Experimental Characterization of the Thermal Diffusivity of Paraffin Phase Change Material Embedded With Herringbone Style Graphite Nanofibers

2012 ◽  
Author(s):  
Ronald J. Warzoha ◽  
Anthony Rao ◽  
Rebecca Weigand ◽  
Amy S. Fleischer
Keyword(s):  
Thermal Conductivity ◽  
Energy Storage ◽  
Thermal Diffusivity ◽  
Phase Change ◽  
Specific Heat ◽  
Latent Heat ◽  
Thermal Energy ◽  
Thermal Energy Storage ◽  
Melt Temperature ◽  
Graphite Nanofibers

Phase change materials (PCMs) are promising candidates for thermal energy storage due to their intrinsically high values of latent heat. However, PCMs are unable to effectively utilize all of their energy storage capacities due to their poor thermophysical properties. In this study, the effect of graphite nanofibers (diameter = 2 to 1000 nm, length = 100μm) on the bulk thermal properties of paraffin PCM (Tmelt = 56 °C) is investigated. Material properties including effective thermal conductivity, specific heat, latent heat, melt temperature and thermal diffusivity are measured using a Differential Scanning Calorimeter (DSC) and comparative reference bar apparatus. Results suggest that the addition of nanostructures not only increases thermal conductivity by up to 180%, but also reduces the specific heat capacity and density of nano-enhanced paraffin, leading to improved thermal diffusivity and thus greater utilization of its latent heat for transient thermal energy storage.

Enhanced thermal conductivity of phase change materials with ultrathin-graphite foams for thermal energy storage

2014 ◽  
Vol 7 (3) ◽  
pp. 1185-1192 ◽  
Author(s):  
Hengxing Ji ◽  
Daniel P. Sellan ◽  
Michael T. Pettes ◽  
Xianghua Kong ◽  
Junyi Ji ◽  
...  
Keyword(s):  
Thermal Conductivity ◽  
Energy Storage ◽  
Phase Change ◽  
Specific Heat ◽  
Thermal Energy ◽  
Thermal Energy Storage ◽  
Phase Change Materials ◽  
Heat Of Fusion ◽  
Change Material ◽  
Enhanced Thermal Conductivity

Embedding continuous ultrathin-graphite foams (UGFs) with volume fractions as low as 0.8–1.2 vol% in a phase change material (PCM) can increase the effective thermal conductivity by up to 18 times, with negligible change in the melting temperature or mass specific heat of fusion.

scholarly journals Effectiveness of Thermal Properties in Thermal Energy Storage Modeling

2021 ◽  
Vol 7 ◽  
Author(s):  
Law Torres Sevilla ◽  
Jovana Radulovic
Keyword(s):  
Thermal Conductivity ◽  
Heat Capacity ◽  
Thermal Properties ◽  
Energy Storage ◽  
Specific Heat ◽  
Melting Temperature ◽  
Latent Heat ◽  
Specific Heat Capacity ◽  
Thermal Energy ◽  
Thermal Energy Storage

This paper studies the influence of material thermal properties on the charging dynamics in a low temperature Thermal Energy Storage, which combines sensible and latent heat. The analysis is based on a small scale packed bed with encapsulated PCMs, numerically solved using COMSOL Multiphysics. The PCMs studied are materials constructed based on typical thermal properties (melting temperature, density, specific heat capacity (solid and liquid), thermal conductivity (solid and liquid) and the latent heat) of storage mediums in literature. The range of values are: 25–65°C for the melting temperature, 10–500 kJ/kg for the latent heat, 600–1,000 kg/m3 for the density, 0.1–0.4 W/mK (solid and liquid) for the thermal conductivity and 1,000–2,200 J/kgK (solid and liquid) for the specific heat capacity. The temperature change is monitored at three different positions along the tank. The system consists of a 2D tank with L/D ratio of 1 at a starting temperature of 20°C. Water, as the heat transfer fluid, enters the tank at 90°C. Results indicate that latent heat is a leading parameter in the performance of the system, and that the thermal properties of the PCM in liquid phase influence the overall heat absorption more than its solid counterpart.

scholarly journals Latent Heat Phase Change Heat Transfer of a Nanoliquid with Nano–Encapsulated Phase Change Materials in a Wavy-Wall Enclosure with an Active Rotating Cylinder

