Strontium and oxygen isotopes to trace mobility routes during the Bell Beaker period in the north of Spain

Strontium and oxygen isotopes of individuals from El Hundido and Valdescusa (north of Spain) sites, corresponding to the Bell Beaker culture, were analysed in order to determine mobility patterns and provenance areas. Strontium and oxygen isotope ratios in three teeth from two individuals at El Hundido and two teeth from the five individuals at Valdescusa were studied. The analyses were performed in both dentine and enamel fractions. 87Sr/86Sr ratios of El Hundido individuals indicate one was of foreign origin and the other was local whereas at Valdescusa were all of foreign provenance. Calculated δ18Ow values of El Hundido suggest a provenance from the geographical area close to the site while the Valdescusa would come from a warmer region. The comparison of oxygen and strontium isotope signatures indicate the west of the Iberian Peninsula (Zamora or the east of Leon regions) as the provenance area for the foreign individual at El Hundido and southwest France (Garonne basin) as the region of provenance for the Valdescusa.

The Historic Centre of Urbino, UNESCO World Heritage (Marche Region, Italy): an Urban-Geological Itinerary Across the Building and Ornamental Stones

The local and extra-regional (national and transnational) stones mainly used as building and ornamental materials in the historic centre of Urbino (UNESCO World Heritage List) were unravelled through a detailed geological and petrographic study. The types of building stones used in the past for the development of an urban centre were mostly affected by the availability of suitable geomaterials in the surrounding areas. For this reason, the stones found in the historical buildings of Urbino generally come from the local sedimentary formations (mostly limestones) belonging to the Umbria–Marche–Romagna Succession Auct., which crops out in the Northern Marche Apennines. Only some ornamental highly prized stones used for monuments and decorations come from both extra-regional Italian areas (Alps, other sectors of the Northern Apennines) and foreign countries (France, Egypt). A brief description of the Northern Marche geology was also reported to exactly match the local provenance of the stones, so highlighting the relationship between the territory and the architecture of Urbino. Because of obvious conservation reasons, no samples were collected from buildings or monuments and only autoptic observations, together with a detailed historical and bibliographic research, were carried out to identify the different materials and the provenance areas. Besides the availability of the local sedimentary rocks, we emphasised how the choice of the building and ornamental stones could have been also influenced by the historic period and artistic style, aesthetic features, economic and social importance of the building and/or monument and the relationship to some distinguished personality (e.g., Pope Clemente XI). An open-air stone itinerary across significant places (10 stops and additional sites and monuments in the urban area) is finally proposed for the best fruition of the geological and cultural heritage of Urbino, also aimed at geotourism development.

A tectonic carpet of Variscan flysch at the base of a rootless accretionary prism in northwestern Iberia: U–Pb zircon age constrains from sediments and volcanic olistoliths

The allochthonous complexes of Galicia–Trás-os-Montes Zone (NW Iberia) are part of a rootless tectonic stack which preserves part of a Variscan accretionary prism. They are formed by individual tectonic slices marked by specific tectonometamorphic evolutions, which were piled up in a piggy-back mode onto its relative autochthon, the Central Iberian Zone (CIZ). Allochthony decreases from the structurally upper thrust sheets towards the lower ones. The lowermost unit of the stack is known as the Parautochthon or Schistose Domain. It is characterized by a low metamorphic grade in contrast with higher temperatures and/or pressures estimated for the overlying allochthonous units and shares the stratigraphic sequence with the underlying autochthon. The Parautochthon is divided in two structural and stratigraphic sub-units: (i) the Lower Parautochthon (LPa) is made of synorogenic flysch-type sediments with varied turbiditic units and olistostrome bodies, showing Upper Devonian–lower Carboniferous age according to the youngest zircon populations and fossiliferous content; (ii) the Upper Parautochthon (UPa) is composed of highly deformed preorogenic upper Cambrian–Silurian volcano-sedimentary sequence comparable with the nearby autochthon and to some extent, also with the high-P and low-T Lower Allochthon laying structurally above. The UPa was emplaced onto the LPa along the Main-Trás-os-Montes Thrust, and the LPa became detached from the CIZ relative autochthon by a regional-scale structure, the Basal Lower Parautochthon Detachment, which follows a weak horizon of Silurian carbonaceous slates. A review on the detrital zircon studies on the synorogenic LPa complemented by zircon dating of 17 new samples is presented here. The results support the extension of the LPa underneath the NW Iberian allochthonous complexes, from Cabo Ortegal, to Bragança and Morais massifs. Its current exposure follows the lowermost tectonic boundary between the Galicia–Trás-os-Montes (allochthon) and Central Iberian (autochthon) zones. The youngest zircon age populations point to a maximum sedimentation age for the LPa formations ranging from Famennian to Serpukhovian and supports the piggy-back mode of emplacement of the Galicia–Trás-os-Montes Zone, of which it represents the latest imbricate. The zircon age populations in the LPa allow the sedimentary provenance areas to be constrained, showing the intervention of nearby sources (mostly the UPa) and/or multiply recycled and long-transport sediments with a typically north-central Gondwana age fingerprint, also found in the Lower Allochthon, UPa and Autochthon. Complementary geochronology of volcanic olistoliths trapped in the LPa sediments and of late Cambrian to Upper Ordovician rhyolites from the UPa is also presented. It shows a direct relationship between the major blocks source area (UPa) and the setting place (LPa). Old zircon age patterns show that the LPa sedimentary rocks were recycled from detrital rocks of the allochthon (advancing wedge) and the nearby autochthon (peripheral bulge).

