Improving the Performance of Split Air Conditioner by Adding Nano Silver to the Compressor Oil

A high demand on the energy and power has brought scholars more attention to investigate new ways to reduce the energy consumption. The aim of this research is reducing the power consumption required for air conditioning to cool the room by adding nanomaterials to the compressor oil at a mass concentration of 0.15%. Two models of chambers with dimensions (2 x 2 x 2) meters were fabricated to represent the test section and connected to a 1ton compressor, one operating with natural oil as a standard basis for comparison, while the other one with Nano-oil prepared in the laboratory. The mass concentrations of 0.15% of silver nanoparticles (Ag) were prepared, and the stability of the nanoparticles was tested by direct observation for different time periods. The results indicated that the performance of the air conditioner was better with the addition of nanoparticles to the compressor oil compared to the pure oil in the compressor. Reducing energy consumption in the cooling system by (19%). Also, it was found that there is an increase in the cooling speed of the nanotechnology system by (6%)as well as in the efficiency of the Nano-oil system compared to the regular system by (13%). This study showed that the thermophysical properties of the cooling oil increased by increasing the weight ratios of solid nanoparticles by (12%).

Natural Oil-Based Rigid Polyurethane Foam Thermal Insulation Applicable at Cryogenic Temperatures

This paper presents research into the preparation of rigid polyurethane foams with bio-polyols from rapeseed and tall oil. Rigid polyurethane foams were designed with a cryogenic insulation application for aerospace in mind. The polyurethane systems containing non-renewable diethylene glycol (DEG) were modified by replacing it with rapeseed oil-based low functional polyol (LF), obtained by a two-step reaction of epoxidation and oxirane ring opening with 1-hexanol. It was observed that as the proportion of the LF polyol in the polyurethane system increased, so too did the apparent density of the foam material. An increase in the value of the thermal conductivity coefficient was associated with an increase in the value of apparent density. Mechanical tests showed that the rigid polyurethane foam had higher compressive strength at cryogenic temperatures compared with the values obtained at room temperature. The adhesion test indicated that the foams subjected to cryo-shock obtained similar values of adhesion strength to the materials that were not subjected to this test. The results obtained were higher than 0.1 MPa, which is a favourable value for foam materials in low-temperature applications.

Age-old transformation of oil hydrocarbons in polluted Grey-Brown Soil in the Absheron Peninsula

Oil production, transportation and refining are a source of the extensive environmental pollution. The study of oil pollutants allows the identification of their behavior pattern necessary in order to elaborate efficient decontamination technologies. The Absheron oil field is one of the most long-term exploited deposit in the world. Today this area is a unique place to investigate the long-lasting natural oil transformation processes. Grey-Brown Soils contaminated with crude oil 100 and 40 years ago and currently were investigated. Hexane-extractable fraction of oil compounds was examined by chemical methods, gas chromatography and mass spectrometry. In the process of natural degradation, molecular weight of oil hydrocarbons and degree of oxidation significantly increased, while the contents of carbon and hydrogen slightly decreased with time. The results obtained have shown the accumulation of high-molecular weight aromatic molecules with high degree of unsaturation in the upper layer of the soil contaminated 100 years ago. These aromatic structures exhibit the great resistance to decomposition and may be carcinogenic, thus posing a risk to human health. The contamination with oil resulted in altering soil properties. More pronounced change was observed in the soil carbon, including the soil contaminated 100 years ago. Over time after contamination, the soil alkalinity enhanced, whereas soil pH did not change. Our study evidences that oil pollutants continue to be present and the soil properties have not recovered even 100 years after pollution. Reclamation of these areas requires the application of special technologies.

INDIGENOUS PEOPLES’ RIGHTS OVER NATURAL RESOURCES: AN ANALYSIS OF HOST COMMUNITIES RIGHTS IN NIGERIA

The many States are engulfed in crises over natural resources in the form of claims and counterclaims over who should exercise legal authority over the resources located within the state territory. In Nigeria, the agitation over control of natural resources has led to militancy and rebellion against the federal government and multinational oil companies. The debate on who should control and manage natural oil resources in Nigeria exists at the local community level, the federating states level, and the federal government level. This paper x-rayed the varying contentions of these agitations from an international law perspective. It adopted the doctrinal method to explore international human rights instruments and other legal and non-legal sources to realize the result and arrive at persuasive conclusions. The paper concluded that although international law guarantees states’ exercise of sovereign rights over their natural resources, it safeguards the right of indigenous peoples and communities to manage the natural resources found within their ancestral lands to deepen their economic and social development. It also concluded that the Niger Delta indigenous peoples and oil-producing communities are entitled to exercise some measure of control and management of the processes of exploitation of the natural resources found within their lands. The paper calls on the Nigerian government to fast-track legal and policy reforms to resource rights to indigenous host communities of natural resources in Nigeria.

