Thermal energy storage characteristics of binary molten salt nanofluids: Specific heat and latent heat

Author(s):  
Daehyeong Lee ◽  
Byeongnam Jo
Author(s):  
Ronald J. Warzoha ◽  
Anthony Rao ◽  
Rebecca Weigand ◽  
Amy S. Fleischer

Phase change materials (PCMs) are promising candidates for thermal energy storage due to their intrinsically high values of latent heat. However, PCMs are unable to effectively utilize all of their energy storage capacities due to their poor thermophysical properties. In this study, the effect of graphite nanofibers (diameter = 2 to 1000 nm, length = 100μm) on the bulk thermal properties of paraffin PCM (Tmelt = 56 °C) is investigated. Material properties including effective thermal conductivity, specific heat, latent heat, melt temperature and thermal diffusivity are measured using a Differential Scanning Calorimeter (DSC) and comparative reference bar apparatus. Results suggest that the addition of nanostructures not only increases thermal conductivity by up to 180%, but also reduces the specific heat capacity and density of nano-enhanced paraffin, leading to improved thermal diffusivity and thus greater utilization of its latent heat for transient thermal energy storage.


Nanomaterials ◽  
2020 ◽  
Vol 10 (11) ◽  
pp. 2266
Author(s):  
Binjian Ma ◽  
Donghyun Shin ◽  
Debjyoti Banerjee

Molten salts mixed with nanoparticles have been shown as a promising candidate as the thermal energy storage (TES) material in concentrated solar power (CSP) plants. However, the conventional method used to prepare molten salt nanofluid suffers from a high material cost, intensive energy use, and laborious process. In this study, solar salt-Al2O3 nanofluids at three different concentrations are prepared by a one-step method in which the oxide nanoparticles are generated in the salt melt directly from precursors. The morphologies of the obtained nanomaterials are examined under scanning electron microscopy and the specific heat capacities are measured using the temperature history (T-history) method. A non-linear enhancement in the specific heat capacity of molten salt nanofluid is observed from the thermal characterization at a nanoparticle mass concentration of 0.5%, 1.0%, and 1.5%. In particular, a maximum enhancement of 38.7% in specific heat is found for the nanofluid sample prepared with a target nanoparticle mass fraction of 1.0%. Such an enhancement trend is attributed to the formation of secondary nanostructure between the alumina nanoparticles in the molten salt matrix following a locally-dispersed-parcel pattern. These findings provide new insights to understanding the enhanced energy storage capacity of molten salt nanofluids.


2021 ◽  
Vol 7 ◽  
Author(s):  
Law Torres Sevilla ◽  
Jovana Radulovic

This paper studies the influence of material thermal properties on the charging dynamics in a low temperature Thermal Energy Storage, which combines sensible and latent heat. The analysis is based on a small scale packed bed with encapsulated PCMs, numerically solved using COMSOL Multiphysics. The PCMs studied are materials constructed based on typical thermal properties (melting temperature, density, specific heat capacity (solid and liquid), thermal conductivity (solid and liquid) and the latent heat) of storage mediums in literature. The range of values are: 25–65°C for the melting temperature, 10–500 kJ/kg for the latent heat, 600–1,000 kg/m3 for the density, 0.1–0.4 W/mK (solid and liquid) for the thermal conductivity and 1,000–2,200 J/kgK (solid and liquid) for the specific heat capacity. The temperature change is monitored at three different positions along the tank. The system consists of a 2D tank with L/D ratio of 1 at a starting temperature of 20°C. Water, as the heat transfer fluid, enters the tank at 90°C. Results indicate that latent heat is a leading parameter in the performance of the system, and that the thermal properties of the PCM in liquid phase influence the overall heat absorption more than its solid counterpart.


Author(s):  
Zhao Li ◽  
Liu Cui ◽  
B. R. Li ◽  
xiaoze du

The enhancement of the specific heat capacity of molten salt-based nanofluid is investigated via molecular dynamics (MD) simulations. The results show the addition of the nanoparticle indeed enhances the specific...


Sign in / Sign up

Export Citation Format

Share Document