A tectonic carpet of Variscan flysch at the base of an unrooted accretion prism in NW Iberia: U-Pb zircon age constrains from sediments and volcanic olistoliths

The allochthonous complexes of Galicia – Trás-os-Montes Zone (NW Iberia) are part of the tectonic stack that unrooted the Variscan accretionary prism. They are formed by individual tectonic slices marked by specific tectono-metamorphic evolution, which was piled up in a piggy-back thrust complex onto its relative autochthon, the Central Iberian Zone (CIZ). Consequently, allochthony decreases towards lower, more external and younger thrust sheets. The lowermost unit of this pile of slivers is known as Schistose Domain or Parautochthon and bears low metamorphic grade, contrasting with the higher temperatures and pressures estimated for the upper allochthonous units, but sharing the stratigraphic sequence with the underlying autochthon. The Parautochthon is divided in two structural and stratigraphic sub-units: (i) the Lower (LPa) made of synorogenic flysch-type sediments with varied turbiditic units and olistostrome bodies, showing Upper Devonian-lower Carboniferous age on base of the youngest zircon populations and fossiliferous content; (ii) the Upper (UPa), composed of highly deformed pre-orogenic upper Cambrian-Silurian volcano-sedimentary sequence comparable with both the nearby autochthon and the HP-LT Lower Allochthon, laying structurally above. The UPa thrusted onto the LPa by the the Main-Trás-os-Montes Thrust; and the LPa detached from the CIZ relative autochthon by a regional structure (Basal Lower Parautochthon Detachment) which follows the favourable Silurian carbonaceous beds. A review on the detrital zircon studies of the synorogenic LPa complemented by 17 new samples geochronology is here presented. The results support the extension of the LPa underneath the NW Iberia allochthonous complexes, from Cabo Ortegal, to Bragança and Morais Massifs. Its current exposure follows the lowermost tectonic boundary between the Galicia – Trás-os-Montes (allochthon) and Central Iberian (autochthon) Zones. Youngest zircon age populations point to a maximum sedimentation age for the LPa formations ranging from Famennian to Serpukhovian and endorse the piggy-back evolution inside this unit, mimicking the general structure of the Galicia – Trás-os-Montes Zone. The zircon populations in the LPa allow constraining the sedimentary provenance areas, showing the intervention of nearby sources (mostly the UPa) and/or multiply recycled/long transport sediments with typically N-Central Gondwana age fingerprint, also found in the Lower Allochthon, UPa and Autochthon. Complementary geochronology of volcanic olistoliths trapped in the LPa sediments and of upper Cambrian to Upper Ordovician rhyolites from the UPa is also presented, showing a direct relation between the major block's source area (UPa) and the setting place (LPa). Old zircon age patterns show that the LPa sedimentary rocks were recycled from detrital rocks of the allochthon (advancing wedge) and the nearby autochthon (peripheral bulge).

Highly mature sediments in the tropical monsoonal environment of southwestern India: an appraisal based on weathering indices

Purpose This paper aims to examine the geochemical change experienced by laterites in Kerala, India, subjected to tropical monsoonal climate. These sediments are underlain by hard rock. The source rock characteristics have a major stake on the ultimate composition of sediments, as also the climatic conditions which an area experience. Design/methodology/approach Core samples have been obtained from several locations in a lateritic plateau. The upper portions of the borehole cores are composed of the lateritic hard cap, followed by lateritic soils. The soil samples were subjected to sediment texture analysis and XRF analysis (Bruker S4 Pioneer Sequential Wavelength-Dispersive XRF) for the determination of major elements ((in oxide form). Findings Major element geochemistry has revealed the following order of relative proportions of elements (in oxide form) SiO2 > Al2O3 > Fe2O3 > TiO2 >> Na2O > P2O5 > CaO > K2O > MgO > MnO. Even though the concentrations of SiO2, Al2O3 and Fe2O3 contribute 90% of major element chemistry, there is no significant correlation found for these elements within themselves or with others. Research limitations/implications Microscale movement of elements could not be characterised in this study. This requires access to an electron probe micro analyzer. Practical implications The practical implication of tropical weathering is that enhanced chemical leaching leads to movement of most elements out of the system, except for Al, leading to the possible formation of bauxite, or aluminous laterite. Social implications The weathered products in this study provide livelihood sustenance for many of the local households, through manual production of laterite bricks, which are used in construction. Originality/value The indices of the intensity of chemical alteration/weathering like chemical index of alteration (CIA), chemical index of weathering (CIW) and weathering index of parker (WIP) reveal that the sediments indicate intense weathering of the source area prior to being deposited in the present location. This indicates enhanced monsoonal activity in the provenance areas, than that obtained today.

