Eco-efficient concrete, optimized by Alfred’s particle packing model, with partial replacement of Portland cement by stone powder

The partial replacement of clinker by complementary cementitious materials can significantly contribute to the reduction of carbon emissions in the production of concrete. Another alternative to reduce these emissions is to increase the efficiency of the concrete, achieving higher compressive strength with lower consumption of cement. Particle packing models are efficient tools to optimize the composition of the matrix and contribute to the production of more eco-efficient concretes. In this context, the objective of the present study is evaluating the production of concretes with partial replacement of cement by stone powder, optimized by Alfred’s particle packing model, seeking to reduce cement consumption and CO2 emissions per MPa of compressive strength. The replacement content of cement by stone powder was 20% by mass (equivalent to 22.4% by volume). Concretes were produced with different distribution factor (q) - 0.37; 0.21; 0.45 - to verify the influence of fines on the flow between particles and on the efficiency of the produced concrete. The analyses were carried out in terms of properties in the fresh state, hardened state, and sustainability parameters (cement consumptions and CO2 emissions). The application of the proposed method resulted in a higher compressive strength than the expected for the water/cement ratio used (0.5). The most efficient concrete reached the compressive strength of 68 MPa with 240 kg/m3 of cement, which represents 3.5 kg of cement/m3/MPa and 3.1 kg of CO2/m3/MPa, a value below the references found in the literature for conventional concretes. Therefore, the proposed method allows to produce more eco-efficient concrete, contributing to the use of waste and reducing CO2 emissions.

Graphene-Reinforced Carbon-Bonded Coarse-Grained Refractories

Carbon-bonded alumina refractories offer excellent thermal shock performance but are lacking in terms of mechanical strength. In the present contribution, the influence of the particle packing and the addition of graphene oxide (GO) to carbon-bonded alumina refractories on the physical and mechanical properties before and after thermal shock was investigated. Coarse tabular alumina grains were coated by a GO suspension and used to prepare dry-pressed compacts. The included graphite fraction (15 wt%) was either regarded as a lubricating matrix component or as a quasi-spherical component of a calculated density-optimized aggregate size distribution. During coking, the GO was reduced to thermally reduced graphene. The porosity, true density and thermal shock behavior in terms of the cold modulus of rupture (CMOR) and Young’s modulus were compared. Samples with a higher density were obtained when the irregularly shaped graphite was considered as the matrix component (lubricant). The results showed that the use of GO had a positive impact on the mechanical properties of the graphene-reinforced Al2O3–C refractories, especially in the case of a less optimized packing, due to the bridging of delamination gaps. In addition, the thermal shock only had a minor impact on the Young’s modulus and CMOR values of the samples. SEM investigation revealed very similar microstructures in coked as well as thermally shocked samples.

Towards Efficient Use of Cement in Ultra High Performance Concrete

This paper presents an investigation on substituting the cement content with an inert material, in a typical locally produced UHPC mix. A structured literature review was performed to enrichen the discussion and to benchmark the results towards already reported investigations in the research society. Investigations on cement substitution in UHPC are frequently reported. However, usually the cement is substituted with other binding materials – often pozzolanic by-products from other industries. Reports from investigations on the use of inert materials for cement substitution in UHPC seem scarce. An experimental program that included a total of 210 test specimens was executed. This program included evaluating several questions embedded to the problem on how to substitute cement while keeping all other variables constant. It is concluded that up to 40% of the cement can be substituted with an inert material, without significantly changing the flexural tensile strength or compressive strength of the hardened UHPC. Two preconditions were caretaken: the particle packing was maintained by securing that the substitution material had a Particle Size Distribution (PSD) near identical to the cement and that the water balance was maintained through preconditioning of the substitution material. Suggestions are made for improving benchmarking.

Angle-dependent spectrum measurement of polystyrene opal-like structure described by Bragg-Snell diffraction and perturbed photonic band structure

Optical diffraction of opal structure, a colloidal photonic crystal, can be predicted by Bragg-Snell diffraction and photonic band structure. Theoretical prediction and optical measurement are frequently slightly different due to distance variation of particle packing. In this research, opal of 310 nm polystyrene beads was fabricated by self-assembly process and optically investigated in transmission spectra at varied angles. The measured spectra had less agreement to the Bragg-Snell prediction at large angle of detection. To explore influence of packing distance on optical response, photonic band structures were numerically simulated via plane-wave expansion method at presence of perturbed length in primitive lattice vectors. Extending each primitive vector with fixing others provided a different eigen-frequency of the first photonic band, although they had a symmetrical perturbation on (111) face-centered cubic. Perturbation on lattice length became much strong when the disturbing direction was out of eigenstate orientation plane.

Cement Paste Mixture Proportioning with Particle Packing Theory: An Ambiguous Effect of Microsilica

Recently, the research of innovative building materials is focused on applying supplementary materials in the form of micro- and nanopowders in cementitious composites due to the growing insistence on sustainable development. Considering above, in paper, a research on the effect of microsilica and SiO2 nanoparticles addition to cement paste, designed with Andreasen and Andersen (AA) packing density model (PDM), in terms of its physical and mechanical properties was conducted. Density, porosity, compressive strength, hardness, and modulus of indentation were investigated and compared regarding different amount of additives used in cement paste mixes. Microstructure of the obtained pastes was analyzed. The possibility of negative influence of alkali-silica reaction (ASR) on the mechanical properties of the obtained composites was analyzed. The results of the conducted investigations were discussed, and conclusions, also practical, were presented. The obtained results confirmed that the applied PDM may be an effective tool in cement paste design, when low porosity of prepared composite is required. On the other hand, the application of AA model did not bring satisfactory results of mechanical performance as expected, what was related, as shown by SEM imaging, with inhomogeneous dispersion of microsilica, and creation of agglomerates acting as reactive aggregates, what as a consequence caused ASR reaction, crack occurrence and lowered mechanical properties. Finally, the study found that the use of about 7.5% wt. of microsilica is the optimum in regards to obtain low porosity, while, to achieve improved mechanical properties, the use of 4 wt. % of microsilica seems to be optimal, in the case of tested cement pastes.

Large Particle 3D Concrete Printing—A Green and Viable Solution

The Large Particle 3D Concrete Printing (LP3DCP) process presented in this paper is based on the particle bed 3D printing method; here, the integration of significantly larger particles (up to 36 mm) for selective binding using the shotcrete technique is presented. In the LP3DCP process, the integration of large particles, i.e., naturally coarse, crushed or recycled aggregates, reduces the cement volume fraction by more than 50% compared to structures conventionally printed with mortar. Hence, with LP3DCP, the global warming potential, the acidification potential and the total non-renewable primary energy of 3D printed structures can be reduced by approximately 30%. Additionally, the increased proportion of aggregates enables higher compressive strengths than without the coarse aggregates, ranging up to 65 MPa. This article presents fundamental material investigations on particle packing and matrix penetration as well as compressive strength tests and geometry studies. The results of this systematic investigation are presented, and the best set is applied to produce a large-scale demonstrator of one cubic meter of size and complex geometry. Moreover, the demonstrator features reinforcement and subtractive surface processing strategies. Further improvements of the LP3DCP technology as well as construction applications and architectural design potentials are discussed thereafter.