Synergistic Effect of Pendant N Moieties for Proton Shuttling in the Dehydrogenation of Formic Acid Catalyzed by Biomimetic Ir III Complexes

ChemSusChem ◽  
2020 ◽  
Vol 13 (18) ◽  
pp. 5015-5022
Author(s):  
Wan‐Hui Wang ◽  
Hong Wang ◽  
Yajing Yang ◽  
Xiaoling Lai ◽  
Yang Li ◽  
...  
Keyword(s):  
Synergistic Effect ◽  
Formic Acid ◽  
Acid Catalyzed ◽  
Proton Shuttling

Electro-oxidation of formic acid catalyzed by FePt nanoparticles

2006 ◽  
Vol 8 (23) ◽  
pp. 2779 ◽  
Author(s):  
Wei Chen ◽  
Jaemin Kim ◽  
Shouheng Sun ◽  
Shaowei Chen
Keyword(s):  
Formic Acid ◽  
Fept Nanoparticles ◽  
Electro Oxidation ◽  
Acid Catalyzed

A structure–activity relationship study using DFT analysis of Bronsted–Lewis acidic ionic liquids and synergistic effect of dual acidity in one-pot conversion of glucose to value-added chemicals

2018 ◽  
Vol 42 (2) ◽  
pp. 1423-1430 ◽  
Author(s):  
Firdaus Parveen ◽  
Tanmoy Patra ◽  
Sreedevi Upadhyayula
Keyword(s):  
Ionic Liquids ◽  
Synergistic Effect ◽  
Formic Acid ◽  
Levulinic Acid ◽  
Value Added ◽  
One Pot ◽  
Structure Activity ◽  
Acidic Ionic Liquids ◽  
Commercially Important ◽  
Relationship Study

The catalytic conversion of biomass-derived carbohydrates to value-added chemicals, such as 5-hydroxymethylfurfural, levulinic acid, and formic acid, is a commercially important reaction and requires the use of both Lewis and Bronsted acids.

Synergistic effect of co-reactant promotes one-step oxidation of cyclohexane into adipic acid catalyzed by manganese porphyrins

2015 ◽  
Vol 93 (7) ◽  
pp. 696-701 ◽  
Author(s):  
Hui Li ◽  
Yuanbin She ◽  
Haiyan Fu ◽  
Meijuan Cao ◽  
Jing Wang ◽  
...  
Keyword(s):  
Synergistic Effect ◽  
Co Oxidation ◽  
Adipic Acid ◽  
Molar Ratio ◽  
Reaction Conditions ◽  
Catalyst Structure ◽  
Manganese Porphyrins ◽  
Co Oxidation Reaction ◽  
One Step ◽  
Acid Catalyzed

The synergistic effect of cyclohexane and cyclohexanone promoted synthesis of adipic acid catalyzed by [MnIIIT(p-Cl)PP]Cl with cyclohexane and cyclohexanone as co-reactants. The results showed that the conversions of cyclohexane and cyclohexanone were significantly enhanced because of the cyclohexanone synergistic effect, and the higher selectivity to adipic acid was obtained with dioxygen as an oxidant. The studies indicated that the co-oxidation of cyclohexane and cyclohexanone was influenced by the initial molar ratio of cyclohexanone and cyclohexane, catalyst structure, catalyst concentrations, and reaction conditions. The preliminary mechanism of the co-oxidation reaction of cyclohexane and cyclohexanone using [MnIIIT(p-Cl)PP]Cl as the catalyst was proposed.

Acid-catalyzed Solvolysis of Isonitriles. I

1971 ◽  
Vol 49 (14) ◽  
pp. 2455-2459 ◽  
Author(s):  
Y. Y. Lim ◽  
A. R. Stein
Keyword(s):  
Formic Acid ◽  
Acid Catalysis ◽  
Hydrolysis Product ◽  
Rate Dependence ◽  
Linear Rate ◽  
First Order ◽  
Methyl Amine ◽  
Acid Catalyzed ◽  
Pseudo First Order ◽  
Hydrolysis Of

The acid-catalyzed hydrolysis of methyl isonitrile has been examined. The initial hydrolysis product is N-methylformamide which is further hydrolyzed to methyl amine and formic acid at a much slower rate. The hydrolysis to N-methylformamide is pseudo-first order in methyl isonitrile and shows a linear rate dependence on concentration of general (buffer) acid at fixed pH. The significance of general acid-catalysis in terms of the mechanism of the hydrolysis is considered and taken as evidence for carbon protonation rather than nitrogen protonation as the initiating step.

Room Temperature Reduction of Graphene Oxide by Formic Acid Catalyzed by Platinum Nanoparticles

2013 ◽  
Vol 13 (4) ◽  
pp. 2967-2973 ◽  
Author(s):  
Yinjie Wang ◽  
Jincheng Liu ◽  
Lei Liu ◽  
Tong Zhang ◽  
Darren D. Sun
Keyword(s):  
Graphene Oxide ◽  
Formic Acid ◽  
Platinum Nanoparticles ◽  
Room Temperature ◽  
Temperature Reduction ◽  
Acid Catalyzed

Chromium-catalysed efficient N-formylation of amines with a recyclable polyoxometalate-supported green catalyst

2021 ◽  
Vol 50 (1) ◽  
pp. 90-94
Author(s):  
Demin Dan ◽  
Fubo Chen ◽  
Whenshu Zhao ◽  
Han Yu ◽  
Sheng Han ◽  
...  
Keyword(s):  
Formic Acid ◽  
Green Catalyst ◽  
Chromium Catalyst ◽  
Acid Catalyzed

A simple and efficient protocol for the formylation of amines with formic acid, catalyzed by a polyoxometalate-based chromium catalyst, is described.

scholarly journals Theoretical kinetic study of the formic acid catalyzed Criegee intermediate isomerization: multistructural anharmonicity and atmospheric implications

2018 ◽  
Vol 20 (16) ◽  
pp. 10806-10814 ◽  
Author(s):  
M. Monge-Palacios ◽  
Matti P. Rissanen ◽  
Zhandong Wang ◽  
S. Mani Sarathy
Keyword(s):  
Carbon Atom ◽  
Formic Acid ◽  
Kinetic Study ◽  
Theoretical Study ◽  
Isomerization Reaction ◽  
Hydrogen Shift ◽  
Acid Catalyzed ◽  
Double Hydrogen

We performed a theoretical study on the double hydrogen shift isomerization reaction of a six carbon atom Criegee intermediate (C6-CI), catalyzed by formic acid (HCOOH), to produce vinylhydroperoxide (VHP), C6-CI + HCOOH → VHP + HCOOH.

Hydrogenation of CO2 to formic acid catalyzed by heterogeneous Ru-PPh3/Al2O3 catalysts

2018 ◽  
Vol 178 ◽  
pp. 98-103 ◽  
Author(s):  
Wenjing Zhang ◽  
Shengping Wang ◽  
Yujun Zhao ◽  
Xinbin Ma
Keyword(s):  
Formic Acid ◽  
Hydrogenation Of Co2 ◽  
Acid Catalyzed

Synergistic effect of binanoenzyme and cryogel column on the production of formic acid from carbondioxide

2019 ◽  
Vol 76 ◽  
pp. 251-257
Author(s):  
Yiğitcan Sümbelli ◽  
Özlem Biçen Ünlüer ◽  
Arzu Ersöz ◽  
Rıdvan Say
Keyword(s):  
Synergistic Effect ◽  
Formic Acid
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