scholarly journals Corrosion protection of soft‐cast steel in 1 M HCl with Araucaria heterophylla leaves extract

Author(s):  
Manohar R. Rathod ◽  
S. K. Rajappa
1991 ◽  
Vol 257 ◽  
Author(s):  
W. Schwarzkopf ◽  
E. Smailos ◽  
R. KÖster

ABSTRACTPrevious corrosion studies have shown that the passive alloys Ti 99.8-Pd and Hastelloy C4 are the most promising corrosion protection materials for long-term resistant carbon-steel containers for the disposal of heat-generating wastes in rock salt formations. Consequently, these materials are subject to more detailed investigations. The influence of selected container manufacturing characteristics (sealing technique, application mode of the corrosion protecting layer on the steel) on the corrosion behaviour of Ti 99.8-Pd and Hastelloy C4was studied using in-situ experiments. The corrosion resistance of the materials was examined both in NaCI brine and MgCl2-rich brine, which might enter into an HLW borehole under certain disposal conditions. Four electron-beam welded cast-steel tubes plated with corrosion protection layers made of Ti 99.8-Pd and Hastelloy C4, respectively, were stored for 18 months in 2-m deep heated boreholes in the Asse salt mine. The annular gap between the tubes and the borehole wall was filled with saturated NaCl-brine or Qbrine (MgCl2-rich). The vertical temperature profile in the boreholes ranged from 90°C to 200°CIn the cast-steel tube with a corrosion protection of Ti 99.8-Pd, no indication of corrosion was observed on the EB-welds or on the explosion plated material in both brines. The cast-steel tube with a corrosion protection of Hastelloy C4 also was found to be resistant to any kind of corrosion in the NaCl-brine. In the MgCl2-rich brine, however, small pitting corrosion of 15 pm was observed after 1.5 years on the passive surface layer that was formed.On the basis of these results, Ti 99.8-Pd continues to be considered as a promising corrosion protection material for long-lived HLW containers.


Author(s):  
Jiang Xishan

This paper reports the growth step pattern and morphology at equilibrium and growth states of (Mn,Fe)S single crystal on the wall of micro-voids in ZG25 cast steel by using scanning electron microscope. Seldom report was presented on the growth morphology and steppattern of (Mn,Fe)S single crystal.Fig.1 shows the front half of the polyhedron of(Mn,Fe)S single crystal,its central area being the square crystal plane,the two pairs of hexagons symmetrically located in the high and low, the left and right with a certain, angle to the square crystal plane.According to the symmetrical relationship of crystal, it was defined that the (Mn,Fe)S single crystal at equilibrium state is tetrakaidecahedron consisted of eight hexagonal crystal planes and six square crystal planes. The macroscopic symmetry elements of the tetrakaidecahedron correpond to Oh—n3m symmetry class of fcc structure,in which the hexagonal crystal planes are the { 111 } crystal planes group,square crystal plaits are the { 100 } crystal planes group. This new discovery of the (Mn,Fe)S single crystal provides a typical example of the point group of Oh—n3m.


2001 ◽  
Vol 11 (PR3) ◽  
pp. Pr3-861-Pr3-867 ◽  
Author(s):  
S. M. Zemskova ◽  
J. A. Haynes ◽  
K. M. Cooley

2020 ◽  
Vol 117 (6) ◽  
pp. 610
Author(s):  
Nadia Hammouda ◽  
Kamel Belmokre

Organic coatings are widely employed in the corrosion protection of most metal surfaces, particularly steel. They provide a barrier against corrosive species present in the environment, due to their high resistance to oxygen, water and ions transport. This study focuses on the evaluation of corrosion protection performance of epoxy paint on the carbon steel surface in chloride environment (3% NaCl) by Electrochemical Impedance Spectroscopy (EIS). The electrochemical behavior of painted surface was estimated by EIS parameters that contained paint film resistance, paint film capacitance and double layer capacitance. On the basis of calculation using EIS spectrums it was observed that pore resistance (Rpore) decreased with the appearance of doubled layer capacitance (Cdl) due to the electrolyte penetration through the film. This was further confirmed by the decrease of diffusion resistance (Rd) which was also the indicator of the deterioration of paint film protectiveness. Microscopic analyses have shown that oxidation dominates the corroded surfaces.


1986 ◽  
Vol 84 ◽  
Author(s):  
M.D. Merz ◽  
F. Gerber ◽  
R. Wang

AbstractThe Materials Characterization Center (MCC) at Pacific Northwest Lab- oratory is performing three kinds of corrosion tests for the Basalt Waste Isolation Project (BWIP) to establish the interlaboratory reproducibility and uncertainty of corrosion rates of container materials for high-level nuclear waste. The three types of corrosion tests were selected to address two distinct conditions that are expected in a repository constructed in basalt. An air/steam test is designed to address corrosion during the operational period and static pressure vessel and flowby tests are designed to address corrosion under conditions that bound the condi ring the post-closure period of the repository.The results of tests at reference testing conditions, which were defined to facilitate interlaboratory comparison of data, are presented. Data are reported for the BWIP/MCC-105.5 Air/Steam Test, BWIP/MCC-105.1 Static Pressure Vessel, and BWIP/MC-105.4 Flowby Test. In those cases where data are available from a second laboratory, a statistical analysis of interlaboratory results is reported and expected confidence intervals for mean corrosion rates are given. Other statistical treatment of data include analyses of the effects of vessel-to-vessel variations, test capsule variations for the flowby test, and oven-to-oven variations for air/steam tests.


Alloy Digest ◽  
1965 ◽  
Vol 14 (5) ◽  

Abstract BOFORS 2RM2 is a hardenable stainless cast steel having good weldability, high mechanical strength and improved corrosion resistance. This datasheet provides information on composition, physical properties, hardness, elasticity, and tensile properties as well as fracture toughness. It also includes information on low temperature performance and corrosion resistance as well as casting, forming, heat treating, machining, and joining. Filing Code: SS-169. Producer or source: Aktiebolaget Bofors.


Alloy Digest ◽  
1976 ◽  
Vol 25 (10) ◽  

Abstract Alloy Steel 1.8 Cu-1.0 Mn-1.2 Si is a low-carbon (0.20% max.) cast steel designed to provide intermediate tensile and yield strength. Copper lowers the ductility and toughness of cast steel but, for a given increase in tensile strength, the loss of ductility and toughness is less if copper is added than if carbon is increased. This steel has many uses such as booms, long shafting and gears. This datasheet provides information on composition, physical properties, elasticity, and tensile properties. It also includes information on corrosion resistance as well as casting, heat treating, machining, and joining. Filing Code: SA-325. Producer or source: Alloy steel mills and foundries.


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