key vector in the oceanic carbon cycle

<p>Despite the potential importance in the oceanic carbon cycle and benthic ecosystem, global feature of lateral supply of aged organic matter hosted on lithogenic particles derived from sediment resuspension has not been systematically examined. We compiled concentrations and fluxes of lithogenic material in the ocean in a global-scale by using literature data of sediment trap studies to understand the contribution of resuspended sediment to sinking particulate matter. We find that these contributions are significant in various oceanic settings, particularly over continental margins. Lithogenic material flux decreased with increasing distance from the margins and above the seafloor. Examination of Δ<sup>14</sup>C values of sinking POC revealed strong relationships with parameters that represent contribution of resuspended sediment. We then derive estimates for the contribution of aged POC from sediment resuspension to sinking POC based on these relationships and global lithogenic material flux data.</p>

Comparative Examination of Nonequilibrium Thermodynamic Models of Thermodiffusion in Liquids

We analyze existing models for material transport in non-isothermal non-electrolyte liquid mixtures that utilize non-equilibrium thermodynamics. Many different sets of equations for material have been derived that, while based on the same fundamental expression of entropy production, utilize different terms of the temperature- and concentration-induced gradients in the chemical potential to express the material flux. We reason that only by establishing a system of transport equations that satisfies the following three requirements can we obtain a valid thermodynamic model of thermodiffusion based on entropy production, and understand the underlying physical mechanism: (1) Maintenance of mechanical equilibrium in a closed steady-state system, expressed by a form of the Gibbs–Duhem equation that accounts for all the relevant gradients in concentration, temperature, and pressure and respective thermodynamic forces; (2) thermodiffusion (thermophoresis) is zero in pure unbounded liquids (i.e., in the absence of wall effects); (3) invariance in the derived concentrations of components in a mixture, regardless of which concentration or material flux is considered to be the dependent versus independent variable in an overdetermined system of material transport equations. The analysis shows that thermodiffusion in liquids is based on the entropic mechanism.