Sedimentary response to current and nutrient regime rearrangement in the Eastern Mediterranean Realm during the early to middle Miocene (southwestern Cyprus)

During the early and middle Miocene, the Mediterranean had become a restricted marginal marine sea with diminishing and ultimate loss of connectivity to the Indian Ocean. This dramatically changed the heat, energy, freshwater and nutrient budgets across the Mediterranean and most notably in its eastern basin. While one of the most prominent lines of evidence of this change in the Eastern Mediterranean is the onset of sapropel formation, many other aspects of the sedimentary system changed in response to this rearrangement. Here we present a detailed analysis of a hemipelagic succession from southeastern Cyprus dated to the late Aquitanian to the early Serravallian (22.5 – 14.5 Ma). This sequence is carbonate-dominated and formed during the decoupling of the Mediterranean Sea and the Indian Ocean. It exhibits sedimentation with mass transport contribution from shallow water carbonates to deeper facies with phosphatization and bottom current (at intermediate depth) interactions. This succession traces both local subsidence and loss of a local carbonate factory. Additionally, it records a shift in bottom current energy and seafloor ventilation, which are an expected outcome of connectivity loss with the Indian Ocean.

A New Model for the Genesis of Carboniferous Mn Ores, Longtou Deposit, South China Block

The lower Carboniferous Luzhai and Baping Formations (ca. 359 Ma) of the South China block, Guangxi Province, comprise an ca. 170-m-thick clastic-carbonate succession capped by Mn ore horizons near the town of Longtou. Excellent exposure of the stratigraphic succession provides an unparalleled opportunity to investigate the origin of carbonate-hosted Mn deposits, which are generally understudied. Lithofacies associations suggest inner and middle shelf clastic rocks accumulated with deposition of carbonates on a mesotrophic middle to outer shelf. In the Longtou region, carbonate deposition during marine transgression culminated with the precipitation of high-grade Mn deposits during maximum flooding. Mn ore horizons are composed of amalgamated alabandite-bearing rhodochrosite, Mn calcite, and braunite laminae. Mn carbonates have been largely interpreted as forming in oxic water columns via reduction of Mn oxides by organic matter. However, paragenetic relationships and δ13C values (similar to those of seawater) indicate the Mn carbonates of Longtou were formed during authigenesis by the emplacement of anoxic, Mn-rich water masses on the distal to middle shelf. Such anoxia is interpreted to have shut down the carbonate factory and diminished sedimentation, a prerequisite for the concentration and precipitation of Mn carbonates in pore water. This research supports the notion that areas of the Paleozoic deep ocean were persistently anoxic and periodically tapped by coastal upwelling to produce Mn- and Fe-rich deposits. Application of this emerging ore deposit model to other economically important carbonate-hosted Mn deposits may improve resource exploration.

Benthic Foraminiferal Assemblages and Rhodolith Facies Evolution in Post-LGM Sediments from the Pontine Archipelago Shelf (Central Tyrrhenian Sea, Italy)

The seabed of the Pontine Archipelago (Tyrrhenian Sea) insular shelf is peculiar as it is characterized by a mixed siliciclastic–carbonate sedimentation. In order to reconstruct the Late Quaternary paleoenvironmental evolution of the Pontine Archipelago, this study investigates the succession of facies recorded by two sediment cores. For this purpose, benthic foraminifera and rhodoliths assemblages were considered. The two cores (post-Last Glacial Maximum in age) were collected at 60 (CS1) and 122 m (Caro1) depth on the insular shelf off Ponza Island. The paleontological data were compared with seismo-stratigraphic and lithological evidence. The cores show a deepening succession, with a transition from a basal rhodolith-rich biodetritic coarse sand to the surface coralline-barren silty sand. This transition is more evident along core Caro1 (from the bottom to the top), collected at a deeper water depth than CS1. In support of this evidence, along Caro1 was recorded a fairly constant increase in the amount of planktonic foraminiferal and a marked change in benthic foraminiferal assemblages (from Asterigerinata mamilla and Lobatula lobatula assemblage to Cassidulina carinata assemblage). Interestingly, the dating of the Caro1 bottom allowed us to extend to more than 13,000 years BP the rhodolith record in the Pontine Archipelago, indicating the possible presence of an active carbonate factory at that time.

