Determination of bond dissociation energies using mass spectrometry

2007 ◽  
Vol 107 (6) ◽  
pp. 1367-1372 ◽  
Author(s):  
John Hanna El-Nakat ◽  
Noha Ghanem ◽  
Paolo Yammine ◽  
Gary Willett ◽  
Keith Fisher
Keyword(s):  
Mass Spectrometry ◽  
Bond Dissociation Energies ◽  
Bond Dissociation ◽  
Dissociation Energies

Determination of Ruthenium−Phosphorus Bond Dissociation Energies by ES-FTICR Mass Spectrometry

2002 ◽  
Vol 21 (26) ◽  
pp. 5688-5691 ◽  
Author(s):  
John B. Westmore ◽  
Lisa Rosenberg ◽  
Timothy S. Hooper ◽  
Gary D. Willett ◽  
Keith J. Fisher
Keyword(s):  
Mass Spectrometry ◽  
Bond Dissociation Energies ◽  
Fticr Mass Spectrometry ◽  
Bond Dissociation ◽  
Dissociation Energies

Experimental methods for measurement of bond dissociation energies and heats of formation of radicals

1951 ◽  
Vol 207 (1088) ◽  
pp. 5-13 ◽  
Keyword(s):  
Experimental Methods ◽  
Experimental Results ◽  
Heats Of Formation ◽  
Bond Dissociation Energies ◽  
Carrier Gas ◽  
Bond Dissociation ◽  
Dissociation Energies ◽  
Kinetics Of

The paper describes a pyrolytic method of investigating the kinetics of gaseous reactions in which toluene is used as a carrier gas. It is shown that the method is particularly suitable for the determination of bond dissociation energies. The scope of the method is illustrated by various examples. A list of bond dissociation energies obtained is given. The manner in which the experimental results obtained can be cross-checked, is indicated and illustrated by examples. The effects of various constitutional factors on the bond dissociation energies are discussed.

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