An experiment was conducted on densification processing of sorghum straw stalks with self-made steel molds on a hydraulic universal test platform. The influences of different densification conditions on physical quality of briquette fuel are investigated, including pressures, temperatures, moisture contents and straw preheating method. Moreover, the relationship between molding temperature and inner stress decreasing rate of straw briquette at holding pressure stage is also analyzed. The result shows that the suitable value of moisture content, temperature and molding pressure for straw compression process is 20%, 90°C and at least 50MPa, respectively. The phenomenon of uneven temperature distribution in straw briquette keeps in existence even in the case of microwave preheating. However, in contrast with the very low central temperature in straw briquette when preheating by electric heater wire, the phenomenon of local overheating caused by microwave preheating may be helpful to straw molding process.