Modification of Sulfonated Polyethersulfone Membrane as a Selective Adsorbent for Co(II) Ions

In the current study, a variety of sulfonated polyethersulfone (SPES)-based ion-exchange membranes were prepared and utilized as efficient and selective solid adsorbents for the detection of Co(II) ions in aquatic solutions. SPES membranes were treated with a variety of cations at a 2:1 ratio overnight. The produced materials were assessed via XRD, FT-IR, SEM, and TGA analyses. The structure of these materials was confirmed by FT-IR and XRD, which also confirmed the inclusion of Na+, NH4+, and amberlite on the SPES surface successfully. TGA analysis showed that the thermal stabilities of these materials were enhanced, and the order of stability was NH4-SPES > SPES > Na-SPES > A-SPES. Furthermore, the efficiency of these modified membranes for the determination and adsorption of a variety of metal ions was also examined by the ICP-OES analytical technique. A-SPES expressed a powerful efficiency of adsorption, and it showed an efficient as well as quantitative adsorption at pH = 6. Moreover, A-SPES displayed the highest adsorption capacity of 90.13 mg/g for Co(II) through the Langmuir adsorption isotherm.

Applicability of ferric(III) hydroxide as a phosphate selective adsorbent for sewage treatment

This research was undertaken to evaluate the usability of ferric(III) hydroxide for phosphate removal from sewage. A batch adsorption experiments, partly a fixed bed column experiments, were conducted to study the influence of various factors, competing anions and contact time on the adsorption of phosphate on ferric(III) hydroxide. Processing ferric iron in the form of akaganeite (β-FeOOH) greatly increased the adsorption capacity for phosphate. The optimum phosphate removal was observed in the pHeq ≤ 6.0. All results from this study demonstrate the potential usability of β-FeOOH as a good phosphate selective adsorbent for the phosphate removal system of sewage treatment plant.