⁴⁰Ar/³⁹Ar dating of a hydrothermal pegmatitic buddingtonite–muscovite assemblage from Volyn, Ukraine

We determined 40Ar/39Ar ages of buddingtonite, occurring together with muscovite, with the laser-ablation method. This is the first attempt to date the NH4-feldspar buddingtonite, which is typical for sedimentary–diagenetic environments of sediments, rich in organic matter, or in hydrothermal environments, associated with volcanic geyser systems. The sample is a hydrothermal breccia, coming from the Paleoproterozoic pegmatite field of the Korosten Plutonic Complex, Volyn, Ukraine. A detailed characterization by optical methods, electron microprobe analyses, backscattered electron imaging, and IR analyses showed that the buddingtonite consists of euhedral-appearing platy crystals of tens of micrometers wide, 100 or more micrometers in length, which consist of fine-grained fibers of ≤ 1 µm thickness. The crystals are sector and growth zoned in terms of K–NH4–H3O content. The content of K allows for an age determination with the 40Ar/39Ar method, as well as in the accompanying muscovite, intimately intergrown with the buddingtonite. The determinations on muscovite yielded an age of 1491 ± 9 Ma, interpreted as the hydrothermal event forming the breccia. However, buddingtonite apparent ages yielded a range of 563 ± 14 Ma down to 383 ± 12 Ma, which are interpreted as reset ages due to Ar loss of the fibrous buddingtonite crystals during later heating. We conclude that buddingtonite is suited for 40Ar/39Ar age determinations as a supplementary method, together with other methods and minerals; however, it requires a detailed mineralogical characterization, and the ages will likely represent minimum ages.

Geochronology of granites of the western Korosten AMCG complex (Ukrainian Shield): implications for the emplacement history and origin of miarolitic pegmatites

The origin of large miarolitic (also known as “chamber”) pegmatites is not fully understood although they may have great economic value. The formation of cavities in magmatic bodies is related to melt degassing and gas or fluid flow through partially solidified magma. In this paper, the origin of the Volyn pegmatite field, located in the Palaeoproterozoic Korosten anorthosite–mangerite–charnockite–granite (AMCG) complex, North-Western region of the Ukrainian Shield, is discussed. Pegmatites of the field host deposits of piezoelectric quartz that is accompanied by gem-quality beryl and topaz. The Volyn pegmatite field is confined to granites located in the south-western part of the Korosten complex and extends for 22 km along the contact with the anorthosite massif within the Korosten plutonic complex. Geological data indicate hybridization of basic melts and partly crystallized granites, as well as direct impact of fluids derived from basic melts on the chamber pegmatites. The new U–Pb zircon ages obtained for granites and pegmatites of the Korosten complex confirm that the rock assemblage in the northern part of the complex crystallized between 1800 and 1780 Ma, whereas rocks in the southern part intruded mainly between 1768 and 1755 Ma. U–Pb zircon ages for granites from the south-western part of the Korosten complex indicate that granites were emplaced at 1770–1765 Ma, a few million years prior to the intrusion of the gabbro–anorthosite massif (1762–1758 Ma), while chamber pegmatites in these granites crystallized at 1760 ± 3 Ma, coevally with the basic rocks. Ultimately, the formation of the chamber pegmatites was related to the reheating of the semi-crystallized granitic intrusion and to fluids migrating from the underlying gabbro–anorthosite massif.

Genesis of trondhjemite by low-pressure low-melt fraction anatexis of hornblende-gabbro at Alvand Plutonic Complex (Hamedan, NW Iran): insights from geochemical modelling

Amphibole-dominated dehydration melting of gabbro is the primary process responsible for the genesis of adakites, low-K tonalites, modern trondhjemites, and plagiogranites as well as Archean tonalite-trondhjemite-granodiorite suites that represent the earliest examples of continental crust. Previous literature has mostly focused on the role of Al-rich amphibole during anatexis of a mafic source and many of these studies have investigated this process through experimental melting runs. However, due to experimental boundary conditions, little is known about partial melting of amphibole-bearing mafic rock at temperatures < 800°C for upper crustal conditions (pressure < 500 MPa). Classic and forward thermobarometric modelling suggests that in situ trondhjemite leucosomes, hosted by Cheshmeh-Ghasaban mafic metatexites (Alvand Plutonic Complex, Hamedan, NW Iran), represent a rare natural case study of a low-temperature incipient amphibole-dominated anatectic event of a mafic source with a primary assemblage (Pl+Hbl+Cpx+Bt+Opx) typical of a hornblende-bearing gabbroic rock.