On the relationship between NMR-derived amide order parameters and protein backbone entropy changes

The paper discusses the main manufactures-suppliers mode cooperation mechanism based on synergetic theory, and it explicates the rule of interests flow through order parameter forming principle, and evaluated the synergetic degree of the system based on five key order parameters, then it designs an interest distribution model to explain the relationship among synergy degree and contribution coefficients and interest distribution coefficients, which made important meaning to guide the supply chain practical operation.

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Acquisition of isotopic composition for surface snow in East Antarctica and the links to climatic parameters

The Cryosphere Discussions ◽

10.5194/tcd-9-6275-2015 ◽

2015 ◽

Vol 9 (6) ◽

pp. 6275-6313 ◽

Cited By ~ 1

Author(s):

A. Touzeau ◽

A. Landais ◽

B. Stenni ◽

R. Uemura ◽

K. Fukui ◽

...

Keyword(s):

Isotopic Composition ◽

Ice Cores ◽

Order Parameters ◽

Second Order ◽

East Antarctica ◽

Distillation Process ◽

Past Climate ◽

Climatic Signal ◽

Surface Snow ◽

The Relationship

Abstract. The isotopic composition of oxygen and hydrogen in ice cores are invaluable tools for the reconstruction of past climate variations. Used alone, they give insights into the variations of the local temperature, whereas taken together they can provide information on the climatic conditions at the point of origin of the moisture. However, recent analyses of snow from shallow pits indicate that the climatic signal can become erased in very low accumulation regions, due to local processes of snow reworking. The signal to noise ratio decreases and the climatic signal can then only be retrieved using stacks of several snow pits. Obviously, the signal is not completely lost at this stage, otherwise it would be impossible to extract valuable climate information from ice cores as has been done, for instance, for the last glaciation. To better understand how the climatic signal is passed from the precipitation to the snow, we present here results from varied snow samples from East Antarctica. First, we look at the relationship between isotopes and temperature from a geographical point of view, using results from three traverses across Antarctica, to see how the relationship is built up through the distillation process. We also take advantage of these measures to see how second order parameters (d-excess and 17O-excess) are related to δ18O and how they are controlled. d-excess increases in the interior of the continent (i.e. when δ18O decreases), due to the distillation process, whereas 17O-excess decreases in remote areas, due to kinetic fractionation at low temperature. In both cases, these changes are associated with the loss of original information regarding the source. Then, we look at the same relationships in precipitation samples collected over one year at Dome C and Vostok, as well as in surface snow at Dome C. We note that the slope of the δ18O / T relationship decreases in these samples compared to those from the traverses, and thus advocate caution when using spatial slopes for past climate reconstruction. The second-order parameters behave in the same way in the precipitation as in the surface snow from traverses, indicating that similar processes are active. Finally we check if the same relationships between δ18O and second-order parameters are also found in the snow from four snow pits. While the d-excess remains opposed to δ18O in most snow pits, the 17O-excess is no longer positively correlated to δ18O and even shows anti-correlation to δ18O at Vostok. This may be due to a stratospheric influence at this site and/or to post-deposition processes.

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The Elasticity of Rubber

Rubber Chemistry and Technology ◽

10.5254/1.3542364 ◽

1958 ◽

Vol 31 (5) ◽

pp. 959-981

Author(s):

Lawrence A. Wood

Keyword(s):

