Structure–property behavior of UV-curable polyepoxy–acrylate hybrid materials prepared via sol–gel process

This work successfully prepared an UV curable organic-inorganic hybrid material consisting of organic modified colloidal silica. Applications of UV curable organic-inorganic hybrid materials include abrasion resistant coatings, photo-patternable thin films and waveguides. Colloidal silica containing reactive functional groups were also prepared by reacting organic silane and tetraethyl orthosilicate (TEOS) using sol-gel process. In addition, the efficiency of grafting organic moiety onto silica nanoparticles was investigated by applying TGA and FTIR techniques. Experimental results indicated a strong interdependence between surface modification efficiency and solution pH. Acrylate-SiO2 hybrid formation could result in a shifting of thermal degradation temperature of organic component from about 200°C to near 400°C. In addition, the stability of organic modified colloidal silica in UV curable formula and the physical properties of resulting coatings were discussed. Furthermore, the morphology of organic modified colloidal silica was investigated by performing TEM and SEM studies‥

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Structure-property behavior of new hybrid materials incorporating oligomeric poly(tetramethylene oxide) with inorganic silicates by a sol-gel process

Polymer Bulletin ◽

10.1007/bf00275602 ◽

1987 ◽

Vol 18 (5) ◽

Cited By ~ 71

Author(s):

Hao-Hsin Huang ◽

GarthL. Wilkes

Keyword(s):

Hybrid Materials ◽

Sol Gel ◽

Structure Property ◽

Sol Gel Process ◽

Tetramethylene Oxide

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Characterization and properties of UV-curable polyurethane-acrylate/silica hybrid materials prepared by the sol-gel process

Polymer International ◽

10.1002/pi.1536 ◽

2004 ◽

Vol 53 (10) ◽

pp. 1431-1435 ◽

Cited By ~ 11

Author(s):

Ling Zhang ◽

Zhaohua Zeng ◽

Jianwen Yang ◽

Yonglie Chen

Keyword(s):

Hybrid Materials ◽

Sol Gel ◽

Uv Curable ◽

Polyurethane Acrylate ◽

Sol Gel Process ◽

Silica Hybrid

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Synthesis of silsesquioxane urethane hybrid materials by a modified sol–gel process

New Journal of Chemistry ◽

10.1039/c5nj00960j ◽

2015 ◽

Vol 39 (12) ◽

pp. 9789-9799 ◽

Cited By ~ 1

Author(s):

Sizhe Wang ◽

Guangli Li ◽

John J. Chiao ◽

Z. Jeffrey Wang ◽

Yanwen Yvonne Duan

Keyword(s):

Functional Groups ◽

Hybrid Materials ◽

Sol Gel ◽

Uv Curable ◽

Sol Gel Process ◽

Molecular Hybrids ◽

The Stability

UV-curable molecular hybrids were prepared by a sol–gel process that could be adopted industrially. The stability was improved and additional functional groups introduced.

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The preparation of poly(methylsilsesquioxane) network-polyimide hybrid materials by the sol-gel process and their properties

High Performance Polymers ◽

10.1088/0954-0083/6/1/005 ◽

1994 ◽

Vol 6 (1) ◽

pp. 43-52 ◽

Cited By ~ 24

Author(s):

Yoshitake Iyoku ◽

Masa-aki Kakimoto ◽

Yoshio Imai

Keyword(s):

Hybrid Materials ◽

Sol Gel ◽

Tensile Modulus ◽

Hybrid Films ◽

Elongation At Break ◽

Dimethyl Acetamide ◽

Flexible Films ◽

Sol Gel Process ◽

Heating Up ◽

Silicone Content

Poly(methylsilsesquixoane) network (silicone)-polyimide hybrid materials were successfully prepared by the sol-gel reaction of methyltriethoxysilane (MTES). The ethoxysilyl group in MTES was hydrolyzed and polycondensed in the solution of the polyamic acid, derived from pyromellitic dianhydride and bis(4-aminophenyl)ether, in N,N-dimethyl-acetamide (DMAc). The hybrid films were obtained by casting the reaction mixture, followed by heating up to 300°C. The hybrid materials containing 0-60wt% of silicone afforded flexible films. The films containing less than 7 wt% silicone were yellow and transparent, whereas the films with higher silicone content were yellow and opaque. Silicone particles with a diameter of around 1-10 μm were observed in the fracture surface of the hybrid films by scanning electron microscopy. Although the tensile strength and tensile modulus of the films obtained decreased with increasing silicone content. the value of the elongation at break remained at 60% up to 30% silicone content.

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Organic–inorganic hybrids having a talc-like structure as suitable hosts to guest a wide range of species

Dalton Transactions ◽

10.1039/c7dt03902f ◽

2018 ◽

Vol 47 (9) ◽

pp. 2925-2932 ◽

Cited By ~ 4

Author(s):

J. Brendlé

Keyword(s):

Hybrid Materials ◽

Sol Gel ◽

Step Method ◽

Mild Conditions ◽

Condensation Reactions ◽

Wide Range ◽

Sol Gel Process ◽

Hydrolysis And Condensation ◽

One Step

The sol–gel process involving hydrolysis and condensation reactions is an attractive way to form siloxane based hybrid materials since it is a one-step method performed under mild conditions.

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Homogeneous phase synthesis of chitosan silica hybrid materials in ionic liquid medium and adsorption of Fe(III) from aqueous solutions

Journal of Carbohydrate Chemistry ◽

10.1080/07328303.2019.1663205 ◽

2019 ◽

Vol 38 (9) ◽

pp. 586-597 ◽

Cited By ~ 2

Author(s):

Ananda S. Amarasekara ◽

Deping Wang

Keyword(s):

Ionic Liquid ◽

Hybrid Materials ◽

Sol Gel ◽

Phase Reaction ◽

Phase Synthesis ◽

Homogeneous Phase ◽

Sol Gel Process ◽

Hydrolysis Of ◽

Silica Hybrid ◽

Ionic Liquid Medium

Two chitosan silica hybrid materials were prepared by a two-step process in 78–84% yields using the homogeneous phase reaction of 3-(triethoxysilyl)propyl isocyanate with chitosan dissolved in 1-n-butyl-3-methylimidazolium chloride ionic liquid (∼10% w/w), which was followed by NH4OH catalyzed hydrolysis of triethoxysilyl groups and then sol-gel process. These new hybrid materials were shown to adsorb up to about 95% of Fe3+ from 5 × 10−4 M aqueous solution at room temperature in 24 h.

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