Acetylated African Oil Bean Seed Pod For Crude Oil Spill Mop

Oil spill remediation has continued to be a challenge in the world today. Thus efforts are still been made to develop more efficient oil spill mop up techniques. Natural adsorption with agricultural wastes, which otherwise constitute environmental pollution, has become an attractive technique for oil spill mop. Acetylation using acetic anhydride with iodine catalyst was carried out to improve the hydrophobicity of African oil bean seed pod (AOBSP), which is a lignocellulosic material and as such is naturally hydrophilic. Characterization of the raw and acetylated AOBSP were done using SEM, BET and FTIR analyses. Batch crude oil sorption tests were performed using both the raw and acetylated AOBSP. Isotherm, kinetic and thermodynamic studies were also carried out. FTIR analysis showed evidence of successful acetylation of AOBSP and adsorption of crude oil onto the raw and acetylated AOBSP. SEM and BET analyses showed improvement of the surface properties of AOBSP by the acetylation process. The BET surface area increased from 226.4 m2/g for the raw AOBSP to 310.0 m2/g for the acetylated AOBSP. Oil sorption was found to be by monolayer coverage, with monolayer sorption capacity of 5000mg/g and 12500mg/g for raw and acetylated AOBSP, respectively. The rate-controlling mechanism for the sorption processes was chemisorption. Negative values of ΔGo, ΔHo and ΔSo were obtained, showing that the sorption processes were feasible, spontaneous and exothermic, with a degree of orderliness at the solid–mixture interface. The results obtained from this study show that both raw and acetylated AOBSP are efficient oil sorbents with potentials for further improvement for oil spill mop.

Innovation in Managing Leak Repair and Crude Oil Lifting Schedule to Respond to Pipeline Leak in Offshore Terminal System

Offshore terminal usually performs crude oil lifting process regularly every 7-8 days. However, three repetitive leaks in crude oil subsea pipeline 36" MOL SPM-1 to SPM-2 occurred in the offshore terminal area had stopped the natural oil lifting process. Due to complex conditions, leak repair needs a longer duration and some future crude oil lifting schedules facing cancelation possibilities. By simulating the leak parameter, more than 60 bbl. of crude oil would release from the leaking pipeline in 48 hours crude oil lifting operation. An innovative approach is built by designing a new tool to contain oil spills from the source using a pyramid shape tank and safely transport to the temporary storage tank on the diving vessel to keep crude oil lifting process execution still possible to hold while the subsea pipeline repair by installing subsea clamp is undergo. New tools have successfully eliminated oil spill spreading during crude oil lifting takes place schedule. Six crude lifting schedules have been safely delivered with nearly 30,000 liters of crude oil spill have been evacuated and transferred back to processing facilities. Further implementation would possibly be held in pipeline preservation program and diver less application, which can increase leak response time.

Effect of WAF crude oil exposure to larvae development of the black-scar oyster Crasosstrea iredalei

Oil spills potentially effect exposed organisms at various stage of life. This work aimed to access health risk of crude oil to larva development of a sessile organism the Black scar oyster Crassostrea iredalei by using water accommodate fraction (WAF) of crude oil. Male and female gametes was collect and fertilized to obtained larvae at cleavage stage. The larvae were then incubate in various concentrations of WAF (0, 6.25, 12.5, 25, 50, and 100 %). After 24 hour of exposure, normal D-shaped veliger larva (D-larva) was observe. The result showed that WAF crude oil affected the development and the successful of D-larva development. Severity of WAF effect was increasing with dosages of exposure. The abnormal larva developments were increasing in the high concentrations. The information obtaining from current work is important for health risk assessment of crude oil contamination incident in marine ecosystem. This study will also contribute valuable knowledge needed for aquaculture to know effect of crude oil spill to oyster farming area.