Abstract
Valvasor's library is a unique example of a 17th-century personal library, which also includes over 7.300 prints. Today, it is part of the Metropolitan Library of the Archdiocese of Zagreb. In this study, the 17th-century papers in Valvasor's collection of unknown origin and composition were analysed. In order to determine the composition of these papers, a dual approach was used, by combining results obtained by non-destructive and destructive analyses from two sets of samples. On 144 paper sheets from Valvasor’s collection only non-destructive analyses were performed, whereas both, non-destructive and destructive analyses were performed on the second set of samples, 10 historical paper fragments, dating from 16th to 19th centuries. Among non-destructive analyses, surface imaging, measurements of thickness, surface pH and optical properties (brightness, yellowness, opacity, and gloss) of papers were carried out. Optical properties characterized the samples as yellowish, opaque papers without gloss. Destructive analyses performed on the historical paper fragments went deeper into their composition and properties. Initially, spot tests were performed to determine absorbency, an identify lignin and starch in paper samples. Of the elementary analyses, SEM-EDS and XRF analyses for the identification of inorganic elements and FTIR analysis to identify chemical bonds in fibers, fillers, and sizes were applied. Microscopic analyses were performed in two ways - the paper surface was imaged with a digital microscope and the morphological characteristics of the fibers were studied using an optical microscope. Different fibers and components were discovered in fragments of historical papers, thus confirming their presence in handmade paper over four centuries. The dominant fibers were flax and hemp, with a smaller proportion of cotton. Also, thick and thin light brown fibers resembling straw were observed. The presence of calcium containing components, probably calcium carbonate as filler, gelatin and alumn could be confirmed. Relating the composition of historical papers with surface pH and optical properties of papers enabled us to predict the composition of 17th-century papers in Valvasor's collection.