Characteristics of polymetallic enrichment on oceanic red bed in Matano Formation, Baturubei, Central Sulawesi, Indonesia

The Matano Formation on Sulawesi Island has Cretaceous oceanic red bed (CORB) facies, but there is no further research on the geochemical characteristics of the sedimentary rocks. This study aims to classify the CORB of the Matano Formation and reveal the polymetallic element enrichment in CORB by using the X-ray fluorescence (XRF) analysis method. Matano Formation in the research area consists of two different facies: radiolarites facies and red clay facies. Radiolarites facies grouped as Si-ORB, dominated by siliceous pelagic bioclastic and deposited under oxic environment. The red clay facies grouped as Al-ORB, the components dominated by hemipelagic material with a small amount of silica shelled pelagically and deposited under reduction environment. Red clay facies have higher enrichment elements Mn, V, Ni, Zn and La than radiolarites facies. Oceanic red bed facies of Matano Formation deposited in basin plain environment below carbonate compensation depth in a passive margin tectonic setting.

The carbonate compensation depth in the South Atlantic Ocean since the Late Cretaceous

Deep-sea carbonate deposition is a complex process that is encapsulated in the carbonate compensation depth (CCD)—a facies boundary separating calcareous sediments from non-carbonates. Knowing how the CCD has varied over time is important for understanding and predicting the distribution of seafloor sediments and assessing their role in the global carbon cycle. We focus on the South Atlantic Ocean where the most recent CCD curve is based on Deep Sea Drilling Project (DSDP) Leg 73 sites drilled in 1980 in the South Atlantic Ocean. We compute the South and central South Atlantic CCD from the Late Cretaceous to the present day using updated age models from 45 DSDP and Ocean Drilling Program sites and backtracking with lithology-specific decompaction, eustasy, and dynamic topography. Our models extend further back in time and show more fluctuations than previous reconstructions, with the CCD varying by hundreds of meters during a span of 2–3 m.y. The addition of eustasy and dynamic topography deepens the CCD by as much as 500 m between 74 Ma and 45 Ma, and by ~200 m during the Cenozoic. The central South Atlantic CCD diverges from the average South Atlantic CCD during the Eocene and Miocene, when it was ~1 km shallower. These regional deviations may be due to changes in primary productivity and/or carbonate dissolution leading to reduced carbonate accumulation rates. Our CCD curves highlight the importance of regional processes in carbonate deposition across the South Atlantic and provide improved constraints for the modeling of geochemical cycles.

Supplemental Material: The carbonate compensation depth in the South Atlantic Ocean since the Late Cretaceous

Description of datasets and data sources, Figures S1–S14, and Table S1.<br>

Supplemental Material: The carbonate compensation depth in the South Atlantic Ocean since the Late Cretaceous

Description of datasets and data sources, Figures S1–S14, and Table S1.<br>

Geomorphometric descriptions of archipelagic aprons off the southern flanks of French Frigate Shoals and Necker Island edifices, Northwest Hawaiian Ridge

This study describes the geomorphometries of archipelagic aprons on the southern flanks of the French Frigate Shoals and Necker Island edifices on the central Northwest Hawaiian Ridge that are hotspot volcanoes that have been dormant for 10−11 m.y. The archipelagic aprons are related to erosional headwall scarps and gullies on landslide surfaces but also include downslope gravitational features that include slides, debris avalanches, bedform fields, and outrunners. Some outrunners are located 85 km out onto the deep seafloor in water depths of 4900 m. The bedforms are interpreted to be the result of slow downslope sediment creep rather than products of turbidity currents. The archipelagic aprons appear to differ in origin from those off the Hawaiian Islands. The landslides off the Hawaiian Islands occurred because of oversteepening and loading during the constructive phase of the islands whereas the landslides off the French Frigate Shoals and Necker Island edifices may have resulted from vertical tectonics due to the uplift and relaxation of a peripheral bulge or isolated earthquakes long after the edifices passed beyond the hotspot. The lack of pelagic drape in water depths above the 4600 m depth of the local carbonate compensation depth suggests that the archipelagic apron off the French Frigate Shoals edifice is much younger, perhaps Quaternary in age, than that off the Necker Island edifice, which has a 50 m pelagic drape. The pelagic drape off the Necker Island edifice suggests that the landslides may be as old as 9 Ma. The lack of pelagic drape off the French Frigate Shoals edifice suggests that the most recent landslides are more recent, perhaps even Quaternary in age. The presence of a chute-like feature on the mid-flank of the French Frigate Shoals edifice appears to be the result of rejuvenated volcanism that occurred long after the initial volcanism ceased to build the edifice.