Clay Minerals and Detrital Material in Paleocene–Eocene Biogenic Siliceous Rocks (Sw Western Siberia): Implications for Volcanic and Depositional Environment Record

The paper presents the results of a study on clay minerals and detrital material of biosiliceous rocks (Paleocene–Eocene) from three sections in the Transuralian region. The authigenic processes in sediments resulted in the formation of dioctahedral clay minerals (illite, smectite) and insignificant amounts of sulfide phases (pyrite, hydrotroillite). Detrital minerals from the studied diatomites and diatomaceous clays often have a subangular and semi-rounded habit that is evidence of a low degree alteration of the sedimentary material in the provenance areas. The high degree of preservation of the bioclastic debris and the transformation of the limited volcanogenic substratum in clay minerals apparently was possible by initial burial diagenesis. The morphology of kaolinite and illite suggests that these mineral formations were caused by diagenesis with feldspars and smectites as a substrate for their formation. The smectite zone of weathering crust that developed on the adjacent land could have also served as a significant source of smectites entering the sea basin. The association with smectite in aggregates of mixed clayey composition indicates a sequential smectite-to-illite reaction via mixed-layered minerals. Such minerals as amphiboles, pyroxenes, and olivines, semi-stable to transportation and genetically associated with ultramafic rocks, form a significant part of the clastic fraction of the rock, indicating the proximity of provenance areas. This is the evident reason that the provenance areas made of mafic and ultramafic rocks played an essential role.

Multi-Tool (LA-ICPMS, EMPA and XRD) Investigation on Heavy Minerals from Selected Holocene Peat-Bog Deposits from the Upper Vistula River Valley, Poland

Peat sediments represent important environmental and climatic archives, as well as recording information on the processes affecting the formation of these deposits; combined these data can be used for paleoreconstruction of peat-bogs. In this paper we characterize heavy mineral-rich sandy layers from two peat-bog sites in Mizerów and Strumień (Poland). In both cases, the most common identified mineral suite is: epidote, staurolite, tourmaline (dravite and schörl), garnet, spinel, Al2SiO5 polymorphs (sillimanite, kyanite, andalusite), amphibole (mainly hornblende), pyroxene (e.g., richterite, diopside), perovskite, topaz, cordierite, apatite, monazite, chromite, ilmenite, chlorite, iron oxides, rutile and siderite. This mineral suite is characteristic of a metamorphic aureole surrounding a magmatic body. Pyrite is likely authigenic in origin. Apatite and monazite were employed for U-Pb and CHIME dating, respectively. Based on the U-Pb age information composition and textural features of selected minerals, different provenance areas were indicated: the Tatra Massif, the Bohemian Massif, and the Silesian Basin area. Transport of the investigated mineral phases was linked to development of both the Odra (praOdra) and the Vistula valleys.

Sandstone petrography and geochemistry of the Nayband Formation (Upper Triassic, Central Iran): Implications for sediment provenance and tectonic setting

The Upper Triassic (Norian–Rhaetian) Nayband Formation is situated at the southwestern margin of Central East Iranian Microcontinent and records Eo-Cimmerian events. The formation is composed of mixed carbonate-siliciclastic deposits. This study presents information on the tectonic reconstruction and palaeoclimate of the southwestern margin of Central East Iranian Microcontinent during the Late Triassic. Petrography and modal analyses of sandstones show a variety of quartz-rich petrofacies including subarkose, lithic arkose, sublitharenite, feldspathic litharenite and litharenite. The combined modal analysis and geochemical results of major and trace elements of the sandstone samples represents mixed sedimentary, intermediate, felsic igneous rocks and moderate- to high-grade metamorphic provenance areas. The major elements and modal analyses of the Nayband Formation sandstone samples suggest an active continental margin tec-tonic settings. The palaeoclimatic conditions were sub-humid to humid with relatively low to moderate weathering in the source area which is in agreement with the palaeogeography and palaeotectonic history of southwestern margin of Central East Iranian Microcontinent during the Late Triassic.