The growth of crystalline Si (c-Si) via direct electron beam writing shows promise for fabricating Si nanomaterials due to its ultrahigh resolution. However, to increase the writing speed is a major obstacle, due to the lack of systematic experimental explorations of the growth process and mechanisms. This paper reports a systematic experimental investigation of the beam-induced formation of c-Si nanoparticles (NPs) from amorphous SiO2 under a range of doses and temperatures by in situ transmission electron microscopy at the atomic scale. A three-orders-of-magnitude writing speed-up is identified under 80 keV irradiation at 600°C compared with 300 keV irradiation at room temperature. Detailed analysis reveals that the self-organization of c-Si NPs is driven by reduction of c-Si effective free energy under electron irradiation. This study provides new insights into the formation mechanisms of c-Si NPs during direct electron beam writing and suggests methods to improve the writing speed.
p+ polycrystalline silicon growth via hot wire chemical vapour deposition for silicon solar cells