Effect of bound rubber on characteristics of highly filled styrene-butadiene rubber compounds with different types of carbon black

2004 ◽  
Vol 93 (3) ◽  
pp. 1001-1006 ◽  
Author(s):  
Sung-Seen Choi
Keyword(s):  
Carbon Black ◽  
Styrene Butadiene Rubber ◽  
Butadiene Rubber ◽  
Rubber Compounds ◽  
Bound Rubber ◽  
Different Types ◽  
Styrene Butadiene

A Study of the Combined use of Carbon Black and Silica in Tyre Tread Formulations

2018 ◽  
Vol 45 (1) ◽  
pp. 5-9
Author(s):  
A.M. Mokhnatkin ◽  
V.P. Dorozhkin ◽  
E.G. Mokhnatkina ◽  
V.E. Muradyan ◽  
L.A. Zotov ◽  
...  
Keyword(s):  
Carbon Black ◽  
Relaxation Times ◽  
Styrene Butadiene Rubber ◽  
Butadiene Rubber ◽  
Transmission Electron ◽  
Rubber Compounds ◽  
Combined Use ◽  
Different Types ◽  
Styrene Butadiene ◽  
Tread Rubber

A specially designed relaxometer was used to measure the stress relaxation under 30% elongation for tread rubber compounds based on a blend of three rubbers: natural rubber, neodymium butadiene rubber, and oil-extended styrene butadiene rubber. The rubber compounds were filled with carbon black and silica in different ratios: with 80 parts carbon black only, with 80 parts silica only, and with different ratios of carbon black and silica. The method proposed by Bartenev was used to calculate the relaxation specta. The maxima of the spectra at different relaxation times were assigned to different types of interaction: rubber-filler interaction, carbon black-carbon black interaction, silica-silica interaction, carbon black-silica interaction. New maxima were obtained for specimens containing roughly equal amounts of carbon black and silica. These results were compared with data obtained using transmission electron microscopy. The existence of three levels of structure of filled elastomers and the presence of ‘rigid’ rubber around filler particles are suggested.

scholarly journals Insights into the Payne Effect of Carbon Black Filled Styrene-butadiene Rubber Compounds

2020 ◽  
Vol 39 (1) ◽  
pp. 81-90
Author(s):  
An Zhao ◽  
Xuan-Yu Shi ◽  
Shi-Hao Sun ◽  
Hai-Mo Zhang ◽  
Min Zuo ◽  
...  
Keyword(s):  
Carbon Black ◽  
Styrene Butadiene Rubber ◽  
Butadiene Rubber ◽  
Payne Effect ◽  
Rubber Compounds ◽  
Styrene Butadiene

STUDY ON NANOMORPHOLOGY OF HIGH-STRUCTURE CARBON BLACK AND ITS BOUND RUBBER BY AFM

2012 ◽  
Vol 19 (01) ◽  
pp. 1250003
Author(s):  
JIAN CHEN ◽  
YONGZHONG JIN ◽  
JINGYU ZHANG ◽  
YAFENG WU ◽  
CHUNCAI MENG
Keyword(s):  
Carbon Black ◽  
Cluster Structure ◽  
Chemical Activity ◽  
Styrene Butadiene Rubber ◽  
Butadiene Rubber ◽  
Atomic Force ◽  
Filled Rubber ◽  
Bound Rubber ◽  
Styrene Butadiene ◽  
High Structure

Bound rubber in carbon black (CB) filled rubber (natural rubber (NR) and styrene–butadiene rubber (SBS)) was prepared by the solvent method. The nanomorphology of CB and rubber/CB soluble rubber was observed by atomic force microscope. The results show that high-structure CB DZ13 has a "grape cluster" structure which consists of many original particles with the grain size of about 30–50 nm. Graphitizing process of CB decreases the amount of bound rubber. The NR/DZ13 soluble rubber with island–rim structure has been obtained, where the islands are DZ13 particles and the rims around the islands are occupied by NR film. But when the graphitized DZ13 particles were used as fillers of rubber, we have only observed that some graphitized DZ13 particles were deposited on the surface of the globular-like NR molecular chains, instead of the spreading of NR molecular chains along the surface of DZ13 particles, indicating that graphitized DZ13 has lower chemical activity than ungraphitized DZ13. Especially, we have already observed an interesting unusual bound rubber phenomenon, the blocked "bracelet" structure with the diameter of about 600 nm in which CB particles were blocked in ring-shaped SBS monomer.

scholarly journals Use of mesoporous silica as a reinforcing agent in rubber compounds

e-Polymers ◽  
2005 ◽  
Vol 5 (1) ◽  
Author(s):  
Betty L. López ◽  
León Dario Pérez ◽  
Mónica Mesa ◽  
Ligia Sierra ◽  
Eric Devaux ◽  
...  
Keyword(s):  
Mesoporous Silica ◽  
Styrene Butadiene Rubber ◽  
Butadiene Rubber ◽  
Rubber Content ◽  
Scanning Calorimetry ◽  
Rubber Compounds ◽  
Reinforcing Agent ◽  
Bound Rubber ◽  
Filler Dispersion ◽  
Styrene Butadiene

AbstractMesoporous silica is used as filler for styrene-butadiene rubber (SBR); filler-polymer interactions are compared with those exhibited when Ultrasil silica (VN3) is used. A silane coupling agent is added to improve filler dispersion and its influence on the bound-rubber formation is also investigated. The bound-rubber content is higher for the mesoporous silica and increases further for the sample containing silane. The increase is explained by chemical interactions between filler and rubber and penetration of the rubber chains into the mesopores. This is confirmed by 13C solid-state NMR, IR spectroscopy and differential scanning calorimetry. Dynamic mechanical thermal analysis shows higher storage modulus for the rubber filled with mesoporous silica.

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