Antimicrobial Activity and Synergy Investigation of Hypericum scabrum Essential Oil with Antifungal Drugs

The chemical composition of Lebanese Hypericum scabrum essential oil (EO) was analyzed by gas chromatography (GC) and gas chromatography-mass spectrometry (GG-MS). Its antimicrobial activity was evaluated by determining its minimal inhibitory concentrations (MICs) against a Gram-negative and a Gram-positive bacterium, one yeast, and five dermatophytes. H. scabrum EO was most active on filamentous fungi (MIC values of 32–64 µg/mL). Synergy within the oil was investigated by testing each of the following major components on Trichophyton rubrum: α-pinene, limonene, myrcene, β-pinene and nonane, as well as a reconstructed EO. The antifungal activity of the natural oil could not be reached, meaning that its activity might be due, in part, to minor constituent(s). The interactions between H. scabrum EO and commercially available antifungals were assessed by the checkerboard test. A synergistic effect was revealed in the combination of the EO with amphotericin B.

Agronomical Performances of Angolan Natural Oil Palm Accessions and Interests for Oil Palm Selection in Côte d’Ivoire

In Côte d’Ivoire, Deli populations, descendants of four oil palms, constituted Group A of the recurrent reciprocal selection. Their genetic base was narrow, an obstacle to long-term genetic progress. Therefore, Angolan oil palm accessions were acquired to broaden Group A’s genetic base. Angola selfed and Deli × Angola progenies were tested via Angola selfed × La Mé and (Deli × Angola) × La Mé intergroup hybrids for bunch and oil production, height growth, and tolerance to Fusarium in two progeny trials; one in La Mé (Côte d’Ivoire) and the other one in Bangun Bandar (Indonesia). On average, bunch yield (183 kg/palm/year) and oil yield (5.34 t/ha) were close to those of the control. The best 5 hybrids represented 104-112% of the control all traits put together. In addition, Angolan origin has transmitted tolerance to Fusarium to its progenies (Fusarium index = 80-90). [(Deli × Angola)’s LM 5448 T] × La Mé hybrids yielded 241.4 kg/palm/year of bunch and 7.30 t/ha of palm oil. Their mean height was comparable to that of the control and the Fusarium index low (82). Therefore, LM 5448 T was selected for further crop improvements. The modalities of its use were proposed.

Innovation in Managing Leak Repair and Crude Oil Lifting Schedule to Respond to Pipeline Leak in Offshore Terminal System

Offshore terminal usually performs crude oil lifting process regularly every 7-8 days. However, three repetitive leaks in crude oil subsea pipeline 36" MOL SPM-1 to SPM-2 occurred in the offshore terminal area had stopped the natural oil lifting process. Due to complex conditions, leak repair needs a longer duration and some future crude oil lifting schedules facing cancelation possibilities. By simulating the leak parameter, more than 60 bbl. of crude oil would release from the leaking pipeline in 48 hours crude oil lifting operation. An innovative approach is built by designing a new tool to contain oil spills from the source using a pyramid shape tank and safely transport to the temporary storage tank on the diving vessel to keep crude oil lifting process execution still possible to hold while the subsea pipeline repair by installing subsea clamp is undergo. New tools have successfully eliminated oil spill spreading during crude oil lifting takes place schedule. Six crude lifting schedules have been safely delivered with nearly 30,000 liters of crude oil spill have been evacuated and transferred back to processing facilities. Further implementation would possibly be held in pipeline preservation program and diver less application, which can increase leak response time.

Cashew Nut Shell Liquid (CNSL) as a Source of Drugs for Alzheimer’s Disease

Alzheimer’s disease (AD) is a complex neurodegenerative disorder with a multifaceted pathogenesis. This fact has long halted the development of effective anti-AD drugs. Recently, a therapeutic strategy based on the exploitation of Brazilian biodiversity was set with the aim of discovering new disease-modifying and safe drugs for AD. In this review, we will illustrate our efforts in developing new molecules derived from Brazilian cashew nut shell liquid (CNSL), a natural oil and a byproduct of cashew nut food processing, with a high content of phenolic lipids. The rational modification of their structures has emerged as a successful medicinal chemistry approach to the development of novel anti-AD lead candidates. The biological profile of the newly developed CNSL derivatives towards validated AD targets will be discussed together with the role of these molecular targets in the context of AD pathogenesis.