Memory and superposition in a superspin glass

The non-equilibrium dynamics of the superspin glass state of a dense assembly of ~ 2 nm MnFe2O4 nanoparticles was investigated by means of magnetization, ac susceptibility and Mössbauer spectroscopy measurements and compared to the results of Monte Carlo simulations for a mesoscopic model that includes particles morphology and interparticle interactions. The zero-field cooled (ZFC), thermoremanent (TRM), and isothermal remanent magnetization (IRM) were recorded after specific cooling protocols and compared to those of archetypal spin glasses and their dimensionality. The system is found to display glassy magnetic features. We illustrate in detail, by a number of experiments, the dynamical properties of the low-temperature superspin glass phase. We observe that these glassy features are quite similar to those of atomic spin glasses. Some differences are observed, and interestingly, the non-atomic nature of the superspin glass is also reflected by an observed superspin dimensionality crossover. Monte Carlo simulations—that explicitly take into account core and surface contributions to the magnetic properties of these ultrasmall nanoparticles in direct contact, as well as interparticle interactions—evidence effects of the interplay between (intraparticle) core/surface exchange coupling and (interparticle) dipolar and exchange interactions.

Topologically stable helices in exchange coupled rare-earth/rare-earth multilayer with superspin-glass like ordering

Existence of 2π-planar domain walls (DWs) are often reported for transition metal-rare-earth (TM/RE) layered systems. The magnetization process of such two-dimensional randomly anisotropical system in the form of 2π-DWs is directly correlated with topologically stable helices. Here, instead of TM/RE, we have investigated [Dy/Tb]10 multilayers involving two different anisotropic layers of rare-earth/rare-earth (RE/RE). Using magnetization and susceptibility as function of temperature along with thermo-remanent magnetization measurements we have confirmed superspin-glass type of behavior within this RE/RE system. Additionally, an exchange bias field up to –0.88 kOe (–88 mT) was also revealed for such rare-earth based multilayers. Interestingly, using detailed analysis of the polarized neutron reflectometry profiles, we find evidences of superimposed helical magnetic configurations within both materials of Dy and Tb associated with spin-frustrated interfaces. Furthermore, magnetization fluctuations around the mean magnetization from vertically uncorrelated domains were observed with polarized off-specular neutron scattering. We believe that coexistence of helical ground states with superspin-glass-like ordering are fundamentally instrumental for topologically stability in RE/RE systems, which in principle, can be exploited in all-spin-based technology.

Manipulation of dipolar magnetism in low-dimensional iron oxide nanoparticle assemblies

Trench-patterned iron oxide nanoparticles are switched between a superspin glass and a superferromagnetic state.