Miscibility and isothermal crystallization behavior of polyamide 6/poly(vinyl alcohol) blend

2008 ◽  
Vol 46 (13) ◽  
pp. 1360-1368 ◽  
Author(s):  
Li Cui ◽  
Jen-Taut Yeh ◽  
Ke Wang ◽  
Qiang Fu
2006 ◽  
Vol 55 (4) ◽  
pp. 383-390 ◽  
Author(s):  
Zhi-Xuan Zhou ◽  
Xiu-Li Wang ◽  
Yu-Zhong Wang ◽  
Ke-Ke Yang ◽  
Si-Chong Chen ◽  
...  

2019 ◽  
Vol 39 (2) ◽  
pp. 124-133 ◽  
Author(s):  
Bingxiao Liu ◽  
Guosheng Hu ◽  
Jingting Zhang ◽  
Zhongqiang Wang

AbstractStudy of the crystallization kinetics is particularly necessary for the analysis and design of processing operations, especially the non-isothermal crystallization behavior, which is due to the fact that most practical processing techniques are carried out under non-isothermal conditions. The non-isothermal crystallization behaviors of polyamide 6 (PA6) and PA6/high-density polyethylene/maleic anhydride/2,5-dimethyl-2,5-di(tert-butylperoxy)hexane (PA6/HDPE/MAH/L-101) composites were investigated by differential scanning calorimetry (DSC). The crystallization kinetics under non-isothermal condition was analyzed by the Jeziorny and Mo equations, and the activation energy was determined by the Kissinger and Takhor methods. The crystal structure and morphology were analyzed by wide-angle X-ray diffraction (WXRD) and polarized optical microscopy (POM). The results indicate that PA6/HDPE/MAH/L-101 has higher crystallization temperature and crystallization rate, which is explained as due to its heterogeneous nuclei.


RSC Advances ◽  
2017 ◽  
Vol 7 (16) ◽  
pp. 9854-9861 ◽  
Author(s):  
Ming He ◽  
Buning Zhang ◽  
Yao Dou ◽  
Guoqiang Yin ◽  
Yingde Cui ◽  
...  

We have fabricated random and aligned feather keratin (FK)/PVA composite nanofibers through an electrospinning process. The morphology, molecular interactions, crystallization behavior, and tensile properties of the nanofibers were investigated.


2015 ◽  
Vol 1088 ◽  
pp. 52-57 ◽  
Author(s):  
Yan Xu ◽  
Bing Gao ◽  
Bao Qi Zuo

The effects of different proportions of poly (vinyl alcohol) and polyamide 6 on the structure and property of electrospun PA6/PVA membranes have been studied. According to a certain proportion, PVA and PA6 were dissolved in formic acid. The solution was electrospun at 70 kV. The nanofibers membranes were characterized by SEM, FT-IR, XRD, TGA and DSC analyses. The sound absorption coefficients of each absorber are measured with SW477 impedance tube. PA6/PVA composite mats with good compatibility and relatively stable performance, and enhanced sound absorption and property may have many other important applications.


2018 ◽  
Vol 773 ◽  
pp. 100-105
Author(s):  
Umi Rofiqah ◽  
Achmad Chafidz ◽  
Lilis Kistriyani ◽  
Mujtahid Kaavessina ◽  
Muhammad Rizal ◽  
...  

In the present study, high density poly(ethylene) (HDPE)/poly(vinyl alcohol) (PVA) fiber composites were prepared via melt blending technique using a co-rotating twin screw extruder (TSE). The effect of four different PVA fiber concentrations (i.e. 0, 5, 10, 20 wt%) on the melt and crystallization behavior of the HDPE/PVA fiber composites were investigated. The surface morphology of the composites was analyzed by a scanning electron microscopy (SEM). Whereas, the melt and crystallization behavior of the composites were analyzed by a differential scanning calorimetry (DSC). The SEM analysis on the cryo-fractured surface of the HDPE/PVA fiber composites exhibited that the PVA fibers were well blended/distributed in the HDPE matrix. Additionally, the DSC test results showed that the addition of PVA fiber in the HDPE matrix did not significantly change the melting peak temperature (Tm) of the composites. Furthermore, a slight decrease of the crystallization peak temperature (Tc) can be observed when the PVA fiber was incorporated in the HDPE matrix, which indicated a weak nucleation ability of the PVA fibers in the HDPE crystallization process. The same trend was also observed for the crystallinity index (Xc). The crystallinity index of the composites decreased with increasing PVA fiber loadings.


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