Designing of phosphorous based highly functional dendrimeric macromolecular resin as an effective coating material for carbon steel in NaCl : Computational and experimental studies

2020 ◽  
Vol 138 (2) ◽  
pp. 49673 ◽  
Author(s):  
Omar Dagdag ◽  
Ahmed El Harfi ◽  
Lahoucine El Gana ◽  
Zaki Safi ◽  
Lei Guo ◽  
...  
Keyword(s):  
Carbon Steel ◽  
Experimental Studies ◽  
Coating Material

Highly durable macromolecular epoxy resin as anticorrosive coating material for carbon steel in 3% NaCl: Computational supported experimental studies

2020 ◽  
Vol 137 (34) ◽  
pp. 49003 ◽  
Author(s):  
Omar Dagdag ◽  
Avni Berisha ◽  
Zaki Safi ◽  
Saïd Dagdag ◽  
Majda Berrani ◽  
...  
Keyword(s):  
Carbon Steel ◽  
Epoxy Resin ◽  
Experimental Studies ◽  
Coating Material ◽  
Anticorrosive Coating

scholarly journals Theoretical and Experimental Studies for Inhibition Potentials of Imidazolidine 4-One and Oxazolidine 5-One Derivatives for the Corrosion of Carbon Steel in Sea Water

2020 ◽  
pp. 2776-2796
Author(s):  
Rehab M Kubba ◽  
Nada M. Al-Joborry ◽  
Naeemah J. Al-lami
Keyword(s):  
Carbon Steel ◽  
Density Functional ◽  
Sea Water ◽  
Physical Adsorption ◽  
Population Analysis ◽  
Experimental Studies ◽  
Experimental Methods ◽  
Equilibrium Geometry ◽  
Quantum Mechanical Method ◽  
Derivatives Of

Two derivatives of Iimidazolidin 4-one (IMID4) and Oxazolidin 5-one (OXAZ5), were investigated as corrosion inhibitors of corrosion carbon steel in sea water by employing the theoretical and experimental methods. The results revealed that they inhibit the corrosion process and their %IE followed the order: IMID4 (89.093%) > OXAZ5 (80.179%). The %IE obtained via theoretical and experimental methods were in a good agreement with each other. The thermodynamic parameters obtained by potentiometric polarization measurements have supported a physical adsorption mechanism which followed Langmuir adsorption isotherm. Quantum mechanical method of Density Functional Theory (DFT) of B3LYP with a level of 6-311++G (2d, 2p) were used to calculate the geometrical structure, physical properties and inhibition efficiency parameters, in vacuum and two solvents (DMSO and H2O), all calculated at the equilibrium geometry, and correlated with the experimental %IE. The local reactivity has been studied through Mulliken charges population analysis. The morphology of the surface changes of carbon steel were studied using SEM and AFM techniques.

scholarly journals Corrosion in CO2 Systems with Impurities Creating Strong Acids

CORROSION ◽  
10.5006/3110 ◽  
2019 ◽  
Vol 75 (11) ◽  
pp. 1307-1314
Author(s):  
Bjørn H. Morland ◽  
Morten Tjelta ◽  
Arne Dugstad ◽  
Gaute Svenningsen
Keyword(s):  
Sulfuric Acid ◽  
Carbon Steel ◽  
Stainless Steels ◽  
Elemental Sulfur ◽  
Experimental Studies ◽  
Visual Observation ◽  
Low Concentrations ◽  
Strong Acids ◽  
Safety And Environment

There are several proposed specifications for CO2 transport regarding how much impurities that can be allowed in the CO2 stream. Many of these specifications are based on health, safety, and environment (HSE) considerations in case of accidental spill, and only limited focus has been on the pipeline integrity. Previous work has demonstrated that many of the impurities that are expected to be present in CO2 captured from flue gasses may react and form corrosive species. The present paper studied impurity reactions and corrosion under simulated transport conditions (25°C and 10 MPa of CO2). An experiment was performed in a transparent autoclave which allowed for in situ visual observation. Chemical reactions between the impurities were observed even at very low concentrations (<100 ppmv). These reactions contributed to the production of nitric and sulfuric acid together with formation of elemental sulfur. Corrosion was observed on coupons of carbon steel, but not on stainless steels. The corrosion rate of carbon steel was low, but the amount of acids and solids (corrosion products) produced cannot be accepted from a pipeline integrity perspective. Further experimental studies are needed to determine specific limits for impurity concentrations in captured CO2 for transport.

Experimental Studies of Ratcheting of Pressurized Pipe

1991 ◽  
Vol 113 (2) ◽  
pp. 210-218 ◽  
Author(s):  
R. J. Scavuzzo ◽  
P. C. Lam ◽  
J. S. Gau
Keyword(s):  
Stainless Steel ◽  
Carbon Steel ◽  
Experimental Studies ◽  
Initial Pressure ◽  
Steel Pipe ◽  
304 Stainless Steel ◽  
Dynamic Tests ◽  
Stainless Steel Pipe ◽  
Bending Stresses ◽  
Hoop Direction

In these studies, both dynamic and static tests were conducted on pressurized pipe. Dynamic tests were run on 1 in. Schedule 40 and Schedule 10 seamless 304 stainless steel pipe. Welded 1 in. Schedule 40 304 stainless steel pipe and seamless carbon steel (ASTM A106) pipe were tested statically. Internal pressures varied from 1000 psi to 3000 psi. In these tests, axial bending stresses from either inertial loads or static loads were superposed on to the initial pressure stresses. Strain gages were used to measure the cyclic strains on the outer walls of the pipe. Measurements indicated that ratcheting occurred primarily in the hoop direction and varied from a maximum at the top and bottom of the pipe that had the highest bending stresses to zero at the neutral axis. Though ratcheting occurred primarily in the hoop direction, some ratcheting in the axial direction was observed in 304 stainless steel pipe in both static and dynamic tests. Axial ratcheting was insignificant in the carbon steel pipe. Data obtained from these tests are presented. Measured ratcheting strains are compared to approximations of Beaney, Edmunds and Beer and to finite element computations.

scholarly journals The Influence of the Angle of the Working Part of the Die on the High Speed Drawing Process of Low Carbon Steel Wires

2017 ◽  
Vol 62 (2) ◽  
pp. 483-487 ◽  
Author(s):  
M. Suliga ◽  
R. Wartacz ◽  
J. Michalczyk
Keyword(s):  
Mechanical Properties ◽  
Carbon Steel ◽  
Experimental Studies ◽  
Low Carbon Steel ◽  
Drawing Process ◽  
Low Carbon ◽  
Wire Rod ◽  
Steel Wires ◽  
Drawing Angle ◽  
The Impact

Abstract The paper contains the theoretical and experimental analysis of the impact of the drawing angle on the drawing process and the properties of low carbon steel wires. A multi-stage drawing wire rod with a diameter of 5.5 mm on a wire with a diameter of 1.0 mm has been carried out in two stages. The first one consisted of preliminary drawing wire rod for the wire with a diameter of 2.2 mm which was next subjected to the drawing process at a speed of 25 m/sec at the final wire with a diameter of 1.0 mm. The wires were drawn in conventional dies with drawing angle α = 3, 4, 5, 6, 7 degrees. For the wires drawn in respective variants, the investigation of the mechanical properties was performed and the amount of lubricant on the surface of steel wires was determined. Numerical analysis of the process of drawing in the Drawing 2D complemented the experimental studies. It has been shown that when drawing at high speeds, properly chosen the value of the angle of the working part of the die can improve the lubrication conditions and mechanical properties of steel wires.

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