Surface configuration of CO adsorbed on nanostructured Pt electrodes probed using broadband sum frequency generation spectroscopy

Inhomogeneity of adsorbed CO introduced by the aggregation of Pt nanoparticles.

Application of the Electrophoretic Deposition Technique for the Development of Electrodes Containing a Catalyst Layer of Nanostructured Pt-Sn/C for DAFCs

A catalyst layer of Pt-Sn/C (Pt:Sn 1:1 atomic ratio) was deposited on commercial carbon cloth electrodes by electrophoretic deposition (EPD). The Pt-Sn/C nanocatalyst was synthesized by the polyol method. Three current signals were applied: i) continuous direct current (CDC); ii) positive pulsed current (PPC); and iii) asymmetric alternating current (AAC). The chemical composition analysis showed the effect of the applied signal on species transferred onto the carbon cloth to form the catalyst layers. Evaluation by SEM confirmed the effect of deposition-signal on the morphology of the catalyst layer. The CDC signal formed spherical agglomerates with irregular distribution along with carbon fibers over the electrode, showing some cracks. A cross-cut view of the electrode showed that the catalyst penetrated the carbon cloth. Meanwhile, the PPC signal promoted a better deposition of the catalyst layer over the carbon cloth surface, with a thicker and more homogeneous rough layer than CDC. In contrast, the layer developed by the AAC signal showed a morphology similar to that by CDC, suggesting the formation of a layer with low metal loading. The cross-cut view of the AAC electrode showed the formation of a highly rough layer having large areas with limited contact with the carbon cloth fibers. The electro-catalytic activity of the electrodes for the Ethanol Oxidation Reaction (EOR) was studied in acid media. The CDC electrode showed an enhanced performance for the EOR by delivering the highest current density (272 mA mg-1Pt) with the more negative onset potential (341 mV) relative to the PPC and AAC electrodes.

Cu Modified Pt Nanoflowers with Preferential (100) Surfaces for Selective Electroreduction of Nitrate

Improving surface selectivity and maximizing electrode surface area are critical needs for the electroreduction of nitrate. Herein, preferential (100) oriented Pt nanoflowers with an extended surface area were prepared by potentiostatic deposition on carbon cloth (Pt NFs/CC), and then Cu atoms were adsorbed on the Pt NFs (Cu/Pt NFs/CC) for application of nitrate electroreduction. The results reveal that Cu/Pt NFs/CC with 8.7% Cu coverage exhibits a high selectivity for nitrate electroreduction to N2 following two steps: Nitrate firstly converts into nitrite on Cu sites adsorbed on Pt NFs, then nitrite subsequently selective reduction and ammonia oxidation to N2 occur on the large exposed (100) terraces in Pt NFs. In addition, electrocatalytic activity and selectivity of nitrate reduction strongly rely on the Cu surface coverage on Pt NFs, the lower activity of nitrate reduction is displayed with increase of Cu coverage. Accordingly, the selective reduction of nitrate to N2 is feasible at such nanostructured Pt nanoflowers modified with Cu.