Crystal morphology and isothermal crystallization kinetics of short carbon fiber/poly(ethylene 2,6-naphthalate) composites

2008 ◽  
Vol 108 (1) ◽  
pp. 650-658 ◽  
Author(s):  
Li-Juan Zheng ◽  
Jian-Gang Qi ◽  
Qing-Hong Zhang ◽  
Wen-Feng Zhou ◽  
Dan Liu

Polymers ◽  
2021 ◽  
Vol 13 (4) ◽  
pp. 648
Author(s):  
Xiangning Wen ◽  
Yunlan Su ◽  
Shaofan Li ◽  
Weilong Ju ◽  
Dujin Wang

In this work, the crystallization kinetics of poly(ethylene oxide) (PEO) matrix included with poly(ethylene glycol) (PEG) grafted silica (PEG-g-SiO2) nanoparticles and bare SiO2 were systematically investigated by differential scanning calorimetry (DSC) and polarized light optical microscopy (PLOM) method. PEG-g-SiO2 can significantly increase the crystallinity and crystallization temperature of PEO matrix under the non-isothermal crystallization process. Pronounced effects of PEG-g-SiO2 on the crystalline morphology and crystallization rate of PEO were further characterized by employing spherulitic morphological observation and isothermal crystallization kinetics analysis. In contrast to the bare SiO2, PEG-g-SiO2 can be well dispersed in PEO matrix at low P/N (P: Molecular weight of matrix chains, N: Molecular weight of grafted chains), which is a key factor to enhance the primary nucleation rate. In particular, we found that the addition of PEG-g-SiO2 slows the spherulitic growth fronts compared to the neat PEO. It is speculated that the interfacial structure of the grafted PEG plays a key role in the formation of nuclei sites, thus ultimately determines the crystallization behavior of PEO PNCs and enhances the overall crystallization rate of the PEO nanocomposites.



2015 ◽  
Vol 300 (4) ◽  
pp. 466-474 ◽  
Author(s):  
Jesper G. van Berkel ◽  
Nathanaël Guigo ◽  
Jeffrey J. Kolstad ◽  
Laszlo Sipos ◽  
Bing Wang ◽  
...  


2007 ◽  
Vol 9 (17) ◽  
pp. 2137-2141 ◽  
Author(s):  
Frédéric Fraïsse ◽  
Jean-Marie Nedelec ◽  
Jean Pierre E. Grolier ◽  
Mohamed Baba






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