Particle anisotropy tunes emergent behavior in active colloidal systems

Studies of active particle systems have demonstrated that particle anisotropy can impact the collective behavior of a system. However, systems studied to date have served as one-off demonstrations of concept,...

Properties of assembly of superparamagnetic nanoparticles in viscous liquid

Detailed calculations of the specific absorption rate (SAR) of a dilute assembly of iron oxide nanoparticles with effective uniaxial anisotropy dispersed in a liquid are performed depending on the particle diameters, the alternating (ac) magnetic field amplitude H0 and the liquid viscosity. For small and moderate H0 values with respect to particle anisotropy field Hk the SAR of the assembly as a function of the particle diameter passes through a characteristic maximum and then reaches a plateau, whereas for sufficiently large amplitudes, H0 ~ Hk, the SAR increases monotonically as a function of diameter. The realization of viscous and magnetic oscillation modes for particle unit magnetization vector and director for moderate and sufficiently large H0 values, respectively, explains this behavior. It is found that the SAR of the assembly changes inversely with the viscosity only in a viscous mode, for nanoparticles of sufficiently large diameters. In the magnetic mode the SAR of the assembly is practically independent of the viscosity, since in this case the nanoparticle director only weakly oscillates around the ac magnetic field direction. The conditions for the validity of the linear response theory have been clarified by comparison with the numerical simulation data.

Janus Particles at Fluid Interfaces: Stability and Interfacial Rheology

The use of the Janus motif in colloidal particles, i.e., anisotropic surface properties on opposite faces, has gained significant attention in the bottom-up assembly of novel functional structures, design of active nanomotors, biological sensing and imaging, and polymer blend compatibilization. This review is focused on the behavior of Janus particles in interfacial systems, such as particle-stabilized (i.e., Pickering) emulsions and foams, where stabilization is achieved through the binding of particles to fluid interfaces. In many such applications, the interface could be subjected to deformations, producing compression and shear stresses. Besides the physicochemical properties of the particle, their behavior under flow will also impact the performance of the resulting system. This review article provides a synopsis of interfacial stability and rheology in particle-laden interfaces to highlight the role of the Janus motif, and how particle anisotropy affects interfacial mechanics.

Elongation and percolation of defect motifs in anisotropic packing problems

We connect the elongation of defect motifs due to particle anisotropy with the percolation universality class.

Retrieval of Snow Depth and Snow Water Equivalent Using Dual Polarization SAR Data

This paper deals with the retrieval of snow depth (SD) and snow water equivalent (SWE) using dual-polarization (HH-VV) synthetic aperture radar (SAR) data. The effect of different snowpack conditions on the SD and SWE inversion accuracy was demonstrated by using three TerraSAR-X acquisitions. The algorithm is based on the relationship between the SD, the co-polar phase difference (CPD), and particle anisotropy. The Dhundi observatory in the Indian Himalaya was selected as a validation test site where a field campaign was conducted for ground truth measurements in January 2016. Using the field measured values of the snow parameters, the particle anisotropy has been optimized and provided as an input to the SD retrieval algorithm. A spatially variable snow density ( ρ s ) was used for the estimation of the SWE, and a temporal resolution of 90 m was achieved in the inversion process. When the retrieval accuracy was tested for different snowpack conditions, it was found that the proposed algorithm shows good accuracy for recrystallized dry snowpack without distinct layering and low wetness (w). The statistical indices, namely, the root mean square error (RMSE), the mean absolute difference (MAD), and percentage error (PE), were used for the accuracy assessment. The algorithm was able to retrieve SD with an average MAE and RMSE of 6.83 cm and 7.88 cm, respectively. The average MAE and RMSE values for SWE were 17.32 mm and 21.41 mm, respectively. The best case PE in the SD and the SWE retrieval were 8.22 cm and 18.85 mm, respectively.

Co-doped MnFe2O4 nanoparticles: magnetic anisotropy and interparticle interactions

The effect of cobalt doping on the magnetic properties of Mn1− x Co x Fe2O4 nanoparticles was investigated. All samples consist of ensembles of nanoparticles with a spherical shape and average diameter of about 10 nm, showing small structural changes due to the substitution. Besides having the same morpho-structural properties, the effect of the chemical composition, i.e., the amount of Co doping, produces marked differences on the magnetic properties, especially on the magnetic anisotropy, with evident large changes in the coercive field. Moreover, Co substitution has a profound effect on the interparticle interactions, too. A dipolar-based interaction regime is detected for all samples; in addition, the intensity of the interactions shows a possible relation with the single particle anisotropy. Finally, the sample with the strongest interaction regime shows a superspin glass state confirmed by memory effect dynamics.