Curing kinetics of boron-containing phenol-formaldehyde resin formed from paraformaldehyde

2002 ◽  
Vol 34 (11) ◽  
pp. 638-644 ◽  
Author(s):  
Yanfang Liu ◽  
Jungang Gao



2015 ◽  
Vol 121 (2) ◽  
pp. 867-876 ◽  
Author(s):  
Zhao Yi ◽  
Cheng Li ◽  
Jinxue Jiang ◽  
Jizhi Zhang ◽  
Wei Zhang ◽  
...  


2012 ◽  
Vol 184-185 ◽  
pp. 1471-1479
Author(s):  
Jin Sun ◽  
Xiao Feng Zhu ◽  
Xiao Bo Wang ◽  
Rui Hang Lin ◽  
Zhen Zhong Gao

The curing kinetics of PF resin modified with sodium silicate had been investigated by differential scanning calorimetry (DSC). The kinetic analysis was performed at heating rates of 5, 10, 15, and 20°C/min,respectively. The kinetic parameters such as reaction order and activation energy were solved by Kissinger and Crane equation. The relationship between curing temperature and heating rate was also investigated. The activation energy and the curing reaction order,which were obtained by kinetic calculation, are 83.00kJ/mol and 0.917, respectively. The curing reaction kinetics equations were built by the obtained best curing temperature, reaction order, pre-exponential factor and reaction rate constant.



2013 ◽  
Vol 58 (3) ◽  
pp. 837-840 ◽  
Author(s):  
J. Zych

Abstract The results of investigations of the moulding sands hardening process in the cold-box technology - with an application of two ways of gas dosage - are presented in the paper. A new, ultrasound method of testing the kinetics of hardening of moulding sands with chemical binders was applied. Moulding sands with phenol-formaldehyde resin and moulding sands with water-glass hardened by CO2:, were subjected to investigations. A continuous gas dosage was substituted by the pulsating one. It was shown, that the change of the dosage mode could lead to decreasing the gas consumption (even several times). In addition, it was found that the pulsating way of dosage provides improvements of moulding sands technological properties, mainly strength. Investigations concerned the cold-box processes, in which one or two technological gases were used.



Carbon ◽  
2010 ◽  
Vol 48 (2) ◽  
pp. 352-358 ◽  
Author(s):  
Haiyun Jiang ◽  
Jigang Wang ◽  
Shenqing Wu ◽  
Baosheng Wang ◽  
Zhangzhong Wang


2020 ◽  
pp. 34-43
Author(s):  
N. R. Memetov ◽  
◽  
A. V. Gerasimova ◽  
A. E. Kucherova ◽  
◽  
...  

The paper evaluates the effectiveness of the use of graphene nanostructures in the purification of lead (II) ions to improve the ecological situation of water bodies. The mechanisms and characteristic parameters of the adsorption process were analyzed using empirical models of isotherms at temperatures of 298, 303, 313 and 323 K, which correspond to the following order (based on the correlation coefficient): Langmuir (0.99) > Temkin (0.97) > Dubinin – Radushkevich (0.90). The maximum adsorption capacity of the material corresponds to the range from 230 to 260 mg/g. We research the equilibrium at the level of thermodynamic parameter estimates, which indicates the spontaneity of the process, the endothermic nature and structure change of graphene modified with phenol-formaldehyde resin during the adsorption of lead (II) ions, leading to an increase in the disorder of the system.



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