Effects of Pore Structure of Different Rank Coals on Methane Adsorption Heat

Adsorption thermodynamic characteristics are an important part of the methane adsorption mechanism, and are useful for understanding the energy transmission mechanism of coalbed methane (CBM) migration in coal reservoirs. To study the effect of coal pore characteristics on methane adsorption heat, five different types of rank coals were used for low-pressure nitrogen, low-pressure carbon dioxide, and methane adsorption experiments. Pore structure and adsorption parameters, including maximum adsorption capacity and adsorption heat, were obtained for five coal samples, and their relationships were investigated. The results show that the low-pressure nitrogen adsorption method can measure pores within 1.7–300 nm, while the low-pressure carbon dioxide adsorption method can measure micropores within 0.38–1.14 nm. For the five coal samples, comprehensive pore structure parameters were obtained by combining the results of the low-pressure nitrogen and carbon dioxide adsorption experiments. The comprehensive results show that micropores contribute the most to the specific surface area of anthracite, lean coal, fat coal, and lignite, while mesopores contribute the most to the specific surface area of coking coal. Mesopores contribute the most to the pore volume of the five coal samples. The maximum adsorption capacity has a significant positive correlation with the specific surface area and pore volume of micropores less than 2 nm, indicating that methane is mainly adsorbed on the surface of micropores, and can also fill the micropores. The adsorption heat has a significant positive correlation with the specific surface area and pore volume of micropores within 0.38–0.76 nm, indicating that micropores in this range play a major role in determining the methane adsorption heat.

Modeling and Analysis of a Coated Tube Adsorber for Adsorption Heat Pumps

This work investigates the effects of several parameters on the coefficient of performance (COP) and the specific heating power (SHP) of a coated-tube adsorber for adsorption heat pumps (AHP) suitable for water heating (space and/or domestic water heating). The COP and SHP are obtained based on physical models that have already been proven to adequately describe this type of adsorber. Several parameters are tested, namely, the regeneration, condenser and evaporator temperatures, the heat transfer fluid velocity, the tube diameter, the adsorbent coating thickness, the metal–adsorbent heat transfer coefficient, and the cycle time. Two different scenarios were tested, corresponding to distinct working conditions. The working conditions for Scenario A are suitable for pre-heating water in mild climates. Scenario B’s working conditions are based on the European standard EN16147. The maximum COP is obtained for regeneration temperatures of 75 °C and 95 °C for Scenarios A and B, respectively. The COP increases for longer cycle times (more complete adsorption and desorption processes) whilst the SHP decreases (less complete cycles by unit time). Hence, the right balance between the COP and the SHP must be found for each particular scenario to have the best whole performance of the AHP. A metal–adsorbent heat transfer coefficient lower than 200 W·m−2·K−1 leads to reduced SHP. Lower adsorbent coating thicknesses lead to higher SHP and can still provide reasonably high COP. However, low coating thicknesses would require a too-high number of tubes to achieve the desired adsorbent mass to deliver the required useful heating power, resulting in too-large systems. Due to this, the best relationship between the SHP and the size of the system must be selected for each specific application.