Energy Function ◽

Strain Energy ◽

Strain Energy Function ◽

Phenomenological Approach ◽

Entropy Changes ◽

A Value ◽

Strain Invariants ◽

Strain Invariant ◽

The One ◽

The Relationship

Abstract Rubbers, natural and synthetic, are unique in being highly extensible and in retracting forcibly and quickly to substantially their original dimensions when released. It has been found that the stress-strain curves for extension and compression of most of the simplest vulcanizates of natural rubber and the three most important synthetic rubbers are similar in shape. The relationship is expressed by the equation F/M=(L−1−L−2) exp A(L−L−1) where F is the stress, L the ratio of stretched to unstretched length, and M and A are constants. The constant M depends on the nature of the rubber, the extent of vulcanization, and the time of creep. The constant A has a value of about 0.38. By a study of stress-temperature relations it is found that the most important factor in the retraction of stretched rubber is the tendency of long chain flexible molecules to return to a configuration which is statistically more probable than the one which the stretching has forced them to assume. Calculations of entropy changes arising from stretching can be made from probability considerations, and a strain energy function deduced from the entropy changes. Stresses calculated from the strain energy function agree with those observed in compression but are greater than those observed in extension by almost 50 per cent at L=3. A phenomenological approach shows that the strain energy should be expressible as a function of certain quantities called strain invariants, calculable from the deformations. The simplest behavior is found in the region of compression (L less than 1), where the strain energy is merely the first invariant times a constant calculable from the entropy changes. For values of L between 1.5 and 3 a different constant and an added term involving the second strain invariant are required. The explanation of this behavior in molecular terms is one of the most important current problems of rubber elasticity.

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Mechanical analysis of heterogeneous materials with higher-order parameters

Engineering With Computers ◽

10.1007/s00366-021-01555-9 ◽

2021 ◽

Author(s):

Bozo Vazic ◽

Bilen Emek Abali ◽

Hua Yang ◽

Pania Newell

Keyword(s):

Mechanical Properties ◽

Porous Materials ◽

Higher Order ◽

Order Parameters ◽

Constitutive Law ◽

Porous System ◽

First Order ◽

Bio Engineering ◽

The Relationship ◽

Effective Mechanical Properties

AbstractEven though heterogeneous porous materials are widely used in a variety of engineering and scientific fields, such as aerospace, energy-storage technology, and bio-engineering, the relationship between effective material properties of porous materials and their underlying morphology is still not fully understood. To contribute to this knowledge gap, this paper adopts a higher-order asymptotic homogenization method to numerically investigate the effect of complex micropore morphology on the effective mechanical properties of a porous system. Specifically, we use the second-order scheme that is an extension of the first-order computational homogenization framework, where a generalized continuum enables us to introduce length scale into the material constitutive law and capture both pore size and pore distribution. Through several numerical case studies with different combinations of porosity, pore shapes, and distributions, we systematically studied the relationship between the underlying morphology and effective mechanical properties. The results highlight the necessity of higher-order homogenization in understanding the mechanical properties and reveal that higher-order parameters are required to capture the role of realistic pore morphologies on effective mechanical properties. Furthermore, for specific pore shapes, higher-order parameters exhibit dominant influence over the first-order continuum.

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Acquisition of isotopic composition for surface snow in East Antarctica and the links to climatic parameters

The Cryosphere ◽

10.5194/tc-10-837-2016 ◽

2016 ◽

Vol 10 (2) ◽

pp. 837-852 ◽

Cited By ~ 36

Author(s):

Alexandra Touzeau ◽

Amaëlle Landais ◽

Barbara Stenni ◽

Ryu Uemura ◽

Kotaro Fukui ◽

...

Keyword(s):

