Thermal decomposition, pore structure and heats of immersion of zirconia gel

1977 ◽  
Vol 27 (1) ◽  
pp. 58-66
Author(s):  
Suzy A. Selim ◽  
Taghreed M. El-Akkad
2008 ◽  
Vol 62 (1) ◽  
Author(s):  
Zuzana Koreňová ◽  
Juma Haydary ◽  
Július Annus ◽  
Jozef Markoš ◽  
L’udovít Jelemenský

AbstractInternal structure of carbon black produced by pyrolysis (CBp) of rubber samples from the top and bottom parts of sidewall and tread of a passenger car tire was investigated in nitrogen flow at different temperatures. The pore structure (specific surface area, pore size distribution, and porosity) of CBp and commercial CB, was compared. The development of pore structure and the increase of the specific surface area were most intensive during the thermal decomposition at temperatures ranging from 300°C to 500°C. This is caused by the intensive release of volatiles during the pyrolysis. After the pyrolysis was finished, at temperatures above 500°C, further decomposition of solid matter was associated with a slight increase of the specific surface area.


2007 ◽  
Vol 26 (1) ◽  
pp. 191-198 ◽  
Author(s):  
Raouf S. H. Mikhail ◽  
Suzy A. Selim ◽  
Farouk I. Zeidan

Crystals ◽  
2020 ◽  
Vol 10 (9) ◽  
pp. 849
Author(s):  
Jingxue Zheng ◽  
Junchen Huang ◽  
Lin Tao ◽  
Zhi Li ◽  
Qi Wang

The existing kinetic models often consider the influence of a single factor alone on the chemical reaction and this is insufficient to completely describe the decomposition reaction of solids. Therefore, the existing kinetic models were improved using the pore structure model. The proposed model was verified using the thermal decomposition experiment on calcium carbonate. The equation has been modified as fα=n1−α1−1n−ln1−α−1m1−ψln1−α12. This led to the conclusion that the pore structure, generated during the thermal decomposition of calcite, has an important influence on the decomposition kinetics. The existing experimental data show that the improved model, with random pores as the main body, reasonably describes the thermal decomposition process of calcite.


AIChE Journal ◽  
1986 ◽  
Vol 32 (9) ◽  
pp. 1532-1545 ◽  
Author(s):  
Lawrence Candela ◽  
D. D. Perlmutter

1976 ◽  
Vol 26 (4) ◽  
pp. 191-198 ◽  
Author(s):  
Raouf Sh. Mikhail ◽  
Suzy A. Selim ◽  
Farouk I. Zeidan

2015 ◽  
Vol 60 (2) ◽  
pp. 1375-1377 ◽  
Author(s):  
K.Ch. Jeon ◽  
Y.D. Kim ◽  
M.-J. Suk ◽  
S.-T. Oh

Abstract Porous Ti with controlled pore structure was fabricated by thermal decomposition and sintering process using TiH2 powders and Polymethylmethacrylates (PMMA) beads as pore forming agent. The beads sizes of 8 and 50 μm were used as a template for fabricating the porous Ti. The TiH2 powder compacts with 20 and 70 vol% PMMA were prepared by uniaxial pressing and sintered for 2 h at 1100°C. TGA analysis revealed that the PMMA and TiH2 were thermally decomposed at about 400°C forming pores and at about 600°C into metallic Ti phase. The porosity increased with increase in the amount of PMMA addition. Also, the microstructure observation showed that the pore size and shape were strongly dependent on the PMMA shapes.


2019 ◽  
Vol 43 (26) ◽  
pp. 10560-10566 ◽  
Author(s):  
Dakang Wang ◽  
Yanqiu Jiang ◽  
Yinghui Hu ◽  
Dongyu Hao ◽  
Yulin Yang ◽  
...  

Mesoporous/macroporous Cr2O3 beads with 3D continuous pore structure exhibit improved thermal decomposition of ammonium perchlorate compared with Cr2O3 crystals.


Sign in / Sign up

Export Citation Format

Share Document