Suzuki-Coupling of Cp*Ru(para-C6H4Br2) with Phenyl Boronic Acid: A Model Reaction for the Synthesis of Organometallic Polymers

1996 ◽  
Vol 129 (11) ◽  
pp. 1323-1325 ◽  
Author(s):  
Kathrin Harre ◽  
Volker Enkelmann ◽  
Margit Schulze ◽  
Uwe H. F. Bunz
Keyword(s):  
Boronic Acid ◽  
Suzuki Coupling ◽  
Model Reaction ◽  
Organometallic Polymers ◽  
Phenyl Boronic Acid

Arylboronic Acids in Self-condensation of Glucosamines Forming Deoxyfructosazine, Catalysts or Reagents?

2019 ◽  
Author(s):  
Meifeng Wang ◽  
Gan Zhu ◽  
Yiqun Li ◽  
Liuqun Gu
Keyword(s):  
Molecular Recognition ◽  
Boric Acid ◽  
Boronic Acid ◽  
Catalytic Mechanism ◽  
Organic Transformations ◽  
Food Industries ◽  
Arylboronic Acids ◽  
Excess Amount ◽  
Phenyl Boronic Acid ◽  
Boron Acid

Arylboronic acids were widely used as efficient catalysts in direct amide formation and other organic transformations. Surprisingly, reports on their use as catalysts in carbohydrates synthesis are very rare even though boron acid-diol complexation was extensively investigated in molecular recognition for saccharides and so on. Here we developed an efficient arylboronic acids catalyzed dimerization of glucosamines forming deoxyfructosazine which is important compound in pharmaceutical and food industries, against a commonly held belief that excess amount of phenyl boronic acid (or boric acid) is a must. A catalytic mechanism was also proposed and arylboronic acids instead of their boronates was identified as catalysts.

scholarly journals Analysis of glycoproteins by SDS-PAGE with methacrylamido phenyl boronic acid

2014 ◽  
Vol 58 (2) ◽  
pp. 33-35 ◽  
Author(s):  
Yuichi Aikyo ◽  
Masamichi Oh-Ishi
Keyword(s):  
Boronic Acid ◽  
Sds Page ◽  
Phenyl Boronic Acid

On the sensitivity of alginate rheology to composition

Soft Matter ◽  
2019 ◽  
Vol 15 (2) ◽  
pp. 159-165 ◽  
Author(s):  
Karthika Suresh ◽  
Marleen Häring ◽  
Guruswamy Kumaraswamy ◽  
David Díaz Díaz
Keyword(s):  
Viscoelastic Fluid ◽  
Boronic Acid ◽  
Linear Response ◽  
High Strain ◽  
Strain Behaviour ◽  
Phenyl Boronic Acid ◽  
Universal Composition

The linear response of alginate-phenyl boronic acid (Alg-PBA) esters shows a universal, composition-independent viscoelastic fluid-like behaviour. However, their high strain behaviour is very sensitive to composition.

Synthesis of A 1,1′-Binaphthyl Based Main Chain Chiral Conjugated Polymer

1995 ◽  
Vol 413 ◽  
Author(s):  
Qiao-Sheng Hu ◽  
Dilrukshi Vitharana ◽  
Lin Pu
Keyword(s):  
Absorption Spectrum ◽  
Boronic Acid ◽  
Conjugated Polymer ◽  
Main Chain ◽  
Repeat Unit ◽  
Suzuki Coupling ◽  
Optically Active ◽  
Synthesis And Characterization ◽  
Palladium Catalyzed

ABSTRACTThe synthesis and characterization of a 1,1′-binaphthyl based main chain chiral conjugated polymer, R-9, is described. The polymer is prepared from the palladium-catalyzed Suzuki coupling of an optically active binaphthyl molecule, (R)-2,2′-dihexyloxy-1,1′-binaphthyl-6,6′- diboronic acid, R-4 with 1,4-bis(p-bromostyryl)benzene (E:Z = 1:1.2), 8. The Suzuki coupling of 8 with 6-neopentyloxynaphthyl-2-boronic acid, 1 1, leads to the formation of a conjugated molecule 10. The structure of this molecule represents the repeat unit of R-9. The electronic absorption spectrum of 10 demonstrates that the degree of conjugation in the chiral conjugated polymer is almost the same as that of its repeat unit.

Anionic chromogenic chemosensors highly selective for cyanide based on the interaction of phenyl boronic acid and solvatochromic dyes

2015 ◽  
Vol 221 ◽  
pp. 644-652 ◽  
Author(s):  
Lizandra Maria Zimmermann ◽  
Jaqueline Nicolini ◽  
Vanderléia Gava Marini ◽  
Vanderlei Gageiro Machado
Keyword(s):  
Boronic Acid ◽  
Solvatochromic Dyes ◽  
Phenyl Boronic Acid
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