Patterning Configuration of Surface Hydrophilicity by Graphene Nanosheet towards the Inhibition of Ice Nucleation and Growth

Freezing of liquid water occurs in many natural phenomena and affects countless human activities. The freezing process mainly involves ice nucleation and continuous growth, which are determined by the energy and structure fluctuation in supercooled water. Herein, considering the surface hydrophilicity and crystal structure differences between metal and graphene, we proposed a kind of surface configuration design, which was realized by graphene nanosheets being alternately anchored on a metal substrate. Ice nucleation and growth were investigated by molecular dynamics simulations. The surface configuration could induce ice nucleation to occur preferentially on the metal substrate where the surface hydrophilicity was higher than the lateral graphene nanosheet. However, ice nucleation could be delayed to a certain extent under the hindering effect of the interfacial water layer formed by the high surface hydrophilicity of the metal substrate. Furthermore, the graphene nanosheets restricted lateral expansion of the ice nucleus at the clearance, leading to the formation of a curved surface of the ice nucleus as it grew. As a result, ice growth was suppressed effectively due to the Gibbs–Thomson effect, and the growth rate decreased by 71.08% compared to the pure metal surface. Meanwhile, boundary misorientation between ice crystals was an important issue, which also prejudiced the growth of the ice crystal. The present results reveal the microscopic details of ice nucleation and growth inhibition of the special surface configuration and provide guidelines for the rational design of an anti-icing surface.

Ультразвуковой адаптивный томограф бетонных изделий с нестандартной конфигурацией

It is shown that should be used adaptive antenna arrays, the shape of which can take the form of a non-planar surface of the tested product, for ultrasonic tomography of concrete building structures with a non-standard surface configuration. It should also be used adaptive methods of ultrasound tomography, which allows both to determine the coordinates of defects and the velocity of ultrasound in concrete, as well as adjust the parameters of the probing signals to the characteristics of concrete products.

Transverse shear properties of fiber reinforced polymer bars with different reinforced phases

In this study, a total of 105 shear specimens of fiber reinforced polymer bars with different reinforced phases, including the glass fiber, the hybrid of carbon fiber with glass fiber, and the hybrid of steel wire with glass fiber, were prepared to systematically investigate their transverse shear properties. The surface configuration of specimens, the performance characteristics and distribution pattern of reinforced phase were mainly regarded as variables. The results showed the shear strengths of glass fiber reinforced polymer bar specimens increased from 247.9 MPa to 263.5 MPa as the rib depth changed from shallow ribs to deep ribs, and their ultimate strain decreased from 0.374 to 0.328 with the increase in rib spacing from 8 mm to 16 mm. The shear strengths of carbon/glass hybrid fiber reinforced polymer (C/G HFRP) bar specimens declined from 247.4 MPa to 226.3 MPa as the distribution pattern of carbon fiber changed from centralized distribution to dispersed distribution. The shear strength of C/G HFRP bars decreased from 256.5 MPa to 247.4 MPa as the ratio of glass fiber to carbon fiber ranged from 0:1 to 1:4, and increased from 138.7 MPa to 214.8 MPa for steel wire/glass HFRP bars as the volumetric fraction of steel wire replacing glass fiber increased from 0 to 33.3%. This indicated that the surface configuration of specimen, the distribution pattern of fiber, and the performance characteristics of reinforced phase have great effects on the ultimate strain and shear strength of FRP bars, respectively.