conductive carbon black
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2022 ◽  
Vol 58 (4) ◽  
pp. 37-46
Author(s):  
Abeer Adaileh ◽  
Mohammed Al-Tweissi ◽  
Husam Miqdad

The electrical properties of conductive carbon black (CB) nanoparticles (0.1wt percent) doped thin films made of poly(ethylene oxide) (PEO) filled with varying amounts of the electrolyte potassium alum salt and doped with conductive carbon black (CB) nanoparticles (0.1wt percent) have been investigated. The dependence of the activation energy of the composites on frequency, temperature, and filler content was studied using the AC impedance technique. The current research looked at how activation energy changed with frequency (200-1000 kHz) and temperature (30-55oC) for composites with varied potassium alum salt concentrations: 0, 2, 4, 8, 12, and 16 wt. percent. The activation energy (Ea) values measured exhibited frequency, temperature, and filler content relationships. According to polarization processes, the activation energy of the produced sheets decreases with the potassium alum salt content in the composite and decreases with the temperature. With increasing frequency, the activation energy of the produced thin films decreases.


RSC Advances ◽  
2022 ◽  
Vol 12 (2) ◽  
pp. 1184-1193
Author(s):  
Yanli Dou ◽  
Haijing Gu ◽  
Shixiang Sun ◽  
Weiguo Yao ◽  
Dongbo Guan

Schematic of the fabrication procedure of SMCB@Ag with the grape-like structure.


Author(s):  
Husam Miqdad

The electrical characteristics of hybrid polymer thin films consisting of conductive carbon black (CB) nanoparticles (0.1wt%) doped in poly(ethylene oxide) (PEO) filled with electrolyte potassium alum salt at varied concentrations were studied. For varied potassium alum concentrations and fixed content of conductive carbon black of concentration (0.1 wt. percent), the AC electrical characteristics were studied in the frequency range (3kHz - 5MHz) and temperature range (30 oC - 55 oC). Thin film physical constants such as dielectric constant, dielectric loss, AC conductivity, and impedance have been recorded. These measured amounts were discovered to fluctuate with potassium alum concentration, applied field frequency, and temperature. With increasing potassium alum content, frequency, and temperature, the AC conductivity (ac) increases. Dielectric constant (ε') and dielectric loss (ε'') of the composites increase with potassium alum concentration and decrease with frequency.


2021 ◽  
Vol 188 (10) ◽  
Author(s):  
Radosław Porada ◽  
Katarzyna Fendrych ◽  
Bogusław Baś

Abstract The utilization of environmentally friendly nanoporous natural zeolite exchanged with Ni2+ ions (NiZ) and conductive carbon black (CB) in the fabrication of a novel and selective voltammetric sensor of vitamin B6 (VB6) is presented. The used clinoptilolite-rich zeolite material and CB were characterized in terms of morphology and textural properties. The superior properties of Ni-zeolite/carbon black modified glassy carbon electrode (NiZCB-GCE), arising from the synergistic effect of combining the unique features of zeolite and conductive carbon black, were confirmed by cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS) measurements. In the determination of VB6 with the use of differential pulse voltammetry (DPV), the optimization of the pH value of supporting electrolyte and instrumental parameters, as well as the interference study were performed. Under optimized conditions, the oxidation peak current at the potential +0.72 V vs. Ag | AgCl | 3 M KCl reference electrode was linear to the VB6 concentration in the range 0.050 to 1.0 mg L−1 (0.30–5.9 μmol L−1) (R = 0.9993). The calculated limit of detection (LOD, S/N = 3), equal to 15 μg L−1 (0.09 μmol L−1), was much better compared to chemically modified electrodes with other carbon-based materials. The RSD for 0.5 mg L−1 was in the range 2.5–5.4% (n = 4). The developed NiZCB-GCE was successfully applied to the determination of VB6 in commercially available multivitamin dietary supplements, food, and water samples. The obtained recoveries ranged from 95 to 106%. Graphical abstract


NANO ◽  
2021 ◽  
pp. 2150094
Author(s):  
Wei He ◽  
Yawei Wang ◽  
Jihang Xu

Conductive carbon black Super-P (CSP) is a kind of nanomaterial, which is often used as conductive agent. It has excellent conductivity and low production cost. In this paper, CSP was used as the admixture to prepare composite mortar (with the specific gravity of cementitious material). The consistency, mechanical properties, electrical conductivity and temperature sensitivity of composite mortar were studied. The mechanism of CSP was analyzed by scanning electron microscope (SEM) and X-ray diffraction (XRD). The results show that the consistency of composite mortar decreases with the addition of CSP. The mechanical properties of composite mortar first increase and then decrease with the increase of CSP content. The addition of CSP greatly improves the conductivity of mortar. When the CSP content is 0.5–2%, the resistivity decreases rapidly and the seepage threshold appears. When the content of the mixture is large, the influence of different curing conditions on resistivity is small. SEM and XRD analysis show that CSP can fill micro pores and conduct electricity through tunnels, and does not change the composition of hydration products of composite mortar, and the formation of calcium hydroxide can be inhibited when the content is small. This paper explores the properties of CSP composite mortar, which provides theoretical and experimental basis for the preparation and application of conductive mortar.


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