<p>The development and enrichment of
organic materials with narrowband emission in longer wavelength region beyond
515 nm still remains a great challenge. Herein, a series of unique narrowband
green thermally activated delayed fluorescence (TADF) emitters has been
constructed based on a synthetic strategy by localized attachment of acceptor
onto B-N-containing multiple resonance (MR) framework. The precise modulation
of acceptor is an ingenious approach for achieving bathochromic shift and
narrowband emission, simultaneously. Furthermore, an important synthetic
methodology has been proposed to functionalize MR skeleton and generate a
universal building block, which can be utilized to construct multifarious TADF
materials with ultrahigh color purity through a simple one-step Suzuki coupling
reaction. The DtCzB-TPTRZ-based organic light-emitting diode (OLED) exhibits
pure green emission with Commission Internationale de L’Eclairage (CIE)
coordinates of (0.23, 0.68), and achieves remarkable maximum external quantum
efficiency (EQE) of 30.6% with low efficiency roll-off.</p>