Sensitivity and economic analysis of a catalytic distillation process for alkylation desulfurization of fluid catalytic cracking (FCC) gasoline

2014 ◽  
Vol 91 (2) ◽  
pp. 490-506 ◽  
Author(s):  
Ying Ha ◽  
Benshuai Guo ◽  
Yonghong Li
2017 ◽  
Vol 23 (3) ◽  
pp. 391-398
Author(s):  
Zixia Li ◽  
Yin Ran ◽  
Wenqi Zhang ◽  
Wei Sun ◽  
Tinghai Wang

Gasoline aromatization and desulfurization (GARDES) technology is extensively used in refineries of Petrochina, aiming to produce high quality ultraclean fluid catalytic cracking (FCC) gasoline. This article introduces the industrial application results on the hydrodesulfurization unit of the Hohhot refinery, which plays an important role in guiding next round gasoline upgrading. The characteristics and the principle of GARDES technology were elaborated by analyzing the distribution of sulfur and hydrocarbon compounds in the feed and product. The analysis results proved that the presence of broad ranged sulfur types in the feed can be removed at different stages. Olefin can be decreased by saturation and conversion into i-paraffins and aromatics. The sulfur content of the blend product can be limited under 10 mg/kg, showing GARDES technology has excellent sulfur removal ability. The olefin reduction can also satisfy the ever-increasing severe requirement about the olefin limitation, while the loss of research octane number (RON) can be minimized to an acceptable level. Furthermore, according to the demand of gasoline upgrading, GARDES technology has great flexibility by adjusting operation condition without any further investment, which brings more economic benefits for refinery.


2012 ◽  
Vol 550-553 ◽  
pp. 550-553
Author(s):  
Yu Liu ◽  
Chun Hai Yi ◽  
Jia Yang Hu ◽  
Bo Lun Yang

A new approach was proposed to remove sulfuric compounds from fluid catalytic cracking (FCC) gasoline by combining an alkylation desulfurization catalytic distillation (ADCD) column with a hydrodesulfurization catalytic distillation (HDS-CD) column. In the ADCD column, isobutylene (IB) and 3-methylthiophene (3MT) were designated as the model compounds for olefin and sulfide, respectively; NKC-9 cation exchange resin was used as the catalyst. In the HDS-CD column, dibenzothiophene (DBT) was chosen as the model sulfides; Nickel phosphide supported on the TiO2-Al2O3 composite oxide prepared by our laboratory were designated as the HDS catalyst. Simulations for these two CD columns were carried out by RADFRAC module of Aspen Plus. The optimization results revealed that the ADCD column had an alkylation selectivity of 96%, and the sulfur content in the overhead stream was less than 8 μg/g. The simulation results of the HDS-CD process showed that the sulfide in the bottom stream of ADCD column can be removed practically by 100% and the clean oil stream from the bottom of HDS-CD column has hardly any sulfur.


2015 ◽  
Vol 41 (2) ◽  
pp. 3-11 ◽  
Author(s):  
Katarzyna Rychlewska ◽  
Krystyna Konieczny ◽  
Michał Bodzek

Abstract This paper presents the recent advances in pervaporative reduction of sulfur content in gasoline. Methods of preliminary selection of membrane active layer material are presented. Interactions between gasoline components (typical hydrocarbon and sulfur species) and membranes are showed. Influence of pervaporation process parameters i.e. feed temperature, downstream pressure and feed flow rate on the separation efficiency is discussed. Investigations of the influence of sulfur concentration in fluid catalytic cracking (FCC) gasoline on membrane performance have been conducted. A series of PV tests was carried out to investigate the separation properties of the commercial composite membrane with an active layer made of poly(dimethylsiloxane) and to determine the efficiency of organic sulphur compound (thiophene) removal from model thiophene/n-heptane mixture depending on its concentration.


Sign in / Sign up

Export Citation Format

Share Document