Pilot-Scale Experimental Study on Impacts of Biomass Cofiring Methods to NOx Emission from Pulverized Coal Boilers—Part 2: NOx Reduction Capability through Reburning versus Cofiring

In this study the NOx reduction capability of reburning three biomasses (i.e., wood pellet, torrefied biomass, and empty fruit bunch) via 12 cases (i.e., four reburning ratios for every biomass) is investigated in a 1 MWth-scale pilot-scale furnace. These reburning cases are compared with 12 cofiring cases presented in the Part 1 paper on a consistent basis. It is found that, for every cost to purchase and prepare biomass, reburning technology provides significantly better NOx abatement performance than cofiring (up to 3.4 times). NOx reduction effectiveness as high as 4.9 could be achieved by reburning, which means the percent of NOx abatement could be 4.9 times higher than the percent of reburning ratio. It is found that the highest NOx reduction per thermal unit of biomass happens at the lowest reburning ratio, and increasing the reburning ratio leads to a reduction in NOx abatement effectiveness in an exponential decay manner. Unlike cofiring technology, reburning was found to have little dependence on the fuel characteristics, such as fuel ratio or fuel-N, when it comes to NOx abatement potential.

Non-catalytic NOx reduction for marine Diesel engine: an experimental approach

Recent legislation concerning air pollutant emissions from ships (Tier III) has considerably decreased NOx emission limits for recreational ships with less than 500 gross tonnages and greater than 24 m load line length (LLL), the so-called “large yachts”. For these yachts, which adopt multiple Diesel engines with maximum power ranging from 800 to 2000 kW, the new NOx limit is less than 2 g/kWh. To satisfy that limit, engine makers suggest the adoption of a classic SCR system with urea injection but this methodology, in addition to requiring a large space for installation, does not seem so appropriate for diesel engines of large yachts that normally operate at low power with exhaust temperatures often well below 300 °C, therefore not sufficient to allow the correct functioning of the SCR. The aforementioned circumstances have prompted Sanlorenzo Spa (La Spezia – Italy), one of the world’s leading companies in the production of pleasure boats, to collaborate with the University of Pisa in the study of alternative solutions to SCR systems. Recently there is a great interest in innovative NOx abatement systems, based on the possibility of absorbing NOx molecules into seawater through the utilization of appropriate aqueous solutions containing targeted saline oxidizing agents. The present study describes the first results of a research program aimed to identify, from one side, the best saline oxidizing agent for an aqueous NOx abatement and, from the other, the best washing methodology compatible with the propulsion layouts usually adopted on yachts. In the engine testing laboratories of the Department of Energy, Systems, Territory and Construction Engineering (DESTeC) of the University of Pisa, an experimental apparatus has been created to reproduce the real conditions of underwater engine exhausting. This device was combined with a small 1.2 L direct injection diesel engine. The first results showed a reduction of the NOx emissions of about 27% by using a gas washing with wet scrubber, followed by bubbling in water, using 0.2 molar NaClO saline solutions.