Docked ions: vertical-aligned tubular arrays for highly efficient capacitive deionization

Capacitive deionization (CDI) is an effective method for desalination of brackish water to alleviate the global freshwater crisis. Obtaining high desalination capacity is the primary focus of this field. Based on electrical double layer (EDL) theory, current research is mainly devoted to increasing the specific surface area of electrode materials, however, the NaCl adsorption capacity is typically limited to the range of 10 - 20 mg g−1. In this work, we propose a new design paradigm of using a vertical-aligned nanotubular structure for CDI. This design allows ions to be temporarily held inside the electrodes like ships docked in a harbor (ion-docking effect, IDE) due to the greatly diminished water flow inside the tubes, thus enhancing the desalination capacity. As a result, the obtained CDI device based on vertical-aligned nanotubular P-TiO2 arrays shows an ultra-high NaCl adsorption capacity of ~60 mg g−1 within 30 minutes in 0.01 mol L−1 NaCl solution under 1.2 V, corresponding to a rapid average adsorption rate of 2 mg g−1 min−1. Moreover, the adsorption capacity could be further increased up to 121 and 136 mg g−1 under 1.2 and 1.5 V for 2.5 hours adsorption, respectively, but still far from its equilibrium value. Finally, experiments and theoretical simulations are combined to further understand the IDE in CDI. This work highlights the discovery and the utilization of IDE in CDI, and provides new guidance for the design of CDI electrodes and can facilitate the development of CDI technology.

The energy-absorbing characteristics of tubular sandwich structures

The energy-absorbing response of sandwich structures with exceptionally high levels of energy absorption is investigated. The sandwich panels are produced by fixing small composite tubes onto metal facings with surface features that reflect the internal geometry of the tubing. Small diameter tubes are employed to manufacture the cores, since it is well established that the specific energy absorption (SEA) characteristics of a composite tube increase as the inner dimension (diameter or wall-to-wall) to thickness ratio decreases. Tests have been undertaken on tubular arrays based on both circular and square composite tubes. The effect of varying the areal density of the tubular array within the core was investigated by systematically increasing the number of tubes from one to nine. An examination of the composites during the crushing process indicated that all of the tubes failed in a splaying process, involving significant fracturing of fibers and longitudinal splitting. The measured values of SEA remained relatively constant in most cases as the areal density of the tubular arrangement was increased, suggesting that cores could readily be designed to absorb known levels of applied external energy. Arrays based on circular tubes offered higher energy-absorbing characteristics than their square counterparts, with values in excess of 100 kJ/kg being recorded in some cases. It is believed that these tubular sandwich structures offer potential for use in components that are subjected to extreme dynamic loading, such as those associated with impact and blast.

2D CoOOH Sheet-Encapsulated Ni2P into Tubular Arrays Realizing 1000 mA cm−2-Level-Current-Density Hydrogen Evolution Over 100 h in Neutral Water

Water electrolysis at high current density (1000 mA cm−2 level) with excellent durability especially in neutral electrolyte is the pivotal issue for green hydrogen from experiment to industrialization. In addition to the high intrinsic activity determined by the electronic structure, electrocatalysts are also required to be capable of fast mass transfer (electrolyte recharge and bubble overflow) and high mechanical stability. Herein, the 2D CoOOH sheet-encapsulated Ni2P into tubular arrays electrocatalytic system was proposed and realized 1000 mA cm−2-level-current-density hydrogen evolution over 100 h in neutral water. In designed catalysts, 2D stack structure as an adaptive material can buffer the shock of electrolyte convection, hydrogen bubble rupture, and evolution through the release of stress, which insure the long cycle stability. Meanwhile, the rich porosity between stacked units contributed the good infiltration of electrolyte and slippage of hydrogen bubbles, guaranteeing electrolyte fast recharge and bubble evolution at the high-current catalysis. Beyond that, the electron structure modulation induced by interfacial charge transfer is also beneficial to enhance the intrinsic activity. Profoundly, the multiscale coordinated regulation will provide a guide to design high-efficiency industrial electrocatalysts.

Photoactive Anode of NiO/TiO2 Nanotube p-n Junctions and Application in Photoassisted Water Electrolysis

The photoactive anode was fabricated by hydrothermal method using the ZnO nanorod array as the template. NiO nanoflakes were assembled on the TiO2 tubular arrays to form p-n junction heterostrucutures on the Ni substrate. The water electrolysis was coupled with photocatalytic decomposition of water by irradiation of UV and UV-visible light on the modified Ni anode. Under UV and UV-visible light irradiation, the hydrogen evolution rates of the photoactive Ni anode modified by NiO/TiO2 nanotube composites are 2.92 ml/h·cm2 and 3.16 ml/h·cm2 respectively, increased by 5.4 % and 15 % in comparison with that of the Ni anode modified by TiO2 nanotube array and showed 152 % and 172 % improvement in comparison with that of sole Ni anode respectively.

Polyoxometalate-based layered nano-tubular arrays: facile fabrication and superior performance for catalysis

Keggin-type polyoxoanion PW12O403−-containing one-dimensional nano-tubular arrays fabricated within porous templates show a superior performance just through simple filtrating processes.