Evaluation of Heavy Metal Contents and Potential Human Health Risk Assessment of Selected Canned Sardines Fish Sold in Yenagoa, Nigeria

Canned sardine fish is consumed regularly in all countries. The levels of heavy metals which are present in the environment could constitute a hazard to food security and public health. These can be accumulated in aquatic animals such as fish. In this study, selected heavy metals: Copper (Cu), Nickel (Ni), Chromium (Cr), Zinc (Zn), Cadmium (Cd), Manganese (Mn), Lead (Pb) and Iron (Fe) were evaluated in Sardines that are commonly consumed in Nigeria. Eight different brands of canned sardines were purchased in Yenagoa and were taken to the Laboratory for heavy metal analysis. Standard wet digestion procedure was adopted for sample preparation while Atomic Absorption Spectrophotometer (AAS) technique was adopted for metal analysis. The results show that heavy metal concentrations of Fe in the samples were above World Health Organization (WHO) and United States Environmental Protection Agency (USEPA) permissible limits, while Zn was below the permissible limits. However, Pb, Cu, Cd, Cr, Ni and Mn were below detectable limits in all the samples. Daily intake of metal (DIM) values in the sardine samples for Zn and Fe were significantly lower than the recommended daily intake and the upper tolerable daily intake levels. The Health risk index (HRI), Target hazard quotient (THQ) and Hazard Index (HI) for Zn and Fe in this study were less than 1(˂1) for both adult and children, therefore, the canned sardines does not pose a potential human health risk concern for the consumers. However, the high Fe concentrations in all the sardine samples may cause public health concern as they are above WHO and USEPA tolerable limits.

Arsenic Speciation in Rice, Mechanisms and Associated Health Risk Through Rice Consumption in Various Districts of Khyber Pakhtunkhwa, Pakistan

Arsenic (As) is one of the toxic metalloids therefore can cause health risk in the consumers through consumption of contaminated food and rice. The current study focused on As speciation in rice, bioavailability, mechanisms and its potential human health risk. For this purpose, rice and soil samples were collected from 16 different districts (non-mining and mining) of Khyber Pakhtunkhwa (Pakistan). Soil physicochemical characteristic such as texture, electrical conductivity (EC), organic matter (OM), pH, iron (Fe) and phosphorus (P) were determined. Total arsenic (AsT) concentrations were analyzed using ICP-MS, while the arsenite (As3+), arsenate (As5+), arsenobetine (BAs), dimethylarsenic (DMA) and monomethyl arsenic (MMA) were determined by HPLC–ICP-MS method. Results showed the highest AsT (0.28 mg/kg) was observed in the rice samples of DI Khan District and lowest (0.06 mg/kg) in Shangla District. However, these findings were found within the permissible limits set by various authorities. Furthermore, results showed higher concentrations of inorganic As (Asi) than organic As (Aso) species in rice. The estimated daily intake (EDI) and incremental lifetime cancer risk (ILTCR) were used to evaluate the potential human health risk for As consumption in rice. Results revealed that the rice samples collected from the district having mining activities had higher value of As (0.28 mg/kg of AsT) as compared to non-mining (0.072 mg/kg of AsT). The highest ILTCR value (0.00196) was observed for rice collected from mining districts. This study revealed that mining activities have great influence on the As contamination of soil and grown rice. This study recommends the soil amendment in districts having mining activities to lower As availability in soil and its bioaccumulation in growing rice that will help to keep lower the potential risk.