Ice Cores ◽

Order Parameters ◽

Second Order ◽

East Antarctica ◽

Local Temperature ◽

Distillation Process ◽

Climatic Parameters ◽

Climatic Signal ◽

Surface Snow ◽

The Relationship

Abstract. The isotopic compositions of oxygen and hydrogen in ice cores are invaluable tools for the reconstruction of past climate variations. Used alone, they give insights into the variations of the local temperature, whereas taken together they can provide information on the climatic conditions at the point of origin of the moisture. However, recent analyses of snow from shallow pits indicate that the climatic signal can become erased in very low accumulation regions, due to local processes of snow reworking. The signal-to-noise ratio decreases and the climatic signal can then only be retrieved using stacks of several snow pits. Obviously, the signal is not completely lost at this stage, otherwise it would be impossible to extract valuable climate information from ice cores as has been done, for instance, for the last glaciation. To better understand how the climatic signal is passed from the precipitation to the snow, we present here results from varied snow samples from East Antarctica. First, we look at the relationship between isotopes and temperature from a geographical point of view, using results from three traverses across Antarctica, to see how the relationship is built up through the distillation process. We also take advantage of these measures to see how second-order parameters (d-excess and 17O-excess) are related to δ18O and how they are controlled. d-excess increases in the interior of the continent (i.e., when δ18O decreases), due to the distillation process, whereas 17O-excess decreases in remote areas, due to kinetic fractionation at low temperature. In both cases, these changes are associated with the loss of original information regarding the source. Then, we look at the same relationships in precipitation samples collected over 1 year at Dome C and Vostok, as well as in surface snow at Dome C. We note that the slope of the δ18O vs. temperature (T) relationship decreases in these samples compared to those from the traverses, and thus caution is advocated when using spatial slopes for past climate reconstruction. The second-order parameters behave in the same way in the precipitation as in the surface snow from traverses, indicating that similar processes are active and that their interpretation in terms of source climatic parameters is strongly complicated by local temperature effects in East Antarctica. Finally we check if the same relationships between δ18O and second-order parameters are also found in the snow from four snow pits. While the d-excess remains opposed to δ18O in most snow pits, the 17O-excess is no longer positively correlated to δ18O and even shows anti-correlation to δ18O at Vostok. This may be due to a stratospheric influence at this site and/or to post-deposition processes.

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Interstellar gas in the central region of the Galaxy

Symposium - International Astronomical Union ◽

10.1017/s0074180900101032 ◽

1967 ◽

Vol 31 ◽

pp. 239-251 ◽

Cited By ~ 3

Author(s):

F. J. Kerr

Keyword(s):

Central Region ◽

Galactic Plane ◽

Neutral Hydrogen ◽

Continuum Emission ◽

Galactic Centre ◽

Interstellar Gas ◽

Hydrogen Recombination ◽

The Galaxy ◽

Centre Region ◽

The Relationship

A review is given of information on the galactic-centre region obtained from recent observations of the 21-cm line from neutral hydrogen, the 18-cm group of OH lines, a hydrogen recombination line at 6 cm wavelength, and the continuum emission from ionized hydrogen.Both inward and outward motions are important in this region, in addition to rotation. Several types of observation indicate the presence of material in features inclined to the galactic plane. The relationship between the H and OH concentrations is not yet clear, but a rough picture of the central region can be proposed.

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The relationship of the scleractinian corals to the rugose corals

Paleobiology ◽

10.1017/s0094837300025707 ◽

1980 ◽

Vol 6 (02) ◽

pp. 146-160 ◽

Cited By ~ 29

Author(s):

William A. Oliver

Keyword(s):

Critical Points ◽

Scleractinian Corals ◽

Convincing Evidence ◽

Early Triassic ◽

Rugose Corals ◽

History Of ◽

The Subject ◽

Relationship Of ◽

The Relationship ◽

Biologic Factors

The Mesozoic-Cenozoic coral Order Scleractinia has been suggested to have originated or evolved (1) by direct descent from the Paleozoic Order Rugosa or (2) by the development of a skeleton in members of one of the anemone groups that probably have existed throughout Phanerozoic time. In spite of much work on the subject, advocates of the direct descent hypothesis have failed to find convincing evidence of this relationship. Critical points are:(1) Rugosan septal insertion is serial; Scleractinian insertion is cyclic; no intermediate stages have been demonstrated. Apparent intermediates are Scleractinia having bilateral cyclic insertion or teratological Rugosa.(2) There is convincing evidence that the skeletons of many Rugosa were calcitic and none are known to be or to have been aragonitic. In contrast, the skeletons of all living Scleractinia are aragonitic and there is evidence that fossil Scleractinia were aragonitic also. The mineralogic difference is almost certainly due to intrinsic biologic factors.(3) No early Triassic corals of either group are known. This fact is not compelling (by itself) but is important in connection with points 1 and 2, because, given direct descent, both changes took place during this only stage in the history of the two groups in which there are no known corals.

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