Determination of a Surrogate Toxic Metal in a Simulated Hazardous Waste Sample

Author(s):  
Anthony G. Davies ◽  
Jillian A. Sleep

There is now a substantial body of evidence that the growth rates of phytoplankton in culture are more closely related to the cellular levels of the rate-limiting constituent, be it a nutrient, micronutrient or toxic metal, than to the concentrations in the supporting medium; nitrate, Caperon (1968); phosphate, Fuhs (1969); silicate, Paasche (1973); vitamin B12, Droop (1968); iron, Davies (1970); mercury, Davies (1974); cadmium, Davies (1978a). This has suggested the requirement for a technique which would allow the determination of comparable relationships for natural populations of phytoplankton - how, for instance, their carbon fixation rates depend upon the metal contents of the plant cells. Although the effects of metals upon carbon fixation in phytoplankton assemblages from several different sea areas have already been examined (Knauer & Martin, 1972; Patin et al. 1974; Zingmark & Miller, 1975; Ibragim & Patin, 1976) no data seem to have been obtained on the levels of the metals present in the phytoplankton at the time of the measurements.


Author(s):  
MA Bianchini ◽  
RJ Portier ◽  
K Fujisaki ◽  
CB Henry ◽  
PH Templet ◽  
...  

Sensors ◽  
2011 ◽  
Vol 11 (4) ◽  
pp. 3970-3987 ◽  
Author(s):  
Chandre M. Willemse ◽  
Khotso Tlhomelang ◽  
Nazeem Jahed ◽  
Priscilla G. Baker ◽  
Emmanuel I. Iwuoha

2020 ◽  
Vol 145 ◽  
pp. 111651
Author(s):  
Ye Ji Koo ◽  
Eun Chul Pack ◽  
Ye Jin Lee ◽  
Hyung Soo Kim ◽  
Dae Yong Jang ◽  
...  

1991 ◽  
Vol 24 (12) ◽  
pp. 193-200 ◽  
Author(s):  
J. R. Cláudio

From July, 1986 to March, 1987, the author developed laboratory, tests on cementation of electroplating wastewater treatment sludges. Perfomed at the laboratories of Escola Politécnica of the University of São Paulo and of CETESB, tests were conducted with three types of cement produced in Brazil: CPC - Portland Cement, POZ pozzolanic cement and CAF - blast furnace cement. The tests had the following steps:–characterization of electroplating industry wastewater treatment sludge and study of the sludge - cement mixtures;–preparation of sludge - cement mixtures with 3 different water/cement ratios;–measurements of mixture consistency with Casagrande soil mechanics equipment;–determination of leaching quality and resistance to compression of solidified specimen at 3 ages;–analytical determination in the sludge-cement mixture;–test for solubility in water;–analytical determination of cyanide and heavy metals in the cure water of specimen. Results showed that solidification with cement is an efficient technology for the fixation of toxic metal ions such as Cd, Hg and Pb and other metals such as Cr, Ni, Cu or Zn present in large concentrations in electroplating wastewater treatment sludges. With the only exception of Al+++ the other metallic ions determined in the leachate showed concentrations below drinking water standards. As to mechanical resistance after 90 days, the sludge - cement mixtures presented a performance similar to that of structural concrete.


Nanomaterials ◽  
2021 ◽  
Vol 11 (11) ◽  
pp. 3082
Author(s):  
Ekta ◽  
Divya Utreja

We have synthesized sulfonamide based nano-composites of SiO2 and TiO2 for selective and sensitive determination of toxic metal ion Hg2+ in aqueous medium. Nano-composites (11) and (12) were morphologically characterized with FT-IR, solid state NMR, UV-vis, FE SEM, TEM, EDX, BET, pXRD and elemental analysis. The comparative sensing behavior, pH effect and sensor concentrations were carried out with fluorescence signaling on spectrofluorometer and nano-composites (11) and (12), both were evaluated as “turn-on” fluorescence detector for the toxic Hg2+ ions. The LODs were calculated to be 41.2 and 18.8 nM, respectively of nano-composites (11) and (12). The detection limit of TiO2 based nano-composites was found comparatively lower than the SiO2 based nano-composites.


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