scholarly journals Illumination Intensity Dependence of the Recombination Mechanism in Mixed Perovskite Solar Cells

ChemPlusChem ◽  
2021 ◽  
Author(s):  
Alejandra Castro-Chong ◽  
Antonio Jesús Riquelme Expósito ◽  
Tom Aernouts ◽  
Laurence J. Bennet ◽  
Gerko Oskam ◽  
...  
2018 ◽  
Vol 6 (44) ◽  
pp. 21913-21917 ◽  
Author(s):  
Joel Troughton ◽  
Nicola Gasparini ◽  
Derya Baran

Recently developed, highly stable perovskite materials show promise for use in concentrator photovoltaics where the illumination intensity far exceeds standard test conditions.


1992 ◽  
Vol 258 ◽  
Author(s):  
Liyou Yang ◽  
L. Chen ◽  
J.Y. Hou ◽  
Y.M. Li

ABSTRACTThe light induced degradation of a-Si:H p-i-n solar cells under electrical bias has been systematically studied. By comparing the results with the light intensity dependence of cell degradation under open circuit condition, we show that the only recombination mechanism, which can be consistent with the experimental data in both cases, is based on the bimolecular recombination between a free hole and a trapped electron at the “weak” bond site. Other possibilities for defect creation are also pointed out.


Nanophotonics ◽  
2021 ◽  
Vol 0 (0) ◽  
Author(s):  
Waseem Raja ◽  
Michele De Bastiani ◽  
Thomas G. Allen ◽  
Erkan Aydin ◽  
Arsalan Razzaq ◽  
...  

Abstract Metal halide perovskites have emerged in recent years as promising photovoltaic materials due to their excellent optical and electrical properties, enabling perovskite solar cells (PSCs) with certified power conversion efficiencies (PCEs) greater than 25%. Provided radiative recombination is the dominant recombination mechanism, photon recycling – the process of reabsorption (and re-emission) of photons that result from radiative recombination – can be utilized to further enhance the PCE toward the Shockley–Queisser (S-Q) theoretical limit. Geometrical optics can be exploited for the intentional trapping of such re-emitted photons within the device, to enhance the PCE. However, this scheme reaches its fundamental diffraction limits at the submicron scale. Therefore, introducing photonic nanostructures offer attractive solutions to manipulate and trap light at the nanoscale via light coupling into guided modes, as well as localized surface plasmon and surface plasmon polariton modes. This review focuses on light-trapping schemes for efficient photon recycling in PSCs. First, we summarize the working principles of photon recycling, which is followed by a review of essential requirements to make this process efficient. We then survey photon recycling in state-of-the-art PSCs and propose design strategies to invoke light-trapping to effectively exploit photon recycling in PSCs. Finally, we formulate a future outlook and discuss new research directions in the context of photon recycling.


1996 ◽  
Vol 420 ◽  
Author(s):  
Qi Wang ◽  
Richard S. Crandall

AbstractWe study the effect of illumination intensity on solar cell performance in a-Si:H solar cells. We find that the fill factor strongly depends on light intensity. As we increase the illumination intensity from low levels to one sun we observe a decrease in fill factor of approximately 15% in as grown cells. We attribute this effect to electric field collapse inside the cell. We propose that photogenerated space charge (free and trapped charge) increases with light intensity and causes field collapse. We describe the origin of space charge and the associated capacitance - photocapacitance. We measure the photocapacitance as a barometer to probe the collapsed field. We obtain a good agreement between photocapacitance experiments and theory. We also explore the light intensity dependence of photocapacitance and explain the decrease of FF with the increasing light intensity.


2017 ◽  
Vol 30 (5) ◽  
pp. 577-582 ◽  
Author(s):  
Maning Liu ◽  
Masaru Endo ◽  
Ai Shimazaki ◽  
Atsushi Wakamiya ◽  
Yasuhiro Tachibana

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