The recovery of early vertebrates and reef ecosystems following the late Silurian carbon isotope excursion: the Burgen outlier, Gotland, Sweden

<p>The Ludfordian Carbon Isotope Excursion (LCIE) reached the highest known δ<sup>13</sup>C values in the Phanerozoic. It was a global environmental perturbation manifested in a rapid regression attributed to glacial eustasy. Previous studies suggested that it has also heavily affected the diversity of conodonts, early vertebrates and reef ecosystems, but the timing of the crisis and recovery remained complicated owing to the lateral variability of δ<sup>13</sup>C values in epeiric platforms and rapid facies shifts, which drove faunal distribution. One of the best records of this interval is available in the Swedish island of Gotland, which preserves tectonically undisturbed strata deposited in a Silurian tropical carbonate platform. We revisited the world-renowned collection of the late Lennart Jeppsson, hosted at the Swedish Museum of Natural History, Stockholm, which holds the key to reconstruct the dynamics of faunal immigration and diversification following the LCIE. Here we focus on the Burgen erosional outlier, which remained a mystery, as it had been correlated with the excursion strata, but preserved a high diversity of conodonts and reefal ecosystems. We re-examined key outcrops and characterized macro- and microfacies, as well as chemostratigraphy and unpublished fauna in the collection. Strata in the Burgen outlier represent back-shoal facies of the Burgsvik Oolite Member and correspond to the Ozarkodina snajdri Conodont Biozone. The shallow-marine position compared to the more continental setting of coeval strata in southern Gotland, is reflected in the higher δ<sup>13</sup>C<sub>carb</sub> values, reaching +9.2‰. The back-shoal succession in this outcrop includes reefs, which contain a large proportion of microbial carbonates and have therefore been previously compared with low-diversity buildups developed in a stressed ecosystem. However, the framework of these reefs is built by a diverse coral-stromatoporoid-bryozoan fauna, indicating that a high microbial contribution might be a characteristic of the local carbonate factory rather than a reflection of restricted conditions. In the case of conodonts, impoverishment following the LCIE might be a product of facies preferences, as the diverse environments in the outlier yielded at least 20 of the 21 species known from the Burgsvik Formation in Gotland. Fish diversity also returned to normal levels following the LCIE with an estimated minimum of 9 species. Thelodont scales appear to dominate samples from the Burgen outlier, which is in line with previous reports. Our observations highlight how palaeoenvironmental reconstructions inform fossil niche and diversity analyses, but also how fossil museum collections continuously contribute new data on past biodiversity.</p>

Sedimentary factories and ecosystem change across the Permian–Triassic Critical Interval (P–TrCI): insights from the Xiakou area (South China)

The Permian–Triassic mass extinction included a potentially catastrophic decline of biodiversity, but ecosystem change across this event remains poorly characterized. Here we reconstruct sedimentary factories and ecosystem change across the Permian–Triassic Critical Interval (P–TrCI) in the Xiakou area (South China). Six microfacies (MF) were classified. The succession begins with a eukaryote-controlled carbonate factory (MF-1) that passes upward into an organomineralization-dominated carbonate factory (MF-2–3). Organic-rich marls atop these units reflect carbonate factory collapse (MF-4). Organomineralization-driven carbonate formation restarts prior to the Permian–Triassic boundary (MF-5) and subsequently develops into a mixed carbonate factory where organomineralization and biomineralization are almost equally important (MF-6). MF-1 reflects oxygenated shallow water environments. In contrast, MF-2–6 were all deposited in somewhat deeper environments, some of which episodically exhibited elevated salinities, oxygen depletion, and, possibly, euxinic conditions. Our results demonstrate that distinct changes in carbonate production styles, biodiversity, and environmental conditions are not synchronous at Xiakou. Furthermore, the Xiakou record is strikingly different to that of other localities, even from the same area (e.g., the Global Stratotype Section and Point section at Meishan). Together, these findings highlight the enormous complexity of the P–TrCI and calls simplified views of the Permian–Triassic mass extinction into question.

Foraminifer and Ostracod Occurrence in a Cool-Water Carbonate Factory of the Cape Adare (Ross Sea, Antarctica): A Key Lecture for the Climatic and Oceanographic Variations in the Last 30,000 Years

Foraminifers and ostracods were studied in a gravity-core recovered near Cape Adare (Ross Sea, Antarctica) with the aim of identifying the climatic and oceanographic variations during the last 30 ka. The sedimentary sequence represents conditions of a cool-water carbonate factory, which evidences that during the Marine Isotope Stage 2 (MIS2) the area was ice-free and very productive. The overall preservation of delicate skeletal remains such as bryozoans and molluscs indicated moderate bottom currents. This carbonate factory was interrupted by some terrigenous levels, representing conditions of instability/retreat of the ice shelves southward. The younger levels were referred to the meltwater pulse (MWP)-1A and 1B events. The Holocene sequence comprised more terrigenous sediments, reflecting high bottom-currents similar to the present-day conditions. Very abundant and well preserved foraminifers and ostracods, representative of shelf-upper slope paleoenvironments, were recovered. Epistominella exigua, among the foraminifers, suggested the influence of the Circumpolar Deep Water during some periods of the late Quaternary. Heavy-test taxa, such as Cibicides refulgens, indicated strengthening bottom hydrodynamics. As for the ostracods, peaks in the presence of Australicythere devexa, Bairdoppilata simplex and Pseudocythere aff. caudata together with significant values of Polycope spp. allowed us to identify environments rich in nutrients with the influence of cold and deep water upwelling phenomena.