Influence of elongational flow generating nozzles on material properties of polypropylene nanocomposites

In this work, the same formulations of Nano-Silica/intumescent fire retardant polypropylene nanocomposites were prepared via a novel vane extruder and a tri-screw extruder, which represented elongational flow field and shearing flow field, respectively. Not only the synergistic combustion mechanisms of Kissinger method and Flynn-Wall-Ozawa method were revealed, but also the combustion effect and efficiency were compared. Both two methods proved specimens that processed by TE exhibited higher thermal stability. The smaller aggregates of physical initial Nano-Silica, the better dispersivity of aggregates in specimens that processed by VE. Such property broke the compactness degree of char layer.

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A study on material optimization for polypropylene nanocomposites based on layered silicates using elongational flow devices

10.1063/1.4965496 ◽

2016 ◽

Author(s):

W. Friesenbichler ◽

M. G. Battisti ◽

A. Neunhäuserer

Keyword(s):

Elongational Flow ◽

Layered Silicates ◽

Material Optimization ◽

Polypropylene Nanocomposites ◽

Flow Devices

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Polypropylene Nanocomposites, Study of the Influence of the Nanofiller Nature on Morphology and Material Properties

Macromolecular Symposia ◽

10.1002/masy.201150315 ◽

2011 ◽

Vol 301 (1) ◽

pp. 114-127 ◽

Cited By ~ 12

Author(s):

D. Tabuani ◽

S. Ceccia ◽

G. Camino

Keyword(s):

Material Properties ◽

Polypropylene Nanocomposites

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Grain boundary segregation in metals

Proceedings, annual meeting, Electron Microscopy Society of America ◽

10.1017/s0424820100130651 ◽

1992 ◽

Vol 50 (2) ◽

pp. 1204-1205

Author(s):

C.L. Briant

Keyword(s):

Fracture Surface ◽

Grain Boundary ◽

Grain Boundaries ◽

Material Properties ◽

Electron Spectroscopy ◽

High Vacuum ◽

Boundary Segregation ◽

Grain Boundary Segregation ◽

Local Concentration ◽

The One

Grain boundary segregation is the process by which solute elements in a material diffuse to the grain boundaries, become trapped there, and increase their local concentration at the boundary over that in the bulk. As a result of this process this local concentration of the segregant at the grain boundary can be many orders of magnitude greater than the bulk concentration of the segregant. The importance of this problem lies in the fact that grain boundary segregation can affect many material properties such as fracture, corrosion, and grain growth.One of the best ways to study grain boundary segregation is with Auger electron spectroscopy. This spectroscopy is an extremely surface sensitive technique. When it is used to study grain boundary segregation the sample must first be fractured intergranularly in the high vacuum spectrometer. This fracture surface is then the one that is analyzed. The development of scanning Auger spectrometers have allowed researchers to first image the fracture surface that is created and then to perform analyses on individual grain boundaries.

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Relationships Between Grain Boundary Structure and Material Properties

Proceedings, annual meeting, Electron Microscopy Society of America ◽

10.1017/s1431927600001550 ◽

1980 ◽

Vol 38 ◽

pp. 366-369

Author(s):

Brian Ralph ◽

Barlow Claire ◽

Nicola Ecob

Keyword(s):

Grain Boundary ◽

Material Properties ◽

Main Property ◽

Grain Structure ◽

Boundary Structure ◽

Grain Boundary Structure ◽

Property Changes

This brief review seeks to summarize some of the main property changes which may be induced by altering the grain structure of materials. Where appropriate an interpretation is given of these changes in terms of current theories of grain boundary structure, and some examples from current studies are presented at the end of this paper.

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