Revisiting the Meandering Instability During Step-Flow Epitaxy

This paper starts with a generalized Burton, Cabrera and Frank (BCF) model by considering the energetic contribution of the adjacent terraces to the step chemical potential. We use the linear stability analysis of the quasistatic free-boundary problem for a two-dimensional step separated by broad terraces to study the step-meandering instabilities. The results show that the equilibrium adatom coverage has influence on the morphological instabilities.

An ethyl methyl sulfone co-solvent eliminates macroscopic morphological instabilities of lithium metal anode

A lithium metal anode suffers from a short cycle life, and the parasitic reactions of lithium with electrolytes are widely observed.

Stabilizing electrodeposition in elastic solid electrolytes containing immobilized anions

Ion transport–driven instabilities in electrodeposition of metals that lead to morphological instabilities and dendrites are receiving renewed attention because mitigation strategies are needed for improving rechargeability and safety of lithium batteries. The growth rate of these morphological instabilities can be slowed by immobilizing a fraction of anions within the electrolyte to reduce the electric field at the metal electrode. We analyze the role of elastic deformation of the solid electrolyte with immobilized anions and present theory combining the roles of separator elasticity and modified transport to evaluate the factors affecting the stability of planar deposition over a wide range of current densities. We find that stable electrodeposition can be easily achieved even at relatively high current densities in electrolytes/separators with moderate polymer-like mechanical moduli, provided a small fraction of anions are immobilized in the separator.