FINANCIAL ANALYSIS OF GREEN PETROLEUM COKE AS A COAL BLEND IN STEEL INDUSTRY TO SUPPORT NATIONAL ENERGY SECURITY

Green Petroleum Coke (GPC), produced by Pertamina RU II Dumai, is the product of refined petroleum, which still has good quality but has not been utilized to its full potential. Such as Sulfur 0.5%; FC 86.03%; Ash 0.10%; VM 13.82%; Moist 10, 52%; and the calorific value of 7500 kcal/kg. Therefore, one effort that can do is diversification, namely the use of GPC as a mixture of other fuels (fossil) to increase the selling value of GPC. This diversification is also in line with the national energy policy in PP. 79/2014 that the program aims to increase the availability of national energy sources. This study aims to determine the feasibility of using GPC as a coal mixture in Industry (Krakatau Steel) with an overview of economic aspects. Data obtained by qualitative methods consisting of interviews, observation, and documentation. Based on the research results from 2 scenarios, both scenario 1 (GPC 4%) and scenario 2 (GPC 18%), it is found that the NPV is positive, IRR is above the discount rate, and BCR> 1. Thus, the use of GPC as a coal mixture is considered feasible to run and can support national energy security.Keywords: Diversification, Feasibility, Petroleum Coke, Investment DecisionJEL: G11, G32

A synergy model of material and energy flow analysis for the calcination process of green petroleum coke in rotary kiln

The main objective of this paper is to establish a mathematical framework to analyze the complex material and energy performance of the calcinations process based on the fundamental mass and energy conservations. The synergy degree of vital order parameters was defined and evaluated to assess the status and order of the calcination process. Furthermore, the synergy model for resource utilization and energy saving has also been developed. The results show that the energy efficiencies of the drying kiln, rotary kiln, incinerator and the cooler are 63.574%, 37.709%, 76.782% and 74.758%, respectively. Meanwhile, the synergy degree of the whole calcination system is determined as 0.507. Based on the result, several suggestions were proposed to improve the resource utilization, energy-saving and synergy performance. Assessing the performance of suggested improvements, the synergy degree was re-evaluated and recorded a substantial enhancement up to 0.809. The present work provides valuable insights and comprehensive analysis tool for assessing the performance and potential optimization of the calcination process.

Efficient Removal of Bisphenol A Using Nitrogen-Doped Graphene-Like Plates from Green Petroleum Coke

Green petroleum coke, a form of industrial waste produced in the oil-refining process, was used to synthesize nitrogen-doped graphene-like plates (N-GLPs) together with melamine. In this study, characterization and batch experiments were performed to elucidate the interaction mechanism of N-GLPs and bisphenol A (BPA). Structural analysis of N-GLPs, including scanning electron microscopy (SEM), X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), Brunauer-Emmett-Teller (BET), and X-ray photoelectron spectroscopy (XPS), showed an obvious graphene-like structure and successful nitrogen doping. In addition, compared with 8.0 m2/g for green petroleum coke, the BET surface area of N-GLPs markedly increased to 96.6 m2/g. The influences of various factors, including contact time, temperature, and initial pH on BPA removal efficiency were investigated. It was found that 92.0% of BPA was successfully removed by N-GLPs at 50 °C. Based on the adsorption experiments, it was shown that electrostatic attraction, hydrogen bonding, and π-π interaction enhanced the adsorption capacity of N-GLPs for BPA. According to the thermodynamic data, the adsorption process was spontaneous, physical, and endothermic in nature. Therefore, N-GLPs are efficient adsorbent material to remove BPA from wastewater.