Tunable Low Crystallinity Carbon Nanotubes/Silicon Schottky Junction Arrays and Their Potential Application for Gas Sensing

Highly ordered nanostructure arrays have attracted wide attention due to their wide range of applicability, particularly in fabricating devices containing scalable and controllable junctions. In this work, highly ordered carbon nanotube (CNT) arrays grown directly on Si substrates were fabricated, and their electronic transport properties as a function of wall thickness were explored. The CNTs were synthesized by chemical vapor deposition inside porous alumina membranes, previously fabricated on n-type Si substrates. The morphology of the CNTs, controlled by the synthesis parameters, was characterized by electron microscopies and Raman spectroscopy, revealing that CNTs exhibit low crystallinity (LC). A study of conductance as a function of temperature indicated that the dominant electric transport mechanism is the 3D variable range hopping. The electrical transport explored by I-V curves was approached by an equivalent circuit based on a Schottky diode and resistances related to the morphology of the nanotubes. These junction arrays can be applied in several fields, particularly in this work we explored their performance in gas sensing mode and found a fast and reliable resistive response at room temperature in devices containing LC-CNTs with wall thickness between 0.4 nm and 1.1 nm.

Description of zero field steps on the potential energy surface of a Frenkel-Kontorova model for annular Josephson junction arrays

We explain the emergence of zero field steps (ZFS) in a Frenkel-Kontorova (FK) model for a 1D annular chain being a model for an annular Josephson junction array. We demonstrate such steps for a case with a chain of 10 phase differences. We necessarily need the periodic boundary conditions. We propose a mechanism for the jump from M fluxons to $$M+1$$ M + 1 in the chain. Graphic abstract

Charge quantization and detector resolution

Charge quantization, or the absence thereof, is a central theme in quantum circuit theory, with dramatic consequences for the predicted circuit dynamics. Very recently, the question of whether or not charge should actually be described as quantized has enjoyed renewed widespread interest, with however seemingly contradictory propositions. Here, we intend to reconcile these different approaches, by arguing that ultimately, charge quantization is not an intrinsic system property, but instead depends on the spatial resolution of the charge detector. We show that the latter can be directly probed by unique geometric signatures in the correlations of the supercurrent. We illustrate these findings at the example of Josephson junction arrays in the superinductor regime, where the transported charge appears to be continuous. Finally, we comment on potential consequences of charge quantization beyond superconducting circuits.