Two-sided vertical competition considering product quality in a manufacturing-remanufacturing system

<p style='text-indent:20px;'>We study two-sided vertical competition between a manufacturer and a supplier. The problem is formulated as a dynamic game where the supplier has more pricing power than the manufacturer. Based on the one-sided vertical competition modes with different recyclers as benchmarks, we derive optimal pricing and production decisions of manufacturer and supplier and further study the impacts of product quality on those decisions under the two-sided vertical competition mode. A key finding is that manufacturer/supplier prefers to be a follower rather than the first one to engage in recycling activities. Specifically, when the manufacturer/supplier has engaged in recycling activities, the supplier/manufacturer has an incentive to participate in recycling activities as well. We also find that high-quality remanufactured components/products can benefit manufacturer, supplier and consumers at the same time.</p>

Retail outsourcing strategy in Cournot & Bertrand retail competitions with economies of scale

<p style='text-indent:20px;'>This paper investigates a manufacturer's retail outsourcing strategies under different competition modes with economies of scale. We focus on the effects of market competition modes, economies of scale and competitor's behavior on manufacturer's retail outsourcing decisions, and then we develop four game models under three competition modes. Firstly, we find the channel structure where both manufacturers choose retail outsourcing cannot be an equilibrium structure under the Cournot competition. The Cournot competition mode is less profitable to the firm than the Bertrand competition when the products are complements. Secondly, under the hybrid Cournot-Bertrand competition mode, there is only one equilibrium supply chain structure where neither manufacturer chooses retail outsourcing, when the substitutability and complementarity levels are not sufficiently high. In addition, setting price (quantity) contracts as the strategic variables is the dominant strategy for the direct-sale manufacturer who provides complementary (substitutable) products. Thirdly, both competitive firms will benefit from the situation where they choose the same competition mode. When the products are substitutes (complements), both of them choose the Cournot (Bertrand) competition mode. Finally, we show that the economies of scale have little impact on the equilibrium of the outsourcing structure but a great impact on the competition mode equilibrium.</p>

Perovskite-Type Oxides La0.6M0.4Ni0.6Cu0.4O3 (M = Ag, Ba, Ce) towards the Oxygen Reduction Reaction (ORR) in Alkaline Medium: Structural Aspects and Electrocatalytic Activity

In this work, La0.6M0.4Ni0.6Cu0.4O3 (M = Ag, Ba, and Ce, denoted as LANC, LBNC, and LCNC, respectively) electrocatalysts were synthesized by the Pechini method at 1023 K for two hours in air. Rietveld refinement allowed the identification of the crystallographic phases present in all oxides. The electrocatalytic performance of these oxides towards the oxygen reduction reaction (ORR) was examined in alkaline medium by rotating disk electrode (RDE) technique and scanning electrochemical microscopy (SECM) in the redox competition mode. The results indicate that the best performance was found with the LANC electrocatalyst prepared with carbon as a conducting agent (LANC/Carbon), which showed good catalytic activity towards the ORR via a pseudo fourelectron transfer pathway. The enhanced electrocatalytic activity of LANC is probably a result of the presence of a Ag phase, which improves the synergistic effect between the perovskite and carbon added to increase the conductivity, thus leading to a higher ORR performance when compared to other materials.

Characterization of Inherently Chiral Electrosynthesized Oligomeric Films by Voltammetry and Scanning Electrochemical Microscopy (SECM)

A voltammetric and scanning electrochemical microscopy (SECM) investigation was performed on an inherently chiral oligomer-coated gold electrode to establish its general properties (i.e., conductivity and topography), as well as its ability to discriminate chiral electroactive probe molecules. The electroactive monomer (S)-2,2′-bis(2,2′-bithiophene-5-yl)-3,3′-bibenzothiophene ((S)-BT2T4) was employed as reagent to electrodeposit, by cyclic voltammetry, the inherently chiral oligomer film of (S)-BT2T4 (oligo-(S)-BT2T4) onto the Au electrode surface (resulting in oligo-(S)-BT2T4-Au). SECM measurements, performed in either feedback or competition mode, using the redox mediators [Fe(CN)6]4− and [Fe(CN)6]3− in aqueous solutions, and ferrocene (Fc), (S)-FcEA, (R)-FcEA and rac-FcEA (FcEA is N,N-dimethyl-1-ferrocenylethylamine) in CH3CN solutions, indicated that the oligomer film, as produced, was uncharged. The use of [Fe(CN)6]3− allowed establishing that the oligomer film behaved as a porous insulating membrane, presenting a rather rough surface. This was inferred from both the approach curves and linear and bidimensional SECM scans, which displayed negative feedback effects. The oligomer film acquired semiconducting or fully conducting properties when the Au electrode was biased at potential more positive than 0.6 V vs. Ag|AgCl|KCl. Under the latter conditions, the approach curves displayed positive feedback effects. SECM measurements, performed in competition mode, allowed verifying the discriminating ability of the oligo-(S)-BT2T4 film towards the (S)-FcEA and (R)-FcEA redox mediators, which confirmed the results obtained by cyclic voltammetry. SECM linear scans indicated that the enantiomeric discriminating ability of the oligo-(S)-BT2T4 was even across its entire surface.

Scanning Electrochemical Microscopy of Electrically Heated Wire Substrates

We report a new configuration for enhancing the performance of scanning electrochemical microscopy (SECM) via heating of the substrate electrode. A flattened Pt microwire was employed as the substrate electrode. The substrate was heated by an alternating current (AC), resulting in an increased mass transfer between the wire surface and the bulk solution. The electrochemical response of the Pt wire during heating was investigated by means of cyclic voltammetry (CV). The open circuit potential (OCP) of the wire was recorded over time, while varied heating currents were applied to investigate the time needed for establishing steady-state conditions. Diffusion layer studies were carried out by performing probe approach curves (PACs) for various measuring modes of SECM. Finally, imaging studies of a heated substrate electrode surface, applying feedback, substrate generation/tip collection (SG/TC), and the competition mode of SECM, were performed and compared with room temperature results.