Numerical simulation of water entry problems considering air effect using a multiphase Riemann-SPH model

The water entry is a classic fluid-structure interaction problem in ocean engineering. The prediction of impact loads on structure during the water entry is critical to some engineering applications. In this paper, a multiphase Riemann-SPH model is developed to investigate water entry problems. In this model, a special treatment, a cut-off value for the particle density, is arranged to avoid the occurrence of negative pressure. A remarkable advantage of the present multiphase SPH model is that the real speed of sound in air can be allowed when simulating water-air flows. In the present work, considering the air effect, several typical water entry problems are studied, and the evolution of multiphase interface, the motion characteristic of structure and complex fluid-structure interactions during the water entry are analyzed. Compared with the experimental data, the present multiphase SPH model can obtain satisfactory results, and it can be considered as a reliable tool in reproducing some fluid-structure interaction problems.

Thermal Analysis In Fixed, Flowed And Airless Environment For Cooling In Led Luminaires

In this study, a simulation study was conducted for the loss of efficiency caused by the heat emitted by the LED chips. The temperature change of LED luminaire was analysed for three different scenarios using finite element method. Due to the increase in the internal temperature of the luminaire and due to the air effect inside the LED luminaires, failure of the LEDs has been tried to be prevented. For this purpose, a passive cooling method was proposed in the simulation environment. So, in high power LED luminaires, the high heat emitted by the LED chips is reduced to low heat by an air flow method. In this way, efficiency in LED outputs has been achieved.

Heterogeneous ozone effects on the DNA methylome of bronchial cells observed in a crossover study

We used a randomized crossover experiment to estimate the effects of ozone (vs. clean air) exposure on genome-wide DNA methylation of target bronchial epithelial cells, using 17 volunteers, each randomly exposed on two separated occasions to clean air or 0.3-ppm ozone for two hours. Twenty-four hours after exposure, participants underwent bronchoscopy to collect epithelial cells whose DNA methylation was measured using the Illumina 450 K platform. We performed global and regional tests examining the ozone versus clean air effect on the DNA methylome and calculated Fisher-exact p-values for a series of univariate tests. We found little evidence of an overall effect of ozone on the DNA methylome but some suggestive changes in PLSCR1, HCAR1, and LINC00336 DNA methylation after ozone exposure relative to clean air. We observed some participant-to-participant heterogeneity in ozone responses.

Palladium (II)–Salan Complexes as Catalysts for Suzuki–Miyaura C–C Cross-Coupling in Water and Air. Effect of the Various Bridging Units within the Diamine Moieties on the Catalytic Performance

Water-soluble salan ligands were synthesized by hydrogenation and subsequent sulfonation of salens (N,N’-bis(slicylidene)ethylenediamine and analogues) with various bridging units (linkers) connecting the nitrogen atoms. Pd (II) complexes were obtained in reactions of sulfosalans and [PdCl4]2−. Characterization of the ligands and complexes included extensive X-ray diffraction studies, too. The Pd (II) complexes proved highly active catalysts of the Suzuki–Miyaura reaction of aryl halides and arylboronic acid derivatives at 80 °C in water and air. A comparative study of the Pd (II)–sulfosalan catalysts showed that the catalytic activity largely increased with increasing linker length and with increasing steric congestion around the N donor atoms of the ligands; the highest specific activity was 40,000 (mol substrate) (mol catalyst × h)−1. The substrate scope was explored with the use of the two most active catalysts, containing 1,4-butylene and 1,2-diphenylethylene linkers, respectively.