2021 ◽  
Vol 13 (5) ◽  
pp. 2590
Author(s):  
S. A. M. Mehryan ◽  
Kaamran Raahemifar ◽  
Leila Sasani Gargari ◽  
Ahmad Hajjar ◽  
Mohamad El Kadri ◽  
...  
Keyword(s):  
Heat Transfer ◽  
Energy Storage ◽  
Phase Change ◽  
Latent Heat ◽  
Thermal Energy ◽  
Thermal Energy Storage ◽  
Wavy Wall ◽  
Governing Equations ◽  
Stefan Number ◽  
Change Material

A Nano-Encapsulated Phase-Change Material (NEPCM) suspension is made of nanoparticles containing a Phase Change Material in their core and dispersed in a fluid. These particles can contribute to thermal energy storage and heat transfer by their latent heat of phase change as moving with the host fluid. Thus, such novel nanoliquids are promising for applications in waste heat recovery and thermal energy storage systems. In the present research, the mixed convection of NEPCM suspensions was addressed in a wavy wall cavity containing a rotating solid cylinder. As the nanoparticles move with the liquid, they undergo a phase change and transfer the latent heat. The phase change of nanoparticles was considered as temperature-dependent heat capacity. The governing equations of mass, momentum, and energy conservation were presented as partial differential equations. Then, the governing equations were converted to a non-dimensional form to generalize the solution, and solved by the finite element method. The influence of control parameters such as volume concentration of nanoparticles, fusion temperature of nanoparticles, Stefan number, wall undulations number, and as well as the cylinder size, angular rotation, and thermal conductivities was addressed on the heat transfer in the enclosure. The wall undulation number induces a remarkable change in the Nusselt number. There are optimum fusion temperatures for nanoparticles, which could maximize the heat transfer rate. The increase of the latent heat of nanoparticles (a decline of Stefan number) boosts the heat transfer advantage of employing the phase change particles.

scholarly journals Thermophysical Properties of Multifunctional Syntactic Foams Containing Phase Change Microcapsules for Thermal Energy Storage

Polymers ◽  
2021 ◽  
Vol 13 (11) ◽  
pp. 1790
Author(s):  
Francesco Galvagnini ◽  
Andrea Dorigato ◽  
Luca Fambri ◽  
Giulia Fredi ◽  
Alessandro Pegoretti
Keyword(s):  
Thermal Conductivity ◽  
Energy Storage ◽  
Phase Change ◽  
Epoxy Resin ◽  
Storage Modulus ◽  
Thermal Energy ◽  
Thermal Energy Storage ◽  
Neat Epoxy ◽  
Low Density ◽  
Syntactic Foams

Syntactic foams (SFs) combining an epoxy resin and hollow glass microspheres (HGM) feature a unique combination of low density, high mechanical properties, and low thermal conductivity which can be tuned according to specific applications. In this work, the versatility of epoxy/HGM SFs was further expanded by adding a microencapsulated phase change material (PCM) providing thermal energy storage (TES) ability at a phase change temperature of 43 °C. At this aim, fifteen epoxy (HGM/PCM) compositions with a total filler content (HGM + PCM) of up to 40 vol% were prepared and characterized. The experimental results were fitted with statistical models, which resulted in ternary diagrams that visually represented the properties of the ternary systems and simplified trend identification. Dynamic rheological tests showed that the PCM increased the viscosity of the epoxy resin more than HGM due to the smaller average size (20 µm vs. 60 µm) and that the systems containing both HGM and PCM showed lower viscosity than those containing only one filler type, due to the higher packing efficiency of bimodal filler distributions. HGM strongly reduced the gravimetric density and the thermal insulation properties. In fact, the sample with 40 vol% of HGM showed a density of 0.735 g/cm3 (−35% than neat epoxy) and a thermal conductivity of 0.12 W/(m∙K) (−40% than neat epoxy). Moreover, the increase in the PCM content increased the specific phase change enthalpy, which was up to 68 J/g for the sample with 40 vol% of PCM, with a consequent improvement in the thermal management ability that was also evidenced by temperature profiling tests in transient heating and cooling regimes. Finally, dynamical mechanical thermal analysis (DMTA) showed that both fillers decreased the storage modulus but generally increased the storage modulus normalized by density (E′/ρ) up to 2440 MPa/(g/cm3) at 25 °C with 40 vol% of HGM (+48% than neat epoxy). These results confirmed that the main asset of these ternary multifunctional syntactic foams is their versatility, as the composition can be tuned to reach the property set that best matches the application requirements in terms of TES ability, thermal insulation, and low density.

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