Sedimentary and volcanic record of the nascent Izu-Bonin-Mariana arc from IODP Site U1438

The oldest known, intact sedimentary record of a nascent intraoceanic arc was recovered in a ∼100-m-thick unit (IV) above ca. 49 Ma basaltic basement at International Ocean Discovery Program Site U1438 in the Amami Sankaku Basin. During deposition of Unit IV the site was located ∼250 km from the plate edge, where Izu-Bonin-Mariana subduction initiated at 52 Ma. Basement basalts are overlain by a mudstone-dominated subunit (IVC) with a thin basal layer of dark brown metalliferous mudstone followed by mudstone with sparse, graded laminae of amphibole- and biotite-bearing tuffaceous sandstone and siltstone. Amphibole and zircon ages from these laminae suggest that the intermediate subduction-related magmatism that sourced them initiated at ca. 47 Ma soon after basement formation. Overlying volcaniclastic, sandy, gravity-flow deposits (subunit IVB) have a different provenance; shallow water fauna and tachylitic glass fragments indicate a source volcanic edifice that rose above the carbonate compensation depth and may have been emergent. Basaltic andesite intervals in upper subunit IVB have textures suggesting emplacement as intrusions into unconsolidated sediment on a volcanic center with geochemical and petrological characteristics of mafic, differentiated island arc magmatism. Distinctive Hf-Nd isotope characteristics similar to the least-radiogenic Izu-Bonin-Mariana boninites support a relatively old age for the basaltic andesites similar to detrital amphibole dated at 47 Ma. The absence of boninites at that time may have resulted from the position of Site U1438 at a greater distance from the plate edge. The upper interval of mudstone with tuffaceous beds (subunit IVA) progresses upsection into Unit III, part of a wedge of sediment fed by growing arc-axis volcanoes to the east. At Site U1438, in what was to become a reararc position, the succession of early extensional basaltic magmatism associated with spontaneous subduction initiation is followed by a rapid transition into potentially widespread subduction-related magmatism and sedimentation prior to the onset of focused magmatism and major arc building.

Late Miocene to Holocene high-resolution eastern equatorial Pacific carbonate records: stratigraphy linked by dissolution and paleoproductivity

Coherent variation in CaCO3 burial is a feature of the Cenozoic eastern equatorial Pacific. Nevertheless, there has been a long-standing ambiguity in whether changes in CaCO3 dissolution or changes in equatorial primary production might cause the variability. Since productivity and dissolution leave distinctive regional signals, a regional synthesis of data using updated age models and high-resolution stratigraphic correlation is an important constraint to distinguish between dissolution and production as factors that cause low CaCO3. Furthermore, the new chronostratigraphy is an important foundation for future paleoceanographic studies. The ability to distinguish between primary production and dissolution is also important to establish a regional carbonate compensation depth (CCD). We report late Miocene to Holocene time series of XRF-derived (X-ray fluorescence) bulk sediment composition and mass accumulation rates (MARs) from eastern equatorial Pacific Integrated Ocean Drilling Program (IODP) sites U1335, U1337, and U1338 and Ocean Drilling Program (ODP) site 849, and we also report bulk-density-derived CaCO3 MARs at ODP sites 848, 850, and 851. We use physical properties, XRF bulk chemical scans, and images along with available chronostratigraphy to intercorrelate records in depth space. We then apply a new equatorial Pacific age model to create correlated age records for the last 8 Myr with resolutions of 1–2 kyr. Large magnitude changes in CaCO3 and bio-SiO2 (biogenic opal) MARs occurred within that time period but clay deposition has remained relatively constant, indicating that changes in Fe deposition from dust is only a secondary feedback to equatorial productivity. Because clay deposition is relatively constant, ratios of CaCO3 % or biogenic SiO2 % to clay emulate changes in biogenic MAR. We define five major Pliocene–Pleistocene low CaCO3 % (PPLC) intervals since 5.3 Ma. Two were caused primarily by high bio-SiO2 burial that diluted CaCO3 (PPLC-2, 1685–2135 ka, and PPLC-5, 4465–4737 ka), while three were caused by enhanced dissolution of CaCO3 (PPLC-1, 51–402 ka, PPLC-3, 2248–2684 ka, and PPLC-4, 2915–4093 ka). Regional patterns of CaCO3 % minima can distinguish between low CaCO3 caused by high diatom bio-SiO2 dilution versus lows caused by high CaCO3 dissolution. CaCO3 dissolution can be confirmed through scanning XRF measurements of Ba. High diatom production causes lowest CaCO3 % within the equatorial high productivity zone, while higher dissolution causes lowest CaCO3 percent at higher latitudes where CaCO3 production is lower. The two diatom production intervals, PPLC-2 and PPLC-5, have different geographic footprints from each other because of regional changes in eastern Pacific nutrient storage after the closure of the Central American Seaway. Because of the regional variability in carbonate production and sedimentation, the carbonate compensation depth (CCD) approach is only useful to examine large changes in CaCO3 dissolution.