Electronic Conductive Inorganic Cathodes Promising High‐Energy Organic Batteries

2021 ◽  
Vol 33 (8) ◽  
pp. 2005781
Author(s):  
Minglei Mao ◽  
Shu Wang ◽  
Zejing Lin ◽  
Tao Liu ◽  
Yong‐Sheng Hu ◽  
...  
2020 ◽  
Vol 10 (32) ◽  
pp. 2001635 ◽  
Author(s):  
Sechan Lee ◽  
Kyunam Lee ◽  
Kyojin Ku ◽  
Jihyun Hong ◽  
Soo Young Park ◽  
...  

Nano Research ◽  
2020 ◽  
Author(s):  
Youngjin Ham ◽  
Vitalii Ri ◽  
Jin Kim ◽  
Yeoheung Yoon ◽  
Jinho Lee ◽  
...  

2019 ◽  
Author(s):  
Bruno Ernould ◽  
Louis Sieuw ◽  
Gabriella Barozzino-Consiglio ◽  
Jean-François Gohy ◽  
Alexandru Vlad

Fire-retardant electrolyte chemistries have attracted great attention given their potential to solve the grand challenges of alkali-ion batteries : safety, use of metallic anodes and anodic stability. Whereas extensive analysis and correlations are drawn to explain their unusual electrochemical behaviour, one essential property, their effects on redox potentials of battery components (redox potential shift) pervasively lack a strict description and quantification. Here we show that the strong solvation of lithium cations by organic phosphates, the widely used flame-retardant constituents, induces a negative redox potential shift by as much as 500mV. We demonstrate that the redox potential shift is characteristic of Li-cation (de)-solvation processes whereas negligible for other processes. This has important consequences for high energy hybrid battery concepts such as high voltage dual-ion graphite or organic batteries. These findings also shine a different light on the enhanced anodic stability of these non-conventional battery electrolyte formulations.


2019 ◽  
Author(s):  
Bruno Ernould ◽  
Louis Sieuw ◽  
Gabriella Barozzino-Consiglio ◽  
Jean-François Gohy ◽  
Alexandru Vlad

Fire-retardant electrolyte chemistries have attracted great attention given their potential to solve the grand challenges of alkali-ion batteries : safety, use of metallic anodes and anodic stability. Whereas extensive analysis and correlations are drawn to explain their unusual electrochemical behaviour, one essential property, their effects on redox potentials of battery components (redox potential shift) pervasively lack a strict description and quantification. Here we show that the strong solvation of lithium cations by organic phosphates, the widely used flame-retardant constituents, induces a negative redox potential shift by as much as 500mV. We demonstrate that the redox potential shift is characteristic of Li-cation (de)-solvation processes whereas negligible for other processes. This has important consequences for high energy hybrid battery concepts such as high voltage dual-ion graphite or organic batteries. These findings also shine a different light on the enhanced anodic stability of these non-conventional battery electrolyte formulations.


2021 ◽  
Vol 2021 ◽  
pp. 1-9
Author(s):  
Jan Bitenc ◽  
Urban Košir ◽  
Alen Vizintin ◽  
Niklas Lindahl ◽  
Andraž Krajnc ◽  
...  

Al metal-organic batteries are a perspective high-energy battery technology based on abundant materials. However, the practical energy density of Al metal-organic batteries is strongly dependent on its electrochemical mechanism. Energy density is mostly governed by the nature of the aluminium complex ion and utilization of redox activity of the organic group. Although organic cathodes have been used before, detailed study of the electrochemical mechanism is typically not the primary focus. In the present work, electrochemical mechanism of Al metal-phenanthrenequinone battery is investigated with a range of different analytical techniques. Firstly, its capacity retention is optimized through the preparation of insoluble cross-coupled polymer, which exemplifies extremely low capacity fade and long-term cycling stability. Ex situ and operando ATR-IR confirm that reduction of phenanthrenequinone group proceeds through the two-electron reduction of carbonyl groups, which was previously believed to exchange only one-electron, severely limiting cathode capacity. Nature of aluminium complex ion interacting with organic cathode is determined through multiprong approach using SEM-EDS, XPS, and solid-state NMR, which all point to the dominant contribution of AlCl2+ cation. Upon full capacity utilization, Al metal-polyphenanthrenequinone battery utilizing AlCl2+ offers an energy density of more than 200 Wh/kg making it a viable solution for stationary electrical energy storage.


2021 ◽  
Vol 57 (82) ◽  
pp. 10791-10794
Author(s):  
Zifeng Chen ◽  
Pengfei Sun ◽  
Panxing Bai ◽  
Hai Su ◽  
Jixing Yang ◽  
...  

A poorly soluble and high energy density organic compound is reported for lithium battery cathode materials, delivering a high energy density of 1392 W h kg−1. This work provides a strategy for realizing high energy density lithium–organic batteries.


1984 ◽  
Vol 75 ◽  
pp. 599-602
Author(s):  
T.V. Johnson ◽  
G.E. Morfill ◽  
E. Grun

A number of lines of evidence suggest that the particles making up the E-ring are small, on the order of a few microns or less in size (Terrile and Tokunaga, 1980, BAAS; Pang et al., 1982 Saturn meeting; Tucson, AZ). This suggests that a variety of electromagnetic and plasma affects may be important in considering the history of such particles. We have shown (Morfill et al., 1982, J. Geophys. Res., in press) that plasma drags forces from the corotating plasma will rapidly evolve E-ring particle orbits to increasing distance from Saturn until a point is reached where radiation drag forces acting to decrease orbital radius balance this outward acceleration. This occurs at approximately Rhea's orbit, although the exact value is subject to many uncertainties. The time scale for plasma drag to move particles from Enceladus' orbit to the outer E-ring is ~104yr. A variety of effects also act to remove particles, primarily sputtering by both high energy charged particles (Cheng et al., 1982, J. Geophys. Res., in press) and corotating plasma (Morfill et al., 1982). The time scale for sputtering away one micron particles is also short, 102 - 10 yrs. Thus the detailed particle density profile in the E-ring is set by a competition between orbit evolution and particle removal. The high density region near Enceladus' orbit may result from the sputtering yeild of corotating ions being less than unity at this radius (e.g. Eviatar et al., 1982, Saturn meeting). In any case, an active source of E-ring material is required if the feature is not very ephemeral - Enceladus itself, with its geologically recent surface, appears still to be the best candidate for the ultimate source of E-ring material.


Sign in / Sign up

Export Citation